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The toxicity of selected compounds and their binary mixtures of sodium dodecyl sulfate with three substituted aromatic compounds to photobacterium phosphoreum was investigated, respectively.

研究阴离子表面活性剂十二烷基硫酸钠和苯酚、硝基苯、甲苯3种取代烃对发光菌的单一毒性,以及在等浓度配比条件下,SDS与这3种取代烃二元混合体系的联合毒性效应,并采用毒性单位、相加指数、相似性参数和泥合毒性指数进行毒性评价。

But under the same conditions, the reactions of the complex (41) with organic lithium reagents give a kind of novel complexes in which the nucleophile is added to the a-carbon of the phthalazine ring.

然而含有桥羰基的2,3-二氮杂萘配位的羰基双铁络合物4l在相同的条件下与基锂试剂反应时,基锂却是亲核加成在氮杂环的α位羰上,生成一类结构独特的双氮双铁羰基络合物。

To explore new synthetic methods, we set out a careful investigation of the reaction of benzimidazolium salt with many nucleophilic agents, including the active aromatic compounds and heteratom nucleophilic agents, and found that the quaternary C=N is not so active; when benzimidazolium salt is reacted with big nitrogen nucleophilic agent? phthalimide, it does not give the expected addition product, instead, produces N-alkyl phthalimide through alkyl-transfermation from benzimidazolium salt to phthalimide.

为了开发新的合成方法,研究了苯并咪唑盐与各种亲核试剂(活泼环与杂原子亲核试剂)的反应,发现苯并咪唑盐不与活泼环及杂原子亲核试剂发生2位加成反应;在与体积较大的位阻型N亲核试剂邻苯二甲酚亚胺反应时,未得到亲核试剂与极化的C=N的加成产物,而是得到N烷基化的邻苯二甲酰亚胺,进一步研究表明,苯并咪唑盐将1(3)位N上的烷基转移给了邻苯二甲酰亚胺,并讨论了其反应机理和取代基,溶剂效应。

However, research on polycyclic aromatic hydrocarbons in the environmental medium within the industrial area has not been reported yet.

目前国内外对环境中的多环烃已开展了较多的研究,但有关工业区环境介质中的多环烃研究尚未见报道。

The corresponding thiochromanones were synthesized from β-arylthioethers of propionic acid under microwave irradiation in the presence of polyphosphoric acid. Their structures were confirmed by IR, 1H NMR, MS spectra and elemental analysis.

关于这些化合物合成曾有一些报道:以硫酚及卤代羧酸为原料在回流或超声作用下合成β-硫丙酸,硫丙酸在浓硫酸或磷酸作用下环化制备硫色满酮[1,2]。

In this paper, twenty novel meso-substituted porphyrins of four series were designed and synthesized by increasing the conjugation of porphyrins or introducing substituents with high fluorescence quantum yield into the meso-position of porphine, and then red OLEDs were fabricated by doping porphyrins into a suitable host using ten porphyrins compounds and their electrolumin -escence properties were tested. The main contents and results were generalized as follows:Three meso-tetrakisporphyrins 4a-c and three conjugations of porphine-triarylamine linked by styrene 10a-c were synthesized and characterized by 1H NMR, MS, UV-vis spectra and fluorescence emission spectra.

本文通过增大卟啉分子的共轭结构或将具有高荧光量子产率的基团连接到卟吩环的中位得到了四类共20个新型的卟啉化合物,并选取其中10个化合物制备有机发光器件来考察材料的电致发光性能,具体内容包括以下几个部分:设计合成了3个中位直接被三胺取代的卟啉化合物4a-c和3个通过苯乙烯连接的卟吩-三胺共轭体10a-c,通过核磁氢谱、质谱、紫外吸收光谱和荧光发射光谱表征了新化合物的结构。

Besides, we firstly confirmed at the molecular level that P450arom may play an important role in the natural sex change of protandrous fish and revealed that up-regulation of the transcript levels of P450arom during the course of natural sex change of black porgy is not regulated via FTZ-F1.;sturgeon sex related and sex linkage genes by candidate gene approach and suppression subtractive hybridization technique and expression patterns of these genes were also studied.

首次直接在分子水平证明香化酶基因可能参与了雌雄同体鱼类性别逆转的调控,而黑鲷性别逆转期卵巢中香化酶的表达量上调不是由FTZ-F1基因调控的;同时主要利用候选基因法和抑制差减杂交搜寻史氏鲟性别决定或性别特异性基因,并研究其表达情况。

The structure characters of this kind of molecules were discussed. The results show that the phenyl group located in the 4- or 5- position of pyrryl ring are not coplanar with the pyrryl ring.

对这类吡咯环上4或5-位有环取代基时化合物的晶体结构特征进行了扼要讨论,晶体衍射实验结果表明,4, 5-位上的环与吡咯环本身处于非共平面结构。

Autocorrelation topological study on the acute toxicities of substituted aromatic compound s;2. The autocorrelation topological researches on slow and acutetoxicities of substituted aromatic compound s to scenedesmus ubliquus, rat and so on;3. Results show that the SW and KOW of the substituted aromatic compound s could be better forecasted at AM1 level.

应用分子力学方法MM+和半经验量子化学AM1、MNDO和PM3法得到了54种取代烃的优势构象,在此基础上结合分子图形学技术,获得相应优化构象的电子结构参数和几何结构参数,并将这些参数与取代烃的辛醇/水分配系数和溶解度相关联。

Evaluation of some Mannich bases of conjugated styryl ketones and related compounds versus the WiDr colon cancer in vitro.

朱志宏,徐秀娟。2,4-二羟基-3-氨基甲基苯乙酮和8-乙酰基-3-基-3,4-二氢-5-羟基-2H-1,3-苯并噁嗪的合成及其相互转化。

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But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊!不用提了。提到肉,真是糟透了。

Tristan, I have nowhere to send this letter and no reason to believe you wish to receive it.

Tristan ,我不知道把这信寄到哪里,也不知道你是否想收到它。