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Following the lead of Freundlich the generally held opinion is that the effect of one adsorbate on the adsorption of another is simple displacement.

若是溶质甲能使溶质乙的电离度或溶度降低,或增加溶质乙的Gegen-ion,则能使乙的吸附量增加。

The less the oxygen content and the more content of N element in the form of pyrrole-N were observed under stronger microwave power radiation. It was affirmed that the desulfurization capability of activated carbon could be greatly increased by microwave modification. According to the analysis on surface physical and chemical characteristics, a mechanism was concluded: Modified by microwave, functional groups begin to dissociate, alkalescency is enhanced, and surface oxygen content is reduced; the amount of active sites produced by dissociation of oxygen-containing groups increased, so did the pyrrole-N groups. Apparently, the activated energy of SO〓 adsorption decreased.

通过比较微波改性活性炭前后的吸附脱硫能力,结合它们的表面物理和化学性质的变化分析,确认微波改性活性炭的脱硫性能有显著提高,其作用机理在于微波处理后,活性炭表面微观形貌发生了较大的变化,化学基团发生分解,碱性特征增强,表面含氧量减少,以CO形式释出的含氧官能团分解后产生的活性部位和吡咯氮官能团数量增加,吸附SO〓的表观活化能降低。

The nickelous chloride both may use in to galvanize, and is prepares the galvanization chemical thionamic acid nickel the important raw material, lead is affects the electronickelling quality a important attribute, in the present industry 331 ion exchange resin deleading effect still could not arrive in the electronickelling the lead content standard, used pocket weak basicity resin XSC312 after the screening experiment determination to take from the nickelous chloride solution intermediate ion exchange except the micro lead resin, inspected the material fluid pH value, the contact duration in the ionic exchange column to the ionic exchange adsorption lead influence, has determined the resin adsorption capacity and inspected the resin analysis performance.

氯化镍既可用于电镀,又是制备电镀化学品氨基磺酸镍的重要原料,其中的铅是影响电镀镍质量的一个重要因素,现行工业中的331离子交换树脂除铅效果尚不能到电镀镍中铅含量标准,经过筛选试验确定采用大孔弱碱性树脂XSC312作为从氯化镍溶液中离子交换除微量铅树脂,在离子交换柱中考察了料液pH值、接触时间对离子交换吸附铅的影响,测出了树脂的吸附容量并考察了树脂的解析性能。

The negative values of AGH and the positive values of△G~ suggested that the hydrophobic force favored,and the electrostatic force unfavored the bacterial adsorption on kaolinite and montmorillonite.

发现疏水自由能为负,显示疏水作用为引力,有利于细菌与粘粒矿物的吸附;而静电力自由能为正,表明细菌-矿物间存在静电斥力。

The highest occupied molecular orbit and the lowest unoccupied molecular orbit are calculated, and the energy gap of the two orbits determines the activity of the reagents, and yet, in an alkaline solutions for flotation, the HOMOs of the corresponding ions decide the rigidity of the reagents and therefore determine the reaction activity with different rigidity metal cations in minerals, which vary flotation performance to different minerals, and the experimental results were verified.

药剂与矿物作用的能量计算结果表明:苯氧乙酸类抑制剂与方解石和一水硬铝石作用后的能量变化均为负值,能量变化有利,可以形成稳定的吸附;而与黄铁矿作用后的能量变化为正,能量的变化是不利的,故不能形成稳定的吸附,表现出较弱的抑制作用。

The interaction between MT and AA was expressed by infrared spectra, the functional groups of -SH in MT had lone pair electrons, which could formπ-πwith -C=O in AA. The equilibrium binding experiment and Scatchard analysis showed, at least three kinds of binding sites would exist when MT-imprinted polymer formed, the most adsorption capacities were 3.3896mg/g, 0.9362mg/g, 1.6583mg/g respectively; most terminal thiolate sulfurs in MT were polymerized as binding sites in the process of polymerization, which could observed from TEM, binding capability of other thiolate sulfurs was weak since spatial hindrance existed.

采用红外光谱研究了加入金属硫蛋白后功能单体丙烯酸官能团谱峰的变化,结果表明金属硫蛋白分子中的-SH与丙烯酸中的C=O在氯仿溶液中能形成π-π键,由聚合物的吸附特性和Scatchard分析可以得出,金属硫蛋白印迹聚合物至少存在三种结合位点,其高、中、低的最大吸附量分别为3.3896mg/g、0.9362mg/g、1.6583mg/g;通过透射电镜可以观察到,金属硫蛋白在聚合过程中主要以分子两端的巯基作为结合位点,不同位置的巯基受到的空间位阻不同,导致产生了三种不同的结合位点。

The adhesion energy and the intrusion energy were analyzed to reveal that the dipping was a lift-off process and the key for successful patterning was the intrusion energy between pentacene, substrate and the D.I. water.

另外,藉由吸附能与侵入能的分析,我们可知此方法为一剥除机制,而介於pentacene薄膜、基板与去离子水间的不同侵入能,便是成功定义出主动区的关键因素。

The interfacial chemistry, synergistic effects and interfacial kinetics of thesynergistic extraction system D_2EHPA-MPA-Fe~(3+) have been studied, where MPA is amono-alkyl phosphate extraction with long carbon chain. D_2EHPA in the mixed extractionsystem strongly exhibits the effect on the thermodynamics of micella formation and interfaceproperties of MPA. Some thermodynamic parameters of micella formation were obtained.The interfacial adsorption behaviour of D_2EHPA is opposite to that of MPA. Theemulsification for single MPA and the mixed system was discussed. The synergistic effectswere found in this mixed extraction system. It is proved that the process of Fe~(3+) extractionfor non-mixed extraction system is controlled by chemical reaction, the controlling reactionoccurs at the interface, and the reaction rate equation is obtained.

本文研究了协同萃取体系D_2EHPA—MPA—Fe~(3+的胶团形成热力学、界面特性、协萃效应和界面动力学(动力学控制机制和反应速率方程)研究发现,混合萃取体系中的D_2EHPA强烈地影响MPA的胶团形成热力学和界面吸附行为,得到了胶团生成常数、胶团形成自由能和临界胶团浓度的热力学参数D_2EHPA和MPA具有相反的界面吸附行为研究发现D_2EHPA—MPA混合萃取剂体系对Fe~(3+)产生了协萃效应动力学和界面化学的研究结果还证实了非胶束混合萃取体系的Fe~(3+)的萃取过程是受化学反应控制的,控制反应发生在界面上

Objective To establish a competitive RT-PCR method for quantitative determination of IFN-γ mRNA and IL-4 mRNA and explore the optimal inductive condition in vitro. Methods IFN-γ mRNA and IL-4 mRNA in PBMC induced by PMA and calcium ionophore of a healthy volunteer and in unstimulated PBMC of 11 HVs and 13 asthma patients were determined quantitatively with the established competitive RT-PCR method using self-prepared internal standard as competitive templets.

Subject words 】 Competitive templet; IFN-γ; IL-4; mRNA; RT-PCR 检测细胞因子最早使用生物学或免疫学测定法,这两类检测可反映某种细胞因子分泌、吸附、消耗和降解后的净含量〔1〕,但不能为细胞因子产生过程中基因转录、翻译及翻译后调控机制提供必要的信息,也不能反映细胞或组织内细胞因子基因表达水平。

Polys have been widely used in the field of biomedicalmaterials due to their excellent mechanical properties, low immunogenicity andgood biocompatibility.

但聚乳酸的亲水性差,降解速度缓慢,同时结构中不含细胞可识别的分子,不能对细胞实现特异性吸附,在组织工程中不能发挥优势。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

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