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The adsorption enthalpies, free energy changes and entropy changes of the cordycepin on 001×7 were also mensurated. The results indicated that the adsorption is a decalescence process. The breakthrough curve of cordycepin in dynamic experiments supports the above conclusion of thermodynamics.

测试了虫草素在001×7上的吸附焓、自由能和吸附熵,结果表明吸附是吸热过程;并对虫草素的吸附行为作了合理解释,进一步通过虫草素的穿透曲线验证了虫草素吸附热力学结论。

Utilized the natural hollow structure of the haulm adsorption and package paraffin to prepare the storage unit,then adopted resin to bonding the storage unit to become a board,gained the resin basal body haulm adsorption paraffin power storage unit figuration phase change material.

利用稻草的天然空心结构,吸附包裹相变石蜡制作成储能单元,然后采用树脂将储能单元粘结成型,得到树脂基稻草吸附石蜡储能单元定形相变材料。

What is perhaps more important, since the information above is obtained synchronously, the proposed methodology could provide information about the type of adsorption (chemical or physical adsorption), the change of chemical state of aniline in the system during the adsorption process, whether the chemical adsorption and physical adsorption took place simultaneously, the rate of the chemical and physical adsorption, and so on.2 We have studied the uptake of orthoxylene / isoamyl alcohol on silica gel as an example to demonstrate a novel methodology for studying multicomponent gas adsorption on solid adsorbent.

更为重要的是该吸附床为微分吸附床,所得这些信息又是同步的,这就能更全面深入地了解该吸附过程。该研究还表明:该法发挥了近红外光谱的几乎所有优点,提供的信息直观,无需复杂的数学处理和传质理论假设就能建立可信的传质模型以供工程设计和操作之用。

In this study, we developed the ammonia sensing material by using MCM-41 impregnated with bromocresol green. MCM-41 is one kind of mesoporous molecular sieves. It can be applied to many fields due to well-defined pore shapes, narrow distribution of pore sizes, large pore volumes, high surface area, excellent thermal, hydrothermal, chemical and mechanical stability. And the bromocresol green dye is commonly used as a pH indicator with colorimetric from pH 3.8 to pH 5.4.

本研究之目的是结合变色染剂及中孔洞分子筛MCM-41进行氨气吸附,研究中所选择之变色染剂溴甲酚绿是一种偏酸性之大分子有机染剂,其变色范围在pH 3.8到pH 5.4;而MCM-41由於其孔洞大小分布范围狭窄、孔洞体积大、高比表面积、具有良好的吸附容积、表面反应性强及易於改质等优点,故期望利用此复合材料,经气体吸附达到氨的移除并同时在吸附饱和前能产生显色效果。

(1) In the sorption kinetics experiment, Cu2+ sorptions by Ceratophyllum demersum, Myriophyllum triphyllum and Hydrilla verticillata respectively, all reached balance within 35mins, all of the test results of sorption kinetics recommended the pseudo second-order equation and indicated that this kind of sorption was a complicated process of simultaneous actions of many reactions. The test results of thermodynamic sorption fitted with Langmuir model better than Freundlich model, and the maximum sorption quantites were 13.12, 20.12, 7.79mg/g, respectively,In the desorption test, the desorption rates of each plants were all below 1%, indicating strong sorption-holding action of these submersed mcrophytes on Cu2+.

通过上述研究,得到以下结论: 1、狐尾藻、金鱼藻、黑藻在对铜离子的吸附动力学实验中,均在35min内达到吸附平衡,分别用一级动力学方程和伪二级动力学方程拟合,结果均为用伪二级动力学方程拟合效果较好,表明该吸附为多种反应同时作用的复杂过程;在热力学实验中,三种植物的吸附曲线都能较好的用Langmuir曲线拟合,其拟合最大吸附量分别为13.12、20.12、7.79 mg/g;在解吸实验中,三种植物的解吸率都较低,说明对铜离子都有较好的吸持能力。

The isosteric enthalpy of adsorption, free energy, and entropy of adsorption were evaluated.

分别计算了热力学参数吸附焓、自由能、吸附熵,结果表明,此吸附过程是放热和自发的,吸附速率受颗粒内扩散和化学反应等因素的共同控制。

The adsorption behavior of pure CO2 on silicalite was discussed in detail through the adsorption isotherms, adsorption sites, interaction energies, and isosteric heats of adsorption.

首先基于GCMC模拟从吸附等温线,吸附热,吸附位置,相互作用能等方面详细研究了纯组分CO2在全硅沸石Silicalite上的吸附性质,并与实验结果进行了比较。

Because of this property, water is preferentially adsorbed by these surfaces, and large organic compounds cannot compete with strongly held water for adsorption sites on the clay surfaces. Thus, Na-clays are ine_ective sorbents for small organic molecules. However, it is possible to modify the surface properties of clays greatly by neutralizing the anionic framework of layer silicates by using positively charged organic species such as alkylammonim ions. In the modi_ed form (HDTMA-bentonite), the clay surface may become organophilic and interact strongly with organic compounds. Textile dyes represent a relatively large group of organic chemicals. In an HDTMA-bentonite-dye system it is possible that adsorption may be enhanced by the hydrophobic interaction between the adsorbed dye molecule and HDTMA-bentonite.

O组给予亲水的性质到矿物表面,因为这水是吸附在这些表面,和大的有机化合物不能比有坚强的为了吸附位置在泥土表面,因而,Na—泥土是ine_ective吸附剂为了小的分子,希,它是可能的到更改的表面属性,泥土非常在抵销anionic层硅酸盐在用的结构 Positively负荷的物种例如alkylammonim离子,在mod i_ed形状,泥土表面可能变成organophilic和互相作用坚强地有机化合物,织物染料表现相关的大的组化学的,在HDTMA—斑脱土—染料系统它是可能的那吸附可能是提高在交互作用在中间吸附染料分子和HDTMA—斑脱土,interlamellarHDTMA的间隔—斑脱土是获得在substracting泥土层从的厚度实验上坚决的基础的间隔(d001)。

Methane adsorbed on the Mn〓O〓-Na〓WO〓/SiO〓 catalyst can not be found, but it can be adsorbed on outgassed silica at 173K. Such adsorption is formed by interaction of the adsorbed methane with O〓〓 sites and hydroxyls on the surface. The appearance of the band at 2904cm〓 of the V〓 mode (sym. stretch.), which is an infrared forbidden vibration, implies that the Td symmetry of the methane molecule may be distorted somewhat on the surface of silica. The small frequency shift (30cm〓) of OH stretching indicates that only a weak hydrogen-bonding interaction between adsorbed methane and hydroxyls exists in the methane adsorption.

甲烷不能在Mn2O3-Na2WO4/SiO2催化剂上吸附但在l73K的温度条件下可吸附于SiO〓表面上,这种吸附是通过吸附甲烷与表面配位不饱和氧和表面羟基作用而形成的,红外禁阻的V〓振动模式显示出红外活性说明甲烷分子的Td对称性发生畸变,甲烷吸附后羟基位移只有30cm〓,吸附甲烷同表面羟基间的氢键作用很弱。

The test results show that free cyanide, metallic cyanide complexes such as zinc cyanide, copper cyanide, iron cyanide, gold and silver cyanide can be well adsorped by D296r and D261 macro porous strong basic anion exchange resin.

结果表明,大孔强碱性阴离子交换树脂D296_R和D261都能有效地吸附简单氰化物和金、银、铜、锌、铁的氰络合物,热力学实验表明吸附等温线符合Freundlich方程,吸附过程属于优惠吸附。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

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