脱醇

The factors A and the rate constants are given at temperature range of 200-1200 K.The results in-dicate that the loss of aβ-hydrogen from 2-hydroxyethyl radical to yield vinyl alcohol and that a 1,3-hydrogen shift to form ethoxy radical have close A factors and rate constants.

用量子化学结果和Eyring过渡态理论计算了200－1200K温度范围内，标题反应的A因子和速度常数，结果表明，2－羟乙基脱去β－H生成乙烯醇与其经［1，3］重排生成乙氧基有相近的A因子和速度常数，且常温下速度较慢，反应难以进行。

Started from D-tyrosine, we obtained the tetramic acid 96 using Jouin reaction. The assembly of the second fragment 109 was stared from 1,4-butandiol,using asymmetric alkylation reaction developed by Oppolzer as a key step. Coupling of the tetramic acid 96 with 109 provided the key intermediate 110 according to Yoshii\'s procedure. After remove protective group and Sharpless epoxidation, we obtained the key intermediate 113. Its macrocyclization to form the final product is in progress.

本论文的第二章主要对Macrocidin A开展了合成工作，我们从D构型的酪氨酸出发，经过官能团转换；利用Jouin反应生成Tetramic acid 96，另外一个片断从1，4-丁二醇开始经过多步反应生成碘化物104，利用Oppolzer发展的手性樟脑磺酰胺为辅基参与的不对称烷基化反应，引入手性甲基，生成关键中间体109，接着通过Yoshii发展的方法连接96和109生成110，经过Sharpless不对称环氧化反应建立环氧化合物，然后脱去保护基得到关环前体113，分子内的Mitsunobu反应进行关大环反应正在进行之中。

Acetalization of Benzaldehyde with 1,2 Propanediol over Dealuminated USY

脱铝超稳Y沸石催化苯甲醛与1，2-丙二醇的缩醛化反应

Their specific surface area and acid strength were measured, and their catalyt and SBA-15 were ic performance was evaluated in the synthesis of fructone by acetalization of ethyl acetoacetate with ethylene glycol.

用浸渍法制备了一系列负载型磷钨酸及其铯盐催化剂，载体包括超稳Y沸石、脱铝超稳Y沸石、SiO2和SBA-15，测定了催化剂的比表面积和酸强度，并在乙酰乙酸乙酯与乙二醇液相缩合制取苹果酯反应中考察了催化剂的性能。

Supported 12-Phosphotungstic Acid and Its Salts as Catalysts for the Synthesis of Fructone and Fructone-B;2. Their catalytic activities were measured by synthesis of fructone-B from ethyl acetoacetate and 1,2-propanediol.

制备了一系列以脱铝超稳Y沸石为载体的磷钨酸及其铯盐催化剂，考察了催化剂在以乙酰乙酸乙酯和1，2-丙二醇为原料催化合成草莓酯反应过程中的性能。

Ultrasound, Expansive Graphite, Cinnamic Acid, Ethyl Alkylidene a- Cyanoacetate, Montmorillonite, Pinacol

超声波，膨胀石墨，肉桂酸，烷叉基氰乙酸乙酯，蒙脱土，片呐醇

In this thesis, investigations focused on heteropoly acids-catalyzed C-C and C-N bond formation reactions and the synthesis of xanthenediones and acridinediones under thermal conditions are described.1.12-Phosphotungstic acid has been used as an efficient,eco-friendly,and air- and moisture-stable catalyst to promote the direct dehydrative substitution of the hydroxy group of benzylic and allylic alcohols with variousβ-dicarbonyl compounds.

本篇论文主要描述了杂多酸催化下的C-C和C-N键的生成，以及无溶剂直接加热下合成十氢氧杂蒽二酮和9-芳基十氢吖啶二酮。主要内容如下：1。在磷钨酸催化下，1，3-二羰基化合物与醇能够顺利偶合，脱除一分子的水，生成烷基化的1，3-二羰基化合物。反应在甲苯中进行时，二芳基甲醇能与各类1，3-二羰基化合物反应，成率很高；但对于1-苯乙醇，只能得到很低的产率。

Potassium bromide produced in the elimination step was cleaned with steam treatment, then used to bromize tert-Butyl alcohol, producing tert-butyl bromide.

为了回收中间元素澳，用水蒸汽蒸馏方法除去脱漠化氢后生成演化钾盐中的杂质，通过添加硫酸以再生漠化钾用于叙丁醇漠化制漠代叔丁烷。

The effects of reaction conditions on the catalytic activity have been examined and a more than 95% yield of γ-butyrolactone obtained. Moreover, the above results are comparable with the catalytic activity of the same catalyst for hydrogenation of maleic anhydride.

结果表明，Cu/ZnO/Al2O3催化剂不但具有良好的顺酐加氢活性，而且在较温和的反应条件下对于1，4-丁二醇脱氢同样具有良好的催化活性，γ-丁内酯的收率可达95%以上。

This thesis makes up the direction for Cu-Zn-Al-O catalyst, explores the perparation method and technological conditions、the reduction method and technological conditions of Cu-Zn-Al-O catalyst, investigates Cu-Zn-Al-O catalyst activity, and studies the kinetics of γButyrolactone synthesis reaction by the liquid phase dehydrocyclization from 1, 4-Butanediol on Cu-Zn-Al-O catalyst in the batch reactor.

研究了Cu-Zn-Al-O催化剂的配方、制备方法和工艺条件、活化方式和工艺条件，考察了催化剂的活性，并在全混釜反应器中研究了1，4—丁二醇在Cu-Zn-Al-O催化剂上液相脱氢环化合成γ—丁内酯的反应动力学特性。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。