脱去

Removal of a carboxyl group from a chemical compound, usually with hydrogen replacing it.

脱羧作用从一化合物中脱去羧基，通常是用氢来替换

1H NMR spectroscopic analysis of aromatic protons combined with theoretical analysis of molecular structures proved the existence of two rotational isomers at 300 K, as well as a rapid interconversion equilibrium at 330 K for both compounds Ⅰ and Ⅱ. However, only one conformer exists for compound Ⅲ and puerarin containing 7-phenolic hydroxyl instead of propyl in A-ring as the case of compounds Ⅰ and Ⅱ. Based on UV-Visible absorption data of neutral and basic solutions, and on the density function calculations, the 7-phenolic hydroxyl group in A-ring was found to be more acidic than the 4'-phenolic hydroxyl group in B-ring. The mechanism of derivation reaction and the structure-reactivity relationship of puerarin as an antioxidant were further discussed.

其中7-丙基葛根素Ⅱ属于新型取代衍生物；变温1H NMR和理论计算结果表明，在300 K时，葛根素和4'-丙基葛根素以单一构型存在；而7，4'-二丙基葛根素和7-丙基葛根素则存在两种核磁可分辨的旋转异构体，当温度升至330 K时，两种异构体可以相互转化；通过对比分析葛根素及其衍生物脱质子产物的紫外可见吸收光谱并结合理论计算，确定了A环上7位酚羟基比B环上4'位酚羟基先脱去质子，并由此进一步阐明了葛根素衍生化反应机理以及在抗氧化作用中可能的活性位点和结构活性关系。

He spoke and said to those who were standing before him,＂ Take off his filthy garments, and clothe him in festal garments.

使者就吩咐那些立在他面前的说：＂脱去他身上污秽的衣服！＂以后向他说：＂看，我已脱去了你的罪过，给你穿上华丽的礼服。

The de-exined pollen, a kind of artificially treated pollen deprived of its exine and remaining only its intine, has special value in the studies on pollen biology as well as gene manipulation.

用人工方法脱去花粉外壁，仅被内壁覆盖的花粉称为脱外壁花粉，在花粉生物学研究和基因操作上有特殊的研究价值。

The new order of socialist market economy requires the essence of labor union to come back, in this new order, Chinese labor union will take off the seal during the war time of the revolution, take off the seal of times of planned economy and sit and go to its due position.

社会主义市场经济新秩序要求工会本质回归，在这个新秩序中，中国工会将脱去革命战争年代的印记，脱去计划经济时代的印记，坐到它应有的位置上去。

In the process of laboratory study, oxycodone was prepared by oxidating thebaine at 6,14-position under oxydol, hydrodeoxidizing 7,8-position double bond and 14-position ether under palladium catalyst. Furthermore, N-methyl of oxycodone was isolated byα-chloro-ethyl chloroformate under anhydrous condition and protection of 14-position hydroxyl to obtain noroxycodone, which was further converted into methylnaltrexone by N-alkylation in presence of cyclopropyl bromomethane, then by isolating 3-position methyl of methylnaltrexone under boron tribromide, becoming hydrochloride to prepare target compound, natrexone hydrochloride.

实验室工艺方面，本文首先用双氧水氧化蒂巴因的6-位和14-位、在钯炭催化下加氢还原7-8位双键和14-位醚合成羟考酮，然后提出并优化了在无水和14-位保护的情况下，用氯甲酸-α-氯乙酯脱去羟考酮的N-位甲基合成去甲羟考酮，再用环丙甲基溴将去甲羟考酮的N-位烷基化合成甲基纳曲酮，最后采用三溴化硼脱去甲基纳曲酮的3-位甲基和成盐酸盐合成盐酸纳曲酮。

The chlorin e6 7 and chiorin 11 were oxidized further with osmium oxide in the same oxidization condition to yield bateriochlorin 8 and 12, respectively.

卟吩醛2在碱性条件下转化为卟吩e6三甲酯7，2与烷基溴化镁的格氏反应给出脱镁叶绿酸醇9，选择高钌酸四丙基铵和N-甲基吗啉N-氧化物将3-位羟基氧化成羰基，所生成的卟吩二酮10在酸性条件下脱去甲酸甲酯生成焦脱镁叶绿酸衍生物11，用四氧化锇对7和11实施氧化，则分别转化为细菌卟吩衍生物8和12。

Computation makes clear as a result, the smooth balance of power that 6 ammonia in 6 ammonia magnesium chloride form in nucleus and other electron breaks up in field, cent is two class, the first class 4 ammonia, the 2nd class 2 ammonia, when outside ambient changes, it is to shuck off 4 ammonia element likely most, additionally 2 ammonia are shucked off again after warming up, this one conclusion accords with experimental result to agree.

计算结果表明，六氨氯化镁中的6个氨在原子核和其它电子形成的平均势场中分裂，分为两级，第一级4个氨，第二级2个氨，当外界条件变化时，最有可能是脱去4个氨分子，升温后再脱去另外2个氨，这一结论符合实验结果一致。

Heating at different temperatures, the quantity of the desorbed water molecules is different, and without complexed water molecules, the cation H〓 can react with o-Ps.

在不同温度烘烤下，脱去其络合水分子的数量是不同的，而脱去络合水的阳离子H〓会与o-Ps发生化学反应。

The material then flows via the rotor feed valve (17) on to the center of the heated, spinning rotor (5) in the high vacuum distillation chamber.

原料受重力从脱气腔流下，在脱气腔脱去少量的低沸点的原料和残留气体，便于下一步的蒸馏。

The absorption and distribution of chromium were studied in ryeusing nutrient culture technique and pot experiment.

采用不同浓度K2CrO4(0，0.4，0.8和1.2 mmol/L)的Hoagland营养液处理黑麦幼苗，测定铬在黑麦体内的亚细胞分布、铬化学形态及不同部位的积累。

By analyzing theory foundation of mathematical morphology in the digital image processing, researching morphology arithmetic of the binary Image, discussing two basic forms for the least structure element: dilation and erosion.

通过分析数学形态学在图像中的理论基础，研究二值图像的形态分析算法，探讨最小结构元素的两种基本形态：膨胀和腐蚀；分析了数学形态学复杂算法的基本原理，把数学形态学的部分并行处理理念引入到家实际应用中。