芳基

Poly with sulfonic acid groups were readily synthesized with biphenol and 1,3-bis(4-fluorobenzoyl)benzene in the presence of excess potassium carbonate followed by sulfonation with chlorosulfonic acid.

以二氯二苯甲烷和2，6-二甲基苯酚为原料合成了含有阻碍基团的双酚单体，用此双酚单体和1，3-二(4-氟苯甲酰基苯)在无水碳酸钾存在的条件下反应制得聚芳醚酮，然后用氯磺酸磺化，控制反应条件，使磺酸基团恰好进入苯环对位，制得新型结构的磺化聚芳醚酮。

A series of sulfonated poly(arylene thioether/ether phosphine oxide)s was prepared by direct polycondensation of sBFPPO and BFPPO with the diphenol-type or dimercapto-type monomers such as hydroquinone, bisphenol-A, 4,4'-biphenol, 4,4'-diphenol (6F), 1,5-dihydroxynaphthalene, 4,4'-dihydroxybiphenyl, and 4,4'-thiobisbenzenethiol, respectively.

将BFPPO与sBFPPO分别与多种二羟基或二巯基单体，如对苯二酚、双酚A、4，4'-二苯酚、双酚F、1，5'-二羟基萘、4， 4'-二羟基二苯硫醚和4，4'-二巯基二苯硫醚，直接共聚制备了一系列磺化聚芳醚三苯基氧膦，侧重考察了二羟基和二巯基单体结构单元对产物的耐氧化性能的影响。

Result showed that tetrasubstituted calix [4] arenes in lower rim were stronger complex abilities than bisubstituted calix [4] arene with transition metal, heavy metal and rare earth ions. But when introducing the aminephenolicalcohols in the 1, 3-bisubstituted calix [4] arenes, the complex abilities were improved.

结果表明：在Lower rim上四取代的杯[4]芳烃配体比1，3-二取代的杯[4]芳烃配体对过渡金属离子，重金属离子及稀土离子有更好的配位能力，但当1，3-二取代的取代基上引入醇胺链型配体时，对金属离子也有很好的配位能力。

By means of UV-vis spectrophotometer, the complex abilities of calix [4] arene ligands with metal ions were researched, and the effect of solvent systems was discussed.

使用紫外-可见分光光度法研究了杯[4]芳烃配体与金属离子的络合性质，并考虑了溶剂对配体与金属离子配位的影响，评价了杯[4]芳烃的不同取代基对过渡金属离子及稀土离子的配位作用。

Utilizing 6 and several kinds of diazides prepared in our lab, polys containing 1,2,3-triazolyl and perfluorocyclobutane units were synthesized by "Click chemistry". Utilizing the polycondensation reaction between 6 and several commercially available aromatic diphenol or copolymerization reaction after adding another active aromatic dichloride, fluorinated polys containing phenylphosphine oxide units were synthesized. Utilizing the polycondensation reaction between 6 and several commercially available aromatic dianhydride, fluorinated polys containing PPO units were synthesized.Secondly, structure characterization of fluorinated polys.

利用化合物6同各种自制的二叠氮化合物，通过&Click chemistry&，合成了具有1，2，3-三唑环结构单元的全氟环丁基类聚芳醚；利用化合物22同各种商业化的芳香二元酚类化合物进行缩聚反应或者再加入另外一种活性芳香二氯代物进行三元共聚反应，制备了具有苯基氧膦结构单元的含氟聚芳醚；通过化合物25同各种商业化的芳香二元酸酐类化合物进行缩聚反应，得到了具有PPO结构单元的含氟聚醚酰亚胺。

It was found that the thermodynamically unfavourable isomerization of quadracyclane to norbornadiene could be accomplished in the presence of toluene or durene as a co-sensitizer.

首次发现在甲苯、杜苯等芳烃共敏化下，可以使原来不能进行的、热力学不利的四环烷→降冰片二烯异构化得以进行，并根据CIDNP结果提出这是由于生成了敏化剂/底物/芳烃三元基激络合物使反应的势能面改变造成的并促进单线态的系间窜跃。

A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; and a mixture of two or more different selectivity control agents, said SCA mixture comprising from 1 to 99 percent of one or more esters of one or more aromatic monocarboxylic acids or substituted derivatives thereof, and from 99 to 1 percent of one or more alkoxysilane compounds.

一种用于丙烯聚合的催化剂组合物，包括：一种或多种齐格勒-纳塔主催化剂组合物，该齐格勒-纳塔主催化剂组合物包括一种或多种过渡金属化合物和一种或多种芳族二羧酸酯内部电子给体；一种或多种包含铝的辅催化剂；和两种或更多种不同的选择性控制剂的混合物，所述SCA混合物包括1到99％的一种或多种芳族单羧酸的一种或多种酯或其取代衍生物、和99到1％的一种或多种烷氧基硅烷化合物。

The Suzuki reaction, the coupling of organoborate compounds with organic electrophiles catalyzed by Palladium complexes, is a valuable Csp2-Csp bond forming reaction. The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of phenylboronic acid with benzyl halides catalyzed by Pd(PPh3)2Cl2 DMF/H2O(v/v=10 : 2) was first reported.

第四章：微波辐射下Pd配合物催化端烯与芳卤偶联反应研究本章中我们在微波辐射条件下，研究了PdclZ(P Ph3)：催化端烯与芳卤的偶联反应，合成出了七种乙烯基化合物；并分别考察了微波辐射功率、辐射时间、原料配比、和PTc等因素对反应的影响，优选出了较佳的反应条件，并根据文献及实验结果，讨论了可能的反应机理。

Generally, these compounds are derived from accessible α–oxoketen dithioacetals and the common methods of preparation involve regioselective sodium borohydride 1,2-reduce of α–oxoketen dithioacetals, 1,2-nucleophilic addition of organomatals such as organomagnesium, organolithium, Reformatsky regent to α–oxoketen dithioacetals, Baylis-Hillman reaction between polarized ketene dithioacetals and aldehydes.

主要方法包括：使用硼氢化钠1，2-选择性还原α-羰基二硫缩烯酮；利用有机金属化合物（如有机镁试剂，有机锂试剂，Reformatsky试剂等）对α-羰基二硫缩烯酮进行1，2-亲核加成；通过α-羰基二硫缩烯酮与芳醛进行Baylis-Hillman反应等获得。

The toxicity of selected compounds and their binary mixtures of sodium dodecyl sulfate with three substituted aromatic compounds to photobacterium phosphoreum was investigated, respectively.

研究阴离子表面活性剂十二烷基硫酸钠和苯酚、硝基苯、甲苯3种取代芳烃对发光菌的单一毒性，以及在等浓度配比条件下，SDS与这3种取代芳烃二元混合体系的联合毒性效应，并采用毒性单位、相加指数、相似性参数和泥合毒性指数进行毒性评价。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。