芳基化

The author and his colleagues have performed the experiment before the introduction of electro- philic aromatic substitution or enolate halogenation in lectures.

作者和他的团队在介绍亲电芳基取代或烯醇卤化的课程前已经进行了实验。

In this dissertation, I will represent my studies on the nitration of Chalcone derivatives, reaction of epoxide ketone, and the aromatization of 3,5-disubstitued 2-isoxazolines with nitric oxide.

本文主要研究了：(1)NO与查尔酮及其衍生物的硝化反应，反应以较高的产率得到了a-硝基化合物；(2)NO对环氧酮的开环反应，反应生成了顺式羟基硝酸酯；(3)3，5-二取代的-2-异恶唑啉在NO作用下可以发生芳环化反应，生成了对应的2-异恶唑化合物。

In the forth part, in the presence of chiral phosphoric acid, highly enantio-enriched (up to 98% ee)α-aryl glycine derivatives could be synthesized via asymmetric transfer hydrogenation of the α-aryl imino esters using Hantzsch ester as the hydrogen source.

第四部分工作中，利用Hantzsch酯作为氢源，高对映选择性地实现了手性磷酸催化芳基酮酸酯亚胺的不对称仿生氢化反应，以最高98％的对映选择性得到苯甘氨酸衍生物。

Four different ionic liquids, BF4, BF and PF6 were investigated, arid PF6 showed the best effect when used as the reaction media, giving the highest yield in the shortest reaction time. Promoted by KF in PF6, N-aryl or N-alkyl monosubstituted sulfonamides could react with various activated halides and unactivated primary halides smoothly. Reactions were performed at 85℃ for 2~10 hours, and thirteen N-alkylation products were obtained with 70%~97% yields. Moreover, the ionic liquid recovered could be reused for three times with no appreciable decrease in yield and reaction rate.

结果表明，以PF6为反应介质时显示出了最好的效果，反应的时间最短，收率最高。N-芳基或N-烷基单取代的磺酰胺和各类不同结构的活化的卤代烃和未活化的一级卤代烃在PF6中KF作用下，85℃反应2~10h，以70%~97%的优良收率得到了13个N-烷基化产物，而且离子液体回收使用3次后效果未降低。

The pyridinium salts was transformed by the base to 1-hydroxy or 3-hydroxy-quinolizinylides, which undergo 1,3-dipolar cycloadditionreaction with alkenes,and then aromatizated to cycl[3,3,2]azinone in thepresence of oxidant.

实验证明，这是一个连续进行的多步反应：2-羰基吡啶鎓盐在反应中先生成1-羟基或3-羟基喹嗪叶立德，然后与烯烃起1，3—偶极加成反应，最后在氧化剂作用下脱氢芳构化而生成Cycl[3，3，2]azinone。

It was demonstrated that the novel functional hyperbanched polyethylene could be prepared by the copolymerization of ethylene and polar comonomers protected by alkyl or aromatic silyl group.

研究表明，经烷基或芳基硅烷基团保护的极性单体与乙烯在MHNB催化作用下，通过共聚可以得到结构新颖的功能性超支化聚乙烯。

Comparisons between the experimental and computational IR spectra clarify the difference of the open- and closed-ring isomers, which indicate that it is possible to identify the tautomeric form of this diarylethene derivative using a highly selective infrared absorption band and the strong absorption at 1 705 cm-1 of the ring-closed isomer can be used in non-destructive readout by IR light.

通过红外吸收光谱表征了该光致变色二芳基乙烯衍生物在溶液中开、关环前后结构的变化，并采用理论化学计算方法研究了该化合物开、关环异构体的红外吸收振动特性。光致变色异构化过程可以通过红外吸收光谱的变化而识别。关环异构体在1 705 cm

A series of urea,thiourea and thiodiazole derivatives bearing mercaptotetrazole were synthesized using NaN_3 as a nitrogen source.

以叠氮化钠为氮源，合成了一系列含四唑环的芳基脲及噻二唑类化合物，其结构经1H NMR，IR和元素分析表征。

Besides, n-butyl and sec-butyl tosylate that are difficult for oxidative addition can react with phenylmagnesium bromide to form corresponding cross-coupling products. Primary alkyl halide which contains β-hydrogen and is relatively hard to undergo the reaction , n-butyl chloride for instance, can react with aryl Grignard reagents in the presence of NiB alloy as well.

此外，难以进行氧化加成的对甲苯磺酸正丁酯和对甲苯磺酸仲丁酯可以与苯基溴化镁作用生成相应的交叉偶联产物；反应相对困难的含β-H的伯卤烷，如：正氯丁烷也可以在NiB催化下与芳基格氏试剂发生偶联。

METAL ARYLS, WATER

卤化芳基金属，遇水反应，未另作规定的

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。