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The catalytic performance of MDA on a Mo/HZSM-5 catalyst derived from the HZSM-5 zeolite prepared from soluble glass is better than that derived from the HZSM-5 zeolite prepared from silicon gel.

由水玻璃合成的HZSM-5分子筛制得的Mo基催化剂,其甲烷无氧芳构化性能优于由硅溶胶合成的HZSM-5分子筛制得的Mo基催化剂。

CH3OH could attack the phosphor atom in 1,3,2-dioxaphopholane of compiound (1) to give O-methyl O-hydroxyethyl-O-phthalimidoethyl thiophosphate in 85% yield; in the presence of potassium hydroxide aryl selenol could attack the carbon atom in 1,3,2-diox-aphopholane of the cyclic phospholipid conjugate of N^1-(2-furanidyl)-N^3--5-fluorouracil to give the corresponding product of ring-opening in high yields.

在室温下,以异丙醇作溶剂,苯硒酚与化合物2不反应。在氢氧化钾存在下,以异丙醇/水作溶剂(体积比20:1,在室温下,硒酚可以有效地进攻中化合物2中1,3,2-二氧磷杂环戊烷中的碳原子生成相应的开环产物。按照这一反应条件,顺利实现了硒酚对N^1-(2-呋喃基)-N^3-羟烷基-5-氟脲嘧啶硫代环甘油磷脂缀合物的亲核开环,生成甘油骨架的端碳原子上带有芳硒基新颖的磷脂核苷缀合物。

The joint toxicity was evaluated by different methods, including toxicity unit,additive index, similarity parameter and mixtures toxicity index. The results show that the binary joint effects of phenol and toluol mixed with SDS are synergistic, while the binary joint effect of SDS and nitrobenzene is antagonistic. The environment risk of some compounds will be enhanced because of the joint of SDS.

研究结果表明: 4种不同的评价方法对SDS与取代芳烃苯酚、甲苯和硝基苯的联合效应评价结果具有较好的一致性,即SDS与苯酚、甲苯的二元混合体系的毒性表现为不同程度的协同作用,而与硝基苯则表现为弱拮抗作用;对环境存在风险性的阴离子表面活性剂SDS,当与一些有毒有害物质共存时会增加该类物质的环境风险性。

1A series ofω-alkylmercapo acid were synthesized by two methods:one involved the reaction of the appropriateω-bromoalkyl acid with mercaptide under the presence of base;the other method was used only for the long alkyl compound by the reaction ofω-alkenyl acid and alkanethiol in the presence of AIBN.

正是基于以上考虑,本论文探索了合成下沿带有硫醚官能团,而上沿带有偶氮官能团的杯[4]芳烃衍生物的方法,进行了以下研究: 1采用ω-溴代羧酸和烃基硫醇在碱性条件下发生反应,或由ω-烯基羧酸和硫醇在AIBN的存在下反应,得到了ω-硫醚羧酸,使用氯化亚砜将羧酸转化为酰氯。

It was found that the alkoxy of the aluminium alkoxide can be exchanged to the arkoxy of the raw material or product in the process of reaction. The alcohol producing in the exchange reaction reduces the yield of furan phenol by the further by-reaction of the alcohol with the raw material or product.

结果表明,醇铝在催化单醚合成呋喃酚过程中,醇铝中的烷氧基与原料单醚和产物呋喃酚的芳氧基发生了交换,交换生成的醇与单醚或呋喃酚发生副反应降低了呋喃酚收率。

When the 3-keto glycosides was reduced by sodium borohydride, the D-allo configuration was considered the most probable since it has an equatorial arylamino group at C-2 position and reduction of the keto group was considerably less hindered to equatorial attack by borohydride ion to give an axial hydroxyl, than axial attack by borohydride to give an equatorial hydroxyl.

并对反应的立体化学问题进行了讨论,认为该反应的立体专一性是由于向下直立键上的1-位α-甲氧基和2-位向下平伏键上芳胺基大基团的共同影响,造成内侧进攻受阻,而使得氢负离子只能从外侧进攻的结果。

The introduces binaphthyl bisphenol monomer on side-chain benzene ring of sulfonic group on molecular level, prepares sulfonated poly aryl ether with sulfonic group only on naphthalene ring of side chain, so that ensures chemical stability of main chain with high molecular weight, while having no influence on mechanical property thereof.

本发明从分子水平出发,将磺酸基在侧链苯环上的联萘双酚单体引入,制备仅在侧链苯环上有磺酸基的磺化聚芳醚,从而保证了高分子主链的化学稳定性,且不会影响其优异的物理机械性能。

The condensation of aromatic aldehydes with active methylene compounds like malononitrile, cyanoacetamide and ethyl cyanoacetate has been found to proceed very efficiently at room temperature giving excellent yields, but the condensation of heteroaromatic,α,β-unsaturated and aliphatic aldehydes with active methylene compounds proceeded smoothly in 50~65℃ with good yields and the reactions of aromatic, aliphatic ketones as well as p-phthalaldehyde with malononitrile also proceeded in 75~85℃ with moderate yields.

芳香醛与活泼亚甲基化合物如丙二腈、氰基乙酸乙酯、氰基乙酰胺的缩合在室温下即能顺利进行,获得了很高的收率;而对于杂环芳醛、α,β-不饱和的醛以及脂肪醛与活泼亚甲基化合物的缩合,需在50~65℃下进行,也取得了很高的收率;对于脂肪酮、芳香酮以及二元醛与丙二腈的缩合在75~85℃下也能顺利地进行,获得中等以上的收率。

The intramolecular hydrogen bonding can extend the ligand planarity and increase the intercalative ability of the complex to DNA. It is concluded that the torsion between the aromatic rings of ligands, due to introduction of the bulky substituent, results in the complexes only to partially or non-classically intercalate into DNA.

能够使配体平面性增大的分子内氢键的形成,有利于配体对DNA的插入作用;但是,由大体积的取代基所引起的配体芳环间的扭转,致使配体只能&部分地&或&非经典地&插入DNA碱基对。

In addition, the invention further relates to a catalyzer combination used for polymerizing a conjugated dialkene monomer and the anions of an optional mono-vinyl aromatic hydrocarbon into a polydiene polymer having high and medium vinyl content. The catalyzer combination comprises an organolithium compound used as an anionic polymerization initiator, at least an alkali metal alkoxide compound expressed by the formula as a structure regulator.

此外,本发明还涉及一种用于将共轭二烯烃单体和任选的单乙烯基芳烃阴离子聚合成具有中高乙烯基含量的聚二烯聚合物的催化剂组合物,其包含作为阴离子聚合引发剂的有机锂化合物,和作为结构调节剂的至少一种式所示的碱金属醇盐化合物。

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However, as the name(read-only memory)implies, CD disks cannot be written onorchanged in any way.

然而,正如其名字所指出的那样,CD盘不能写,也不能用任何方式改变其内容。

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付款指令文件可从您的 ERP 系统上传到我们的电子银行系统来只是国内及对海外各种币种付款。