芳基

The pigments synthesized from 2, 7-diaminoflurenone consistently show better photosensitivity than that containing anthraquinone. A plot of the E1/2 values against the Hammett constant σ was obtained for the pigments which have different substituents in the anilide ring. The plot reveals that neither a strong electron-releasing group, such as methoxy, nor a electron-withdrawing group, such as nitro-group, enhances the sensitivity of the photoreceptor in which these pigments are used as CGL materiel.

芴酮类偶氮染料的光敏性优于蒽醌类偶氮染料，其偶合基酰胺芳环取代基为强的给电子基团或强的吸电子基团时都不利于其光敏性的提高，只有当取代基基团为氯时其表现出最好的光敏性，这一结果与Law等人的研究结果相同。

In this paper, the study progress of rhodamine dye type in recent years and the reaction mechanism and the methods of aryl methyl oxidation to the fragrant aldehyde group were firstly introduced.

在本论文中，首先介绍了近年来罗丹明类染料的研究进展和芳甲基氧化生成芳醛基的反应机理、方法。

In one embodiment, the invention is a system for initiating free radical polymerization comprising: a in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms and optionally containing one or more heteroatoms or heteroatom containing functional moieties, and one or more cationic counter ions and b in a second part, a liberating compound which reacts with the nitrogen atom bound to the boron atom upon contact with the amido-borate to form an organoborane radical.

在一个实施方案中，本发明是引发自由基聚合的体系，包括：a在一个部分中，一种或多种含有一个或多个包含有机硼酸根的阴离子酰氨基-硼酸盐部分和一个或多个阳离子抗衡离子的酰氨基-硼酸盐化合物，其中的硼原子键合到氨的氮原子或含一个或多个氮原子的有机化合物，例如烃基胺、烃基聚胺或含一个或多个氮原子和任选含一个或多个杂原子或含杂原子的官能部分的芳族杂环的氮原子上，和b在第二部分中，在与酰氨基-硼酸盐接触时与键合到硼原子上的氮原子反应形成有机硼烷基团的释放化合物。

Nitrations of both hydroxyl- and acetamino-substituted porphyrins were found to take place at the adjacent position of the substituent in the very aryl ring, whereas nitro group was guided into para positions of unsubstituted phenyl ring during the nitration of nitro-substituted porphyrin.

结果表明，羟基和乙酰氨基卟啉的硝化反应发生在与该取代基处于同一芳环的meta位，而硝基卟啉进行硝化时，硝基取代于其他未取代苯环的para位。

The Molar conductivity indicates that all the complexes are nonelectrolyte. IR spectra show the ligand is bonded with RE ion through its oxygen atom in hydroxyl group of phenol; NO3 is coordinated as a symmetrical chelating bidentate group; the coordinated atoms of DMF and DMSO are the oxygen atoms in carbonyl and sulfoxyl groups. Fluorescence spectrum suggests that the Tb3+complexes have characteristic luminescence and its fluorescence intensity is enhanced after doping with La3+, Gd3+, Y3+, influence of doping ions and neutral ligands have also been discussed.

摩尔电导率表明，所有配合物均为非电解质；红外光谱及核磁共振氢谱表明，对叔丁基杯[8]芳烃通过酚羟基的氧原子与稀土离子配位；硝酸根为双齿螯合配位；DMF和DMSO则分别通过羰基氧和亚砜基氧与稀土离子配位；配合物的荧光光谱表明，所有Tb的配合物具有较强的特征荧光，掺杂La~(3+)、Gd~(3+)、Y~(3+)离子对Tb~(3+)的荧光有较强的增强作用。

Reaction of NaOAr, SmCl_3 and aryloxo-functional N-heterocyclic carbene precursor [HO-4, 6-di-~tBu-C_6H_2-2-CH_2{CHMe}]Cl in 4:1:1 molar ratio in THF in one-pot hadnt afforded an anionic phenoxide complex of samarium (5) supported by a bridged bisphenoxo through the cleavage of aryloxo-functional N-heterocyclic carbenes.

4将NaOAr、SmCl_3和[HO-4，6-di-~tBu-C_6H_2-2-CH_2{CHMe}]Cl以4∶1∶1摩尔比，采用一锅煮的方法，希望得到芳氧基功能化的氮杂环卡宾稀土芳氧配合物没有取得成功，而是得到了断裂的产物O-4，6-di-~tBu-C_6H_2-2-[CH{NNMe}[(O-4，6-di-~tBu-C_6H_2)_2CH_2][O-2，4-di-~tBu-C_6H_3]Sm(5)。

In this thesis, we want to describe the new one-carbon and three-carbon chain extension and ring expansion of 2-aroyl-3,4-dihydro-2H-naphalen-l-one, which is the first report based on our knowledge.

本文在前人的研究基础上，首次开展了α—芳酰基苯并环己酮增加一个碳原子和三个碳原子的自由基扩环和链增长反应，以及自由基加成成环反应。

O-(1-Arylseleno-3-azido)isopropyl-O-2-(N3-tegafur)alkyl thiophosphate (3a～3f) were obtained via nu-cleophilic ring-opening of sodium azide to 2a～2f in dry DMF at room temperature, and their antitumor activities were tested.

以无水N，N-二甲基甲酰胺作溶剂，室温下，叠氮化钠中对2a～2f进行亲核开环，得到O-(1-芳硒基-3-叠氮基)异丙基-O-2-(N3-替加氟)乙基硫代磷酯。

The results show that the urushiol dimer has the similarstructure with this compound.Therefore,we concluded that thestructure of alkyl phenyl ether is main structure formed in urushiolpolymerization.

合成并用2D—NMR方法研究了烷基芳醚化合物：2—丁基苯醚此化合物的NMR数据进一步确证了烷基芳醚型漆酚二聚体的存在。

Making use of this reaction, thirteen methyl 2-arylamino-2-deoxy 3-keto glucopyranosides (5～17) with different substituted arylamino groups and two

选择不同类型的芳胺利用该反应合成了一系列共十三种2-脱氧2-芳胺基3-位氧化α-甲基D-葡萄糖苷（5～17），该类化合物为重要的手性合成子。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。