芳基化物

Moreover, the polymeric arsine palladium(0) complex is an efficient catalyst for the carbonyl allylation of aldehydes and the coupling reaction of aryl halides with terminal alkynes or Grignard reagent.

该聚合物负载的胂钯(0)配合物还是醛的羰基烯丙基化及芳基卤化物与端炔、Grignard试剂的交叉偶联反应的有效催化剂。

The reaction of the compound - 3 - triaiylstannyl -1,1 - diphenyl - 2 - propenyl - 1 -ol with ICl,Br2,I2 formed organotin halides ,which reacted with KOH to form organotin oxide or hydroxide.

首次以非碳环醇-3-三芳基锡基-1，1-二苯基-2-丙烯基-1-醇[Ph_2 CCH=CHSnAr_3]和卤素或拟卤素发生取代反应得到卤化物，并以此合成了氢氧化物、氧化物和配合物。

A series of liquid crystals containing naphthalene 1~13 was synthesized by the reaction of carbonyl compound with Grignard reagent and coupling reaction between phenyl boronic acid and halogen naphthalene .

经羰基化合物与格氏试剂反应及芳基硼酸与萘基卤化物偶联反应合成了系列含萘环骨架液晶化合物1~13；产率在73%~759%。

In order to find biologically active urea compounds,seven new N-[5-(3-pyridyl)-1,3,4-thiadiazol-2-yl]-N'- urea derivatives were synthesized by the reaction of 2-amino-5-(3-pyridyl)-1,3,4-thiadiazole with aroylazides,which were prepared starting from carboxylic acids,ethyl chloroformate and sodium azide by one-pot procedure.

为了寻找高生物活性的脲类化合物，通过2-氨基-5-(3-吡啶基)-1，3，4-噻二唑与酰基叠氮化物反应，设计合成了7个新的N-[5-(3-吡啶基)-1，3，4-噻二唑-2-基]-N'-取代苯基脲，其中芳酰基叠氮化物是以芳酸、氯甲酸乙酯、叠氮化钠为起始原料采用&一锅法&所制得。

ATRP initiation systems consist of organic chloride initiators (RCl, RBr or aryl sulfonyl chloride, etc.), transition-metal catalysts in lower oxidation state Cu(I, Fe, Ru, Ni, etc. and organic electronic-donating ligands (2,2'-bipyridine―bipy or bpy, PPh3, multidentate ligand compound 1,1,4,7,7-pentamethyldiethylenetriamine, etc.).

普通ATRP引发体系包括引发剂主要为氯或溴化物，芳基磺酰氯；低价过渡金属卤化物如Cu， Fe，Ru，Ni等；有机配体如2，2'-联吡啶，PPh3，脂肪族多元胺等。

Under these conditions several aryl iodides bearing a wide range of functional groups were converted into the corresponding aryl azides in good yields.

在重新优化后的条件下，大部分不活泼芳基溴化物可以与叠氮化钠发生交叉偶联反应得到良好收率的芳基叠氮化合物，但是有拉电子基团取代的芳基溴化物与叠氮化钠的偶联反应则难以进行。

Under these conditions several aryl iodides bearing awide range of functional groups were converted into the corresponding aryl azides in good yields.

在重新优化后的条件下，大部分不活泼芳基溴化物可以与叠氮化钠发生交叉偶联反应得到良好收率的芳基叠氮化储蓄型投资银条合物，但是有拉电子基团取代的芳基溴化物与叠氮化钠的偶联反应则难以进行。

Monophenyltin trichloride reacts withdicarbonyl dicyclopentadienyl titanium immediately at room temperature, but no ti-tanium-tin complex produced, and the products were diphenyltin dichloride〓 and tin or stannous Chloride. When diaryltin dihalides were used, only the chlorides and bromides reacted with 〓form the complexes containing titaninm-tin bond,〓. but the corresponding iodide complex was not found. This reaction is Sensitive totemperature,when the temperature is belw 10℃,the reaction hardly takes place,but as the temperature is above 25℃,more 〓 will be found and the reactionbecome more complex.

Ph-SnC〓室温下即可与Cp〓迅速反应，但不生成含钛一锡链的化合物，而是生成Ph〓和Sn或Sn〓二芳基二卤化锡化物中，只有氯化物和溴化物才能和〓反应生成含钛〓锡键的化合物〓相应的碘化物则不行，而且反应对温度比较敏感，低于10℃，反应几乎不能进行，而高于25〓，则会生成更多的〓，在回流条件下得不到含钛〓锡键的化合物，只能得到分解产物，〓和Sn或〓。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。