胺磺酰基

It was obtained with ethylenediamine and ethenesulfonic sodium as primary material through addition.

它是一种易降解的新型Gemini表面活性剂－N， N'-双癸酰基乙二胺二乙磺酸钠的中间体。

In addition to the lithium salts, we have also synthesized and studied the other types of ionic liquids, in which N-methyl-N-propyl piperidinium bis imide (PP13-TFSI) shows a wider electrochemical window -0.3 ~ 5.6 V vs.

在实践中对项目研究作了部分调整，另外也合成和研究了其它类型的离子液体，其中N-甲基-N-丙基哌啶三氟甲基磺酰亚胺（PP13-TFSI）表现出更宽的电化学稳定窗口-0.3 ~ 5.6 V vs。

Disodium petroleum cyclocarboxylic monoethanolamine sulfosuccinate was synthesized from petroleum cyclocarboxylic acid methyl ester via amidation,esterification and sulfonation.

利用石油环烷酸原料合成出石油环烷酸单乙醇酰胺磺基琥珀酸单酯二钠盐。

In addition to this,we discussed the stereochemistry in the synthesis of polyhydroxyα-amino acid based on chiral tert-butanesulfinyl amide.

除此之外，我们还系统讨论了基于叔丁基亚磺酰胺的多羟基取代α-氨基酸合成方法中的立体化学问题。

The invention belongs to the synthesis technical field of pharmaceutical intermediates, and more particularly relates to a preparation method of Cis-4-(2-bromine ethylene) benzene sulfonamide.

本发明属于药物中间体合成技术领域，具体涉及一种顺式-4-(2-溴乙烯基)苯磺酰胺的制备方法。

Started from D-tyrosine, we obtained the tetramic acid 96 using Jouin reaction. The assembly of the second fragment 109 was stared from 1,4-butandiol,using asymmetric alkylation reaction developed by Oppolzer as a key step. Coupling of the tetramic acid 96 with 109 provided the key intermediate 110 according to Yoshii\'s procedure. After remove protective group and Sharpless epoxidation, we obtained the key intermediate 113. Its macrocyclization to form the final product is in progress.

本论文的第二章主要对Macrocidin A开展了合成工作，我们从D构型的酪氨酸出发，经过官能团转换；利用Jouin反应生成Tetramic acid 96，另外一个片断从1，4-丁二醇开始经过多步反应生成碘化物104，利用Oppolzer发展的手性樟脑磺酰胺为辅基参与的不对称烷基化反应，引入手性甲基，生成关键中间体109，接着通过Yoshii发展的方法连接96和109生成110，经过Sharpless不对称环氧化反应建立环氧化合物，然后脱去保护基得到关环前体113，分子内的Mitsunobu反应进行关大环反应正在进行之中。

And then the intermolecular reductive cyclization reaction of N,N-diethyl-o-nitrobenzenesulfonamide with nitriles promoted by samarium diiodide was studied. 2H-1,2,4-Benzothiadiazine 1,1-Dioxides were prepared in good yields under mild and neutral conditions.

然后研究了二碘化钐促进的邻硝基N，N-二乙基苯磺酰胺与腈发生的分子间交叉还原偶联反应，一步合成了2H-1，2，4-苯并噻二嗪-1，1-二氧化物。

Four different ionic liquids, BF4, BF and PF6 were investigated, arid PF6 showed the best effect when used as the reaction media, giving the highest yield in the shortest reaction time. Promoted by KF in PF6, N-aryl or N-alkyl monosubstituted sulfonamides could react with various activated halides and unactivated primary halides smoothly. Reactions were performed at 85℃ for 2~10 hours, and thirteen N-alkylation products were obtained with 70%~97% yields. Moreover, the ionic liquid recovered could be reused for three times with no appreciable decrease in yield and reaction rate.

结果表明，以PF6为反应介质时显示出了最好的效果，反应的时间最短，收率最高。N-芳基或N-烷基单取代的磺酰胺和各类不同结构的活化的卤代烃和未活化的一级卤代烃在PF6中KF作用下，85℃反应2~10h，以70%~97%的优良收率得到了13个N-烷基化产物，而且离子液体回收使用3次后效果未降低。

And the corresponding chiral tertiary propargylic alcohols were obtained with enantiomeric excesses of up to 86%, which provided a simple, practical and inexpensive method to generate chiral tertiary propargylic alcohols.

经过筛选、测试，发现一β-磺酰胺基醇-钛复合物可在温和条件下，有效促进炔基锌对简单非活化酮的不对称加成，并且得到相应的手性三级炔丙醇，ee值达到了86%。

A readily available β-sulfonamide alcohol-titanium complex was found to be effective on promoting the asymmetric addition reaction of an alkynylzinc reagent to unactivated simple ketones under very mild conditions.

为此我们合成了一系列β-磺酰胺基醇，并将其作为配体与Ti4一起催化炔基锌对简单非活化酮的不对称加成反应。

Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.

我来只是现在，'歼灭战perfuming自己与胡努特，那麼，他来到和SAT 。