色烯

One of them can efficient catalysed the alkene in the absence of dear additives by introducing an imidazole in the salen ligand.

其中分子内含咪唑的手性吡咯烷Mn催化剂成功实现了不加昂贵添加剂的情况下高效催化取代色烯环氧化反应。

The relation of the chromatographic retention indices of alkene to topological index,double bond atomic hybridization state index,polarizability effect index of branched chain to double bond atomic,immobile liquid polarity values and column temperatureat different temperatures on different stationary phases was studied.

通过对部分烯烃在不同固定相不同柱温下的1031个样本集的气相色谱保留指数值与其部分参数关系的研究，发现RI与拓扑指数、双键原子杂化状态指数、支链对双键的极化效应指数、固定液极性值及柱温的关系可表示为：^RI=-58.138+57.7460Q-8.2591Q+0.120T+0.807CP+36.460PBD+7.919DHSI(R=0.9989)继以留一法(Leave-one-out，LOO)进行交互检验，相关系数RCV=0.9977，说明所建模型具有良好的稳定性和预测能力，较好地揭示了烯烃类化合物气相色谱保留指数RI随固定相极性、柱温的改变而变化的规律

The results show that there is excellent linear relationship between solute-related parameters and retention indexes for the saturated hydrocarbon, olefine and diene compounds on different polar chromatographic stationary phases.

结果表明：烷烃、烯烃、二烯烃类化合物在不同极性的色谱柱上的色谱保留与其分子结构描述参数之间具有较好的线性关系，烃类化合物在不同极性固定相上的保留主要与溶质分子的MR有关，即与溶质分子的色散力有关。

N,N-dimethyl-N'-(2-trifluorometyl-1-pentafluoroethyl) perfluoro propenyl propane diamine and N,N-dimethyl N'-(2-trifluorometyl-1-pentafluoroethyl) perfluoro propene propane diamine were prepared by the reaction of hexafluoropropene dimer and N,N-dimethyl propanediamine in the molar ratio 1:1.0 at about 35℃for 8h, and the structures of I were identified by IR and NMR spectra.

本文以六氟丙烯二聚体和N，N-二甲基丙二胺为主要原料合成了两种含氟中间体叔胺——N，N-二甲基-N'-(2-三氟甲基-1-五氟乙基)全氟丙烯基丙二胺和N，N-二甲基-N'-(2-三氟甲基-1-五氟乙基)全氟烯丙基丙二胺，用薄层色谱和柱色谱等方法对产品进行分离提纯，并运用红外光谱和核磁共振等分析手段对其结构进行了表征。

These observations suggest that PVA-MEC is an excellent fluorescent macromolecular material with a convenient method of preparation and had a good water-soluble ability.(2) An acrylic monomer bearing xanthene group, acryloyl-fluorescein was synthesized from fluorescein and acryloyl chloride. The photophysical behaviors of Ac-Flu and its copolymer were explored by recording the fluorescence spectra in solution, solid state and film in detail.

2我们采用基于荧光功能单体制备荧光聚合物的方法，选择荧光素为发色团，使它与丙烯酰氯反应，合成出含有双键的荧光素单体Ac-Flu，然后令其与丙烯酰胺共聚，制备得到含有荧光素生色团的水溶性荧光聚合物poly(Ac-Flu-co-AM)。

Synthesis and application of formaldehyde-free dye-fixing agent ENF;2. Chlorine-resistant reactive dye-fixing agent CRS was prepared by mixing polyamine CS and polymer CR synthesized by dimethyldiallyl-ammonium chloride and allylamine.

文章以二甲基二烯丙基氯化铵和烯丙基胺为原料合成聚合物CR，与胺类聚合物CS复配制备活性染料耐氯固色剂 CRS，用于棉活性染料染色布固色整理，研究其耐氯性能。

To study the bioactive components from water soluble extract of the Chinese eaglewood, various column chromatography of Chinese eaglewood led to the isolation of ten compounds. Their structures were elucidated as 2,3-bis(3-hydroxyphenyl)- propan-1-ol (1), [(2R,3R)-3-(4-amino-3,5-dimethoxyphenyl)oxiran-2-yl]methanol (2), 8-chloro-4'- methoxy-5,6,7,3'-tetrahydroxy-2-(2-phenethyl)-5,6,7,8-tetrahydrochromone (3), 4'-methoxy-5,6,7,3'-tetrahydroxy-2--5,6,7,8-tetrahydrochromone (4), the isomer of 4 (5), 4'-methoxy-5,6,7,8-tetrahydroxy-2-(3'-hydroxyphenethyl)-5,6,7,8- tetrahydrochromenone (6), 4'-methoxyisoagarotetrol (7), 6-hydroxy-2-(2-hydroxy-2- phenethyl)-chromone (8), 6-hydroxy-2-(2-phenethyl)-chromone (9), 6-hydroxy-2-(4'- hydroxy-2-phenethyl)-chromone (10), and Guaiacylacetone (11) by means of spectral analysis and comparison with references.

为了进一步发现沉香中具有生理活性的化学成分，本文对国产沉香的水溶性成分进行了研究，从中分离得到11个化合物，通过红外、紫外、质谱、核磁共振(1H-NMR， 13C-NMR， COSY， HSQC， HMBC， ROESY)波谱解析，分别鉴定为：2，3-二(3-羟基苯基)-丙-1-醇(1)，[(2R，3R)-3-(4-氨基-3，5-二甲氧苯基)-2-氧化烯基]甲醇(2)，8-氯-4'-甲氧基-5，6，7，3'-四羟基-2-(2-苯乙基)-5，6，7，8-四氢色原酮(3)，4'-甲氧基-5，6，7，3'-四羟基-2-(2-苯乙基)-5，6，7，8-四氢色原酮(4)，化合物3的差向异构体(5)，4'-甲氧基-5，6，7，8-四羟基-2-(3'-羟基-2-苯乙基)-5，6，7，8-四氢色原酮(6)，4'-甲氧基异沉香四醇(7)，6-羟基-2-(2-羟基-2-苯乙基)色原酮(8)，6-羟基-2-(2-苯乙基)色原酮(9)，6-羟基-2-(4'-羟基-2-苯乙基)色原酮(10)和Guaiacylacetone (11)。

Has been isolated and identified, by MS-GC, 27 compounds of which main consti tuents are 1,8-cineol, comphor, pinene, terpinol, cabinene, terpinene, tert-buty- penZene, phellandrene, coaryphyllene, sabinene.

河南辛夷的挥发油，通过气相色谱—质谱分离鉴定出27个成份1.8按叶素、樟脑、蒎烯、松油醇、杜松烯、松油烯、特丁基苯、菲兰烯、丁香烯、桧烯为其主要成份。

The enhancement of the reaction activity is attributed to the phasetransfer capability of the built-in quaternary ammonium and pyridinium salts of theMn catalyst.

分子内季铵盐和吡啶盐具有相转移能力，对于取代色烯不对称环氧化的作用与外加的吡啶盐和卤化铵的作用相似，使Mn催化剂催化取代色烯环氧化反应的活性明显提高。

The enhancement of the reaction activity is attributed to the phasetransfer capability of the built-in quaternary ammonium and pyridinium salts of theMn catalyst. The effect of the internal quaternary ammonium and/or pyridiniumsalt on the epoxidation of substituted chromenes is similar to that of the externalpyridinium salts and ammonium halides.

分子内季铵盐和吡啶盐具有相转移能力，对于取代色烯不对称环氧化的作用与外加的吡啶盐和卤化铵的作用相似，使Mn催化剂催化取代色烯环氧化反应的活性明显提高。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。