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脲基

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Target compounds have been synthesized by condensation of the aromatic nucleus and amino heterocylcle with acyl isocyanates or acylisothiocyanates in absolutely anhydrous and aprotic solvent.

为了寻找高活性的农药品种,利用生物等排原理和亚结构连接法,对脲类化合物的母体结构进行了修饰,将芳氧羧酸类及吡唑环引入酰基脲母体结构中,利用酰基异氰酸酯与杂芳环胺类化合物在无水非质子溶剂中发生亲核加成反应,合成了四个系列21种新的酰基脲类目标化合物。

The results showed that there is a strong recognition action between the four substituted ureas and cytosine.

研究结果表明,四个2-吡啶脲基化合物对胞嘧啶分子均具有较强的识别作用。

The biological activity tests show that some target compounds have a good activity as plant growth regulator, and N-5-(3-carboxy-1H-1,2,4-triazolyl)-N'-o- chlorophenylfonnyl urea, N-5-(3-carboxy-1H-1,2,4-triazolyl)-N'-o- bromophenylformyl urea, N-5-(3-carboxy-1H-1,2,4-triazolyl)-N'-p- methyl-phenyl formyl urea have excellent activity of auxin.

生测试验证明部分酰基脲类化合物具有良好的植物生长调节活性,其中N-5(3-羧基-1,2,4-三唑基)-N'-o-氯苯甲酰基脲、N-5-(3-羧基-1,2,4-三唑基)-N'-o-溴苯甲酰基脲和N-5-3-羧基-1, 2,4-三唑基)-N'-p(或m-甲基苯甲酰基脲具有优良的生长素活性。

MIRANDA HT grease is lead-free and based on HVI paraffin mineral oil and special poly urea soap.

万灵达高温润滑脂是由高黏度指数矿物油和聚脲基皂稠化制成,不含铅。

It was interesting to find that the melt flow rate curve went parallel to the impact strength with the increasing of CaCO_3 content.

异氰酸酯衍生的氨基甲酸酯、脲基等基团可以通过配位、氢键等形式与CaCO3表面发生作用。

Furthermore, they are also excellent bifunctional receptors as thiourea moieties have better recognition ability to anions.

同时,由于硫脲基具有较好的阴离子识别能力,它们也是性能优良的双功能团受体。

The complexation behavior of these compounds with linear or aromatic dicarboxylate was investigated by the means of absorption, emission spectra,〓H-NMR and molecular dynamics.

结果显示,二羧酸盐阴离子与双链萘基脲/硫脲哌嗪化合物发生络合形成新的物种导致双链萘基脲/硫脲哌嗪化合物的吸收和荧光光谱行为的变化。

In the first part, five new 4-acyl pyrazolone 4-ethyl-thiosemicarbazones compounds: 1-Phenyl-3-methyl-4-(4-bromo)benzal-pyrazol-5-one N(4)-ethyl-thiosemicarbazone (PM4Br BP-ETSC), 1-Phenyl-3-methyl-4-(4-methyl)benzal-pyrazol-5-one N(4)-ethyl-thiosemicarbaz -one (PM4MBP-ETSC), 1-Phenyl-3-methyl-4-benzal-pyrazol-5-one N(4)-ethyl-thiosemicarba -zone, 1,3-diphenyl-4-benzal-pyrazol-5-one N(4)-ethyl-thiosemicarbazone and 1-Phenyl-3-methyl-4-phenylacetyl-pyrazol-5-one N(4)-ethyl-thiosemi -carbazone have been synthesized and characterized by elemental analyses, IR, 1H NMR spectra and single-crystal XRD.

第一部分合成了五个4-酰基吡唑啉酮缩4-乙基-氨基硫脲化合物:1-苯基-3-甲基-4-(4-溴)苯甲酰基-5-吡唑啉酮缩4-乙基-氨基硫脲(PM4BrBP-ETSC),1-苯基-3-甲基-4-(4-甲基)苯甲酰基-5-吡唑啉酮缩4-乙基-氨基硫脲(PM4MBP-ETSC),1-苯基-3-甲基-4-苯甲酰基-5-吡唑啉酮缩4-乙基-氨基硫脲,1,3-二苯基-4-苯甲酰基-5-吡唑啉酮缩4-乙基-氨基硫脲和1-苯基-3-甲基-4-苯乙酰基-5-吡唑啉酮缩4-乙基-氨基硫脲,其中前四个具有光致变色性质。

The preliminary bioassays indicated that, at 500 g/mL, 1-(o-tolyl-4-(4-chloro-3-ethyl-1-methylpyrazol-5-ylcarbonyl)semicarbazide (4g) and 1-(2,4-dimethyl- phenyl)-4-(4-chloro-3-ethyl-1-methylpyrazol-5-ylcarbonyl)semicarbazide (4k) showed inhibitory activities 90% and 80% against Blumeria graminis, respectively; and at 25 g/mL, 4-phenyl-4-(4-chloro-3-ethyl-1- methylpyrazol-5-ylcarbonylsemicarbazide (4c) showed inhibitory activity 70.1% against Botrytis cinerea and 1-2-nitro-phenyl-4-(4-chloro-3-ethyl-1-methylpyrazol-5-ylcarbonylsemicarbazide (4d) showed inhibi-tory activitiy 51.3% against Pyricularia oryzae.

初步生物活性实验结果表明,在500 mg/mL浓度下,化合物1-(4-氯-3-乙基-1-甲基-1H-吡唑-5-甲酰基)-4-(2-甲基苯基)氨基脲(4g), 1-(4-氯-3-乙基-1-甲基-1H-吡唑-5-甲酰基)-4-(2,4-二甲基苯基)氨基脲(4k)对小麦白粉病菌的抑制率分别达到90%和80%;在25 mg/mL浓度下,化合物1-(4-氯-3-乙基-1-甲基-1H-吡唑-5-甲酰基)-4-苯基氨基脲(4c)对黄瓜灰霉病菌的抑制率达到70.1%;化合物1-(4-氯-3-乙基-1-甲基-1H-吡唑-5-甲酰基)-4-苯基氨基脲(4c)和1-(4-氯-3-乙基-1-甲基-1H-吡唑-5-甲酰基)-4-(2-硝基苯基)氨基脲(4d)对稻瘟病菌的抑制率均达到51.3%。

The results of biological tests indicated that, at 25 g/mL, 1-(4-bromo-3-ethyl-1-methyl-pyrazol-5'-ylcarbonyl-4-(2-nitrophenyl) semicarbazide (4d) showed inhibitory activities (52.6%) against Pyricularia oryzae. 1-(4-bromo-3-ethyl-1-methyl-pyrazol-5'-ylcarbonyl)-4-(3-chlorophenyl) semicarbazide (4j), 1-(4-bromo-3-ethyl-1-methyl-pyrazol-5'-ylcarbonyl)-4-(2,4-dimethylphenyl) semicarbazide (4k), 1-(4-bromo-3-ethyl-1-methyl-pyrazol-5'-ylcarbonyl)-4-(3,4-dimethyiphenyl) semicarbazide (41) and 1-(4-bromo-3-ethy-1-methyl-pyrazo1-5'-ylcarbonyl)-4-(2,4-difluorophenyl) semicarbazide (4m) showed inhibitory activities (45.6%) against Pyricularia oryzae, repestively.

初步生物活性实验结果表明,在25μg/mL浓度下,1-(1-甲基-3-乙基-4-溴-5-吡唑甲酰基)-4-(2-硝基苯基)氨基脲(4d)对水稻稻瘟病菌Pyricularia oryzae抑制活性达到52.6%;1-1-甲基-3-乙基-4-溴-5-吡唑甲酰基)-4-(3-氯苯基)氨基脲(4j,1-(1-甲基-3-乙基-4-溴-5-吡唑甲酰基)-4-(2,4-二甲基苯基)氨基脲(4k),1-(1-甲基-3-乙基-4-溴-5-比唑甲酰基)-4-(3,4-二甲基苯基)氨基脲(41)和1-(1-甲基-3-乙基-4-溴-5-吡唑甲酰基)-4-(2,4-二氟苯基)氨基服(4m)对水稻稻瘟病菌Pyricularia oryzae抑制活性达到45.6%。

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I didn't watch TV last night, because it .

昨晚我没有看电视,因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来,在北京的很多小区里,电梯液晶电视被撤了下来。

I'm running my simile to an extreme.

我比喻得过头了。