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The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.

通过Diels-Alder环加成反应,用茚〓和1,1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物,发现可控制反应条件,使1,1'-联茚与〓反应,并高产率地得到具有新颖结构的单加成物,用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征,测得它的两个〓杂化的桥头碳的化学位移为〓ppm,证明生成的衍生物为6∶6闭式环加成,〓NMR谱中共给出38个信号,表明〓联茚衍生物分子具有〓对称性;在波长532nm,脉冲宽度8ns的激光下,〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近,由于〓联茚单加成衍生物熱稳定性好,在四氢呋喃,丙酮等极性溶剂中溶解性好,能分别均匀地掺入溶胶-凝胶中,已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能;使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究,通过等温压缩曲线测试,证明浓度为〓〓时,〓联茚衍生物能够形成单层膜。

The film of YTF-1 had advantages of coating transparency, removability, low-temperature adhesion, low temperature flexibility, high temperature flow, water immersion resistance and ultraviolet ray resistance.

研究结果表明:YTF-1防锈剂具有良好的可喷涂性、可渗透性和人造海水置换性,防锈剂膜层具有优良的透明性、可去除性、低温结合力、低温柔韧性、抗高温流动性、耐水性及抗紫外老化能力。

After the application of 100μ M linopirdine to OHCs, the peak K+ current was reversibly blocked and the late K+ current was partly reduced. In addition, the decay time constant of the TEA-sensitive K+ current was prolonged in the presence of 100μ M linopirdine. The inward current in OHCs was totally inhibited after the superfusion of 100μ M and 200μ M linopirdine respectively.

结果发现,在正常细胞外液中,单离外毛细胞可记录到四乙基二乙胺敏感的外向性钾电流和静息膜电位附近激活的内向性钾电流( the K+ current activated at negative potential, IKn)两种钾电流,而单离Deiters细胞中只记录到外向整流性钾电流。

These include inflammatory arthritides such as rheumatoid arthritis, ankylosing spondylitis and reactive arthritis,99 101 synovial impingement,meniscoid entrapment, chondromalacia facetae, pseudogout,synovial inflammation, villonodular synovitis, and acute and chronic infection.102 106 Intrafacetal synovial cysts can be a source of pain because of distension and pressure on adjacent pain-generating structures, calcification,and asymmetrical facet hypertrophy.107 110 In a retrospective review of MRI scans in 303 consecutive patients with LBP, Doyle and Merrilees111 found that9.5% had facet joint synovial cysts, the large majority of which were located posteriorly.

包括炎症性关节炎如类风湿性关节炎,强直性脊柱炎及反应性关节炎等,还有滑液撞击,关节软骨版卡压,关节面软骨软化,假性痛风,滑液炎症,绒毛结节性滑膜炎和急慢性感染。小关节内滑囊囊肿可由于拉伸和压缩临近的疼痛发生结构,骨化及不对称关节增生等原因引起疼痛。在一项303例连续患者的MRI研究中,Doyle 和 Merrilees发现其中9.5%存在小关节囊肿,大部分发生于关节囊后部。

Chickens colibacillosis is a focus or systemic infectious disease, which is caused by E.coii ,with complicated antigens, multiple serotype and various clinical symptoms such as salpingitis, synovitis, and so on. Colibacillosis often happens together with various diseases and has been spread everywhere in Haian county in different extent..

鸡大肠杆菌病乃是由大肠埃希氏菌所引起的局部或全身性感染的疾病,其抗原性复杂,血清型多样,临床症状和病理变化多变,包括大肠杆菌性败血症、大肠杆菌性肉芽肿、气囊炎、肿头综合症、腹膜炎、输卵管炎、滑膜炎、全眼球炎及脐炎、卵黄囊炎等。

The location and structures of sex-pheromone-producing gland in female H.insularis were studied by EAG,GC,SEM,and TEM.These studies showed that thegland situate in the intersegmental membrane between the eighth and ninthabdominal segments,and is an eversible abdominal fold;Many plump cones disturbon the surface of the gland.The glandular cells of 2-day old virgin female H.insularis are arranged in one layer,among which the central cells are columnarepithelial cells and flat on two sides.The nucleus is irregular elliptical.There isevident conjugation between cells and the involution is more in the basal membraneof cell.Microvilli are distributed on the cytoplasmic membrane and linked withendocuticle on which there are many layers of chitin,and the outer cuticule is staineddeeper.The cell contains bubbles,mitochondria,glycogen deposits,roughendoplasmic reticulum and smooth endoplasmic reticulum.

结合触角电位、毛细管气相色谱、扫描电镜、透视电镜等技术对小线角木蠹蛾雌蛾腹尖末端不同组织部位提取物的测定分析以及腺体位置和形态结构的观察发现:小线角木蠹蛾性信息素分泌腺位于腹部末端8~9节之间,是一个由节间膜特化而成的上皮结构,为一可外翻的腹褶,腺体表面分布着饱满的锥形体,羽化后2天未交尾的雌蛾腺体细胞呈单层排列,腹面中央由密集的柱形上皮细胞组成,细胞排列向两侧延伸至背部,其形状由柱形逐渐变为扁平形,细胞核为椭圆形,细胞与细胞间有明显的胞连接,细胞基底膜基褶较多,质膜上分布着微绒毛,并与内表皮连接,内表皮上有多层几丁质,外角质层染色较深,细胞质中含有空泡、线粒体、脂质粒、粗面内质网和光面内质网。

objective to observe the treatment effect of dated tibia fracture by ao anatomizeness armor plate and planting bone.methods to make the arc-shaped cutting on the front outboard of shank,then getting diaplasis and redress the abnormality fracture,setting ao anatomizeness armor plate on the faultage of bone and taking the alveolus of oneself plant there.results the 16 cases got rectification of fracture.all cases got concrescence and the function of broke limbs recover well.the time of getting rid of fixation average 13 months.conclusion it is a credible and effective method that treatment of dated tibia fracture by ao anatomizeness armor plate and planting bone.

目的 观察用ao解剖钢板内固定加植骨术治疗陈旧性骨折的疗效。方法在持续硬膜外麻醉下,取胫骨前外侧弧形切口,复位、纠正骨折畸形,ao解剖钢板固定骨折断端,取自体骨移植于骨折间隙或骨质缺损处。结果 16例患者骨折畸形均纠正,骨折全部愈合,患肢功能恢复良好,内固定去除时间平均为13个月。结论 ao解剖钢板内固定加植骨术治疗陈旧性胫骨骨折是一种可靠、疗效肯定的治疗方法。 ao解剖钢板;自体骨移植;胫骨陈旧性骨折

The above production operations to undergo a rigorous control of detection, the ink attachment fastness of general usage requirements can be achieved, but because the milk membrane business card printing and membership card making, as printed on the table, that is, the surface of the ink in the film, is vulnerable to all kinds of injury, and water, acid, machinery, more or less friction will cause ink wash after wash, moreover, milk is in the filling is completed, are generally intended to be appropriated for cold storage of 4 ° c, milk from the inside out, the film surface as a result of alternating hot and cold, dew will be generated, in transit, bags and bags into as a result of vibration between, in the hands of consumers, and some of it will be on milk heating drinking, such a procedure requires ink has both a very good resistance to freezing, resisfance, thermotolerance and crocking performance and this envirogluvtm products in production is very difficult, so far, no inks contain all the characteristics of these four.

以上出产上各道工序不纬功澈底把持的检测后,油不朱的附着牢度凡是可以到达搁置请求,但由于奶膜的制卡和会员卡制作为边印,即油不朱在不厚膜的暗地,容难受到百般保养,火、酸、板滞、磨擦或多或少城市引起油不朱的掉色,况且,牛奶在灌装完不败后,凡是都需放出4℃的冷藏室冷藏,牛奶从冷藏室拿不出来后,不厚膜暗地由于冷冷瓜代,会爆不收结露不隐象,在输送途洋,袋与袋之间由于波动爆不收磨擦,到了出产者手边,有的还需差牛奶增冷饮用,这样一个功程不离请求油不朱同时具有不一不合精良的抗冷冻、耐火性、耐冷性和耐磨擦本能机能,而这样的油不朱产物在出产洋是不一不合艰难的,到目后为止,也操纵一栽油不朱能合座敷裕以上四栽共性。

The results showed that the electrolytic leakage of membrane was amplified, andthe content of MDA were accumulated in Rosa chinensis var floribunda under hightemperature stress.

霍尔恩瓮栽苗均表现出膜相对透性和MDA含量持续增大,表明细胞受到明显的伤害,膜脂过氧化程度不断加剧,同时SOD、CAT活性先降后升再下降,POD活性先降后升,APX活性先降后升再下降。

Some materials scaleslinearlywith, ink adhesion of close, if the present fresh milk products used for PE film, black and white film, design pattern of this nature not only avoid multicolour printing is also simple and avoid large patterns colouring.

有的质料伸缩性不小,油不朱附着性也不对,如纲前不干奶制品所用的PE膜、彩色膜,安排这类包装图案时不仅制止众色套印,还给图案简略、制止不小背积填色。

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This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。

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双标记神经干细胞的增殖、分化活力与未标记神经干细胞相比无改变。