致密的

Experimental study of high temperature phase transformation for pyrophyllite

利用场发射扫描电镜表征了Zr-Co粉体的形貌特征和烧结后的陶瓷薄膜结构，热重分析了Zr-Co粉体烧结过程的失重和相转变吸放热过程，X射线衍射分析跟踪了不同温度段烧结体系的组成变化趋势，在此基础上对粉体烧结后陶瓷薄膜的防氧化效果进行了分析，结果表明：温度对粉体的颗粒形貌和晶相结构有较大的影响，高温烧结的粉体性质稳定，经过1200℃烧结后的陶瓷膜层具有很好的致密性，具有很好的防氧化效果。

The results show that a MgSnO3·H2O conversion film is formed by treatment in the stannate solution at 90℃, and the immersion test and potentiodynamic polarization show that the corrosion resistance of the AZ91D alloy is improved to some extent.

结果表明：锡酸盐转化处理后合金表面形成了以MgSnO3·H2O为主要成分的转化膜，可对合金起到一定的防护作用；转化膜由细小的球形颗粒密积而成，颗粒之间存在间隙，它可以为化学镀镍的前处理过程提供良好的吸附条件；转化膜上的化学镀镍层组织致密、无缺陷， MgSnO3·H2O转化膜在镀镍层与基体之间起到过渡作用，镀层的磷含量达到9%，与基体结合良好；在3.5% NaCl (pH=7)溶液中的动电位极化测试表明，镀镍以后的合金在阳极极化过程中发生了明显的钝化，耐腐蚀性能进一步提高，对基体起到了较好的防护作用。

The results showed that the TiN andN films are polycrystalline phase. The properties and structure of TiN films are mainly determined by the N2 mass flow rate, and as the N2 mass flow rate increases, the structure of the TiN films transforms to f.c.c. type leading to better the properties of films. The presence of negative bias voltage can optimize the grain of TiN films, lower the defect proportion and denser the films, which improves the hardness of films. The TiN films conform to the free carrier absorption mechanism and there are many of free electrons with lower N content in TiN films. With the increase of N content, the quantity of free electrons and reflectivity of films decrease, and the plasma frequence shifts to the lower energy, which leads to the regular change of colors of films from silver, yellowy, golden to yellow-red, meanwhile the lightness of films decreases. The goldenN film consists of TiN and ZrN phase, but belongs to a sigle f.c.c. structure with (111) preferred orientation. The Zr-doping dosen't change the position of the valance band, conduction band and forbidden band ofN film, but leads to the presence of new energy levels, which is the reason thatN film remains golden. The transparent hard films with good corrosion resistance and high hardness have been prepared and the further reseachs showed that the grain size of those films is by far smaller than the wave length and the width of forbidden band of those films is very broad, is the reasons that those films are transparent.

研究表明：氮化钛和N 薄膜为多晶态，氮流量决定了氮化钛薄膜的结构和性能，增加氮流量能使氮化钛薄膜的结构向面心立方结构转变，从而得到性能良好的氮化钛薄膜；施加负偏压能优化氮化钛晶粒和减少薄膜中的缺陷，使膜层变得更致密，从而提高薄膜硬度；氮化钛主要遵循自由载流子光吸收，氮含量较少时薄膜中的自由电子数目较多，随着氮含量的增加，薄膜中的自由电子数目不断减少，反射率逐渐降低，等离子体频率向低能端移动，从而使薄膜颜色出现规律变化，由金属色银白色到淡黄、金黄再到红黄，并且薄膜亮度呈下降趋势；金黄色的N 薄膜中存在TiN 和ZrN 的分离相，但其为单一的面心立方结构并具有(111)面择优取向；相对于TiN 薄膜，Zr 掺杂后，并没有使薄膜的导带、价带和禁带发生变化，只是在TiN 禁带内增加了新能级，这也正是掺杂Zr 后，薄膜仍

The adding of anatase nano-crystalline TiO_2 to the deposition solution accelerates the depositing of TiO_2 articles from the deposition solution on the silica glass fiber. A well-combined and durable TiO_2 thin film on silica glass fibers surface obtained by controlling the deposition temperature, deposition time, deposition cycles, concentration of the deposition solution, relative concentration of the deposition materials, pH value of the deposition solution. The effect of the deposition conditions, the drying conditions and the annealing treatment conditions on the surface morphology, section morphology, growth patterns, thickness of the deposited TiO_2 thin films were investigated. Growth rate and particle size of the thin films were controlled by the deposition conditions.

实验结果表明加入微量的锐钛矿型纳米TiO_2诱导晶可以使沉积液中析出的TiO_2粒子更大程度的以锐钛矿型纳米TiO_2粒子的形式析出；通过对沉积温度、沉积液中组分浓度及相对浓度、沉积溶液的pH值的调节与控制，从而控制沉积溶液中化学反应平衡的移动，研究了以上条件对沉积速率、沉积溶液中[Ti6]2–与—OH、[Ti6]2–之间的脱水聚合反应速率的影响，总结出了获得均匀致密质量较好的TiO_2薄膜的一系列实验参数，并对薄膜的生长模式进行了系统的分析研究；通过对沉积时间及沉积次数的分析，可以有效的控制TiO_2薄膜的厚度及质量；通过对薄膜的干燥条件及热处理条件的控制，可以使利用液相沉积法获得的TiO_2薄膜进一步晶化；并分析了对薄膜引起缺陷的主要原因。

XRD and EDS analysis indicate that at static condition, the composition of the scale is CO3, while the scale changes to CO3 at dynamic conditions. The increment in flow rate increased the thickness of the scale remarkably, but had little influence on the hardness and Young's modulus of the scale. The fracture toughness of the scale exhibited the lowest value at the flow rate of 0.5 m/s whereas the adhesion strength increased with increasing the flow rate.

结果表明，静态条件下形成的腐蚀产物膜的主要成分为CO3，动态条件下的主要成分为CO3；介质的流动能够促进腐蚀产物膜的形成，但对膜的硬度以及杨氏模量影响不大；腐蚀产物膜的断裂韧性随着流速的增大先下降后上升，流动状态下内层腐蚀产物膜的致密性较好，膜与基体的结合强度较高。

The results of electrochemical measurements indicated that in the presence of indomethacin powder it slightly increased the corrosion rate of copper if pH of the fluid was not under control and it did not change the corrosion rate if the pH was daily adjusted to maintain constant roughly. The experimental results for medication by indomethacin releasing silastic were basically the same as those with powdery indomethacin.

结果表明在不调整介质pH的情况下，由于消炎痛有使介质pH降低的作用，因此使铜的腐蚀速度略有上升；在调整模拟宫腔液的pH保持恒定的情况下，消炎痛几乎不影响铜的腐蚀速度；通过消炎痛缓释硅橡胶加药的实验结果与直接加药基本相同；在模拟宫腔液中，添加消炎痛具有促使铜的腐蚀产物中不溶性产物Cu〓O膜生成的作用，消炎痛使Cu〓O生成的量增加且致密。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。