胺化

The effects of rare earth elements on Reformation of amination -catalyst for fatty alcohol were analyzed in this paper.

研究表明，稀土元素具有和镍相反的对高沸物成分的抑制作用，稀土元素的加入普遍提高了脂肪醇胺化反应的选择性。

In reductive amination, how to avoid to turn ketones into alcohols is one of difficulties in industrialized manufacturing.

在还原胺化类催化加氢反应中，如何避免酮被还原成醇，也是工业化生产中面临的难题之一。

The results of the analysis of the pectin extracted show ed that the degree of free and Salted forms, the degree of amide substitution,and the degree of esterification of carboxy groups were 85.1%, 1.1%, and 13.8%,...

我们对蚕粪果胶的分析表明，其羧基的游离及成盐程度、酰胺化程度、酯化程度分别为85.1％、1.1％和13.8％，甲氧基含量、半乳糖醛酸含量分别为1.79％和81.5％；特性粘度为267。

In the ammonifying procedure, al cohol is used as solvent or phase transfer catalyst is added. The results sh ow that the reaction time decreases evidently and the yield of bactericide in creases further.

在产品制备的胺化步骤，作者采用乙醇作为溶剂或加入相转移催化剂，明显缩短了合成时间，使产品双烷基二甲基溴化铵的产率得到了进一步提高。

After the click reaction of the SCL micelles and azide-terminus PNIPAM homopolymer, the novel PNIPAM-functionalized SCL micelles with pH-responsive cores and outer thermosensitive coronas were prepared, which was investigated act as excellent candidate of nanosized drug delivery vehicles. Finally, two types of novel shell cross-linked micelles in aqueous solution were prepared from these remarkable PMEO_2MA-b-P(DMA-co-QDMA)-b-PDEA triblock copolymers by cross-linking the inner P(DMA-co-QDMA) shell of micelles upon the addition of diazide tetra derivative in the presence of copper catalyst using click chemistry.

另外，还可以使用溴丙炔对ATRP聚合出的PMEO_2MA-b-PDMA-b-PDEA三嵌段的中间PDMA嵌段进行部分季胺化，这样可以利用两端叠氮化的四甘醇来交联由PMEO_2MA-b-PDMA-b-PDEA在不同条件下形成的两种分别以PMEO_2MA或PDEA为核的胶束，从而实现了从同一个聚合物直接在水溶液中得到两种内核不同敏感的壳交联胶束。

The lignin-quaternary/polyvinyl alcohol composite resin was made from lignin after phenolization and amination,using glutaraldehyde as cross-linking agent,PVA as carrier.

利用木质素为原料，经酚化、胺化改性后，以戊二醛为交联剂，聚乙烯醇为载体，合成了季铵型木质素/PVA复合阴离子交换树脂。

Diaminoalkanes react with sym - tetrachloroethane to give crystaline 2,2'- Bis -( hexahydropy-rimidine) derivatives 1 - 5, after treatment with aqua ammonia.

利用均四氯乙烷及二氯甲烷的胺化反应，合成了联氢化嘧啶衍生物1～5，4a，8b-反-4，5，8a，9a-四氮杂全氢芴(6)和8b，8c-顺-3a，4a，7a，8a-四氮杂环戊并全氢芴(7)。

At last,a convergent and general protocol to marine natural product,as demonstrated by the enantioselective total synthesis of malyngamides O,P,Q,R, 5"-epi-Q and 5"-epi-R bearing terminal vinylic chloride structure,was developed in detail.E,(7S)-7-methoxytetradec-4-enoic acid was prepared using the above described Johnson-Clainsen rearrangement,the terminal vinyl chloride was constructed using Wittig reaction as key step,the pyrrolidone derivative was constructed using L-serine as natural chiral pool.Starting from the synthesis of malyngamides O and P to explore the general route,an aldol reaction of methyl acetate with the vinyl chloride part in the presence of LDA gave the skeleton of amine portion,followed by amidation with the fatty acid finished the synthesis of malyngamide P.

先以malyngamides O和P为试点探索通用合成路线，将乙酸甲酯和烯氯部分在LDA存在下进行aldol反应得到氨部分的骨架，再将手性不饱和脂肪酸和氨部分进行酰胺化反应完成了malyngamide P的合成，将P在碱性条件下进行烯醇甲基化反应完成了malyngamide O的全合成。

After the click reaction of the SCL micelles and azide-terminus PNIPAM homopolymer, the novel PNIPAM-functionalized SCL micelles with pH-responsive cores and outer thermosensitive coronas were prepared, which was investigated act as excellent candidate of nanosized drug delivery vehicles.

另外，还可以使用溴丙炔对ATRP聚合出的PMEO_2MA-b-PDMA-b-PDEA三嵌段的中间PDMA嵌段进行部分季胺化，这样可以利用两端叠氮化的四甘醇来交联由PMEO_2MA-b-PDMA-b-PDEA在不同条件下形成的两种分别以PMEO_2MA或PDEA为核的胶束，从而实现了从同一个聚合物直接在水溶液中得到两种内核不同敏感的壳交联胶束。

In our research, through derivatization of stable calix[4]pyrroles, active substituting units were jointed on the calixpyrrolic skelecton. After acylamide and free radical transfer reaction, the preparation of new calix[4]pyrrole-bonded stationary phases were fulfilled. the separation abilities of them to inorganic and organic anions and medicines were exploited and new analytical methods were established. The separation mechanisms were discussed. At the same time, through using calix[4]pyrroles as additives in CZE to influence the electrophoresis of inorganic anions, the recognition mechanisms and influencing factors in supramolecular chemistry were also studied.

本项目以新型杯吡咯大环化合物分子识别化学研究为基础，设计合成了含活泼取代基的官能化杯[4]吡咯化合物，通过酰胺化反应和原位自由基链转移反应制备了新型的杯[4]吡咯色谱固定相，系统研究了具有阴离子识别功能的杯[4]吡咯大环化合物作为离子色谱的分离介质对无机、有机离子型化合物和药物分子的色谱分离性能，建立了新的分析方法，对分离机理进行了探索和验证；同时将杯[4]吡咯化合物用作毛细管电泳流动相添加剂，利用其对无机阴离子电泳行为的影响探讨超分子化学中分子识别的机理和影响因素。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。