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胺化

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CNTs were first pre-treated using acid solution (HNO3) to obtain CNTs functionalized with carboxylic groups. Subsequently, the stearyl alcohol was grafted onto CNT with the assistance of dehydrating agent, N,N'-dicyclohexyl-carbodiimide. Excellent dispersion in organic solvents such as acetone, THF, and chloroform was found for the modified CNTs (CNT-C18). In addition, the PBS/CNTs nanocomposites were then prepared through simple melt-blending. Mechanical properties, thermal behavior, conductivity of resultant polymer/CNT composites were investigated. The results show that excellent dispersion of nanotubes in the PBS matrices was achieved.

为了增加多壁奈米碳管在复合材料中的分散性,将碳管表面进行化学修饰,首先将多壁奈米碳管浸入HNO3溶液中,进行酸化,使碳管表面带有羧酸的官能基,然后再加入十八烷醇,在温和的条件下,藉由N,N'-二环己基碳二亚胺(N,N'-dicyclohexyl- carbodiimide,DCC)脱水剂脱水,使碳管和十八烷醇之间产生酯基的化学键结,改质后的碳管可以分散在acetone、THF、chloroform…等有机溶剂中,结果显示成功的利用DCC脱水剂完成碳管的改质。

The facts indicate that apart from the asymmetric induction of chiral diamine backbone,sterically hindered substitute groups on the aromatic rings,and the presence of sp~3-hydridized amino donors and its N,N\'-disubstituted groups in chiral SalanCrX complexes all play important roles in controlling polymer stereochemistry and enantioselectivity.

研究发现除了手性二胺骨架的不对称诱导作用,苯环上的大位阻取代基、N,N\'-二取代基的位阻作用以及N原子上sp~3杂化的供电子效应都对调控聚合物的区域和对映体选择性有很大作用。

A high molecular weight polyisobutenyl succinimide dispersant with high nitrogen content and good thermal and oxidative stabilities was developed.

采用氯化烃化工艺和后偶联反应技术开发了一种氮含量高、热稳定性和氧化稳定性好的高相对分子质量的聚异丁烯基丁二酰亚胺分散剂。

Cold crystallization process of N-(1-naphthyl) succinimide below glass transition temperature was monitored by differential scanning calorimetry and X-ray diffraction.

采用x射线粉末衍射和差示扫描量热分析方法,跟踪研究了N-(1-萘基)琥珀酰亚胺的液氮淬冷样品在室温(25℃)即在玻璃化转变温度以下的冷结晶行为。

The negatively charged sulfonic acid groups was readily introduced through the reaction of the terminal anhydride groups of the anhydride-terminated hyperbranched poly precursor with the amino groups of sulfanilic acid before chemical imidization.

研究表明,在聚合过程的聚酰胺酸阶段,采用过量的邻苯二甲酸酐或苯胺对超支化聚酰亚胺的端氨基或端酸酐基团进行的封端改性切实可行,改性反应可进行地相当彻底。

Changes in synaptic plasticity in dopamine neurons of the ventral tegmental area may contribute to circuit modification induced by many drugs of abuse, including cocaine.

这种LTP的易化产生是由可卡因诱导衰减GABA受体而产生的。GABA受体可以抑制多巴胺神经元的活动。

A series of polys based on pyromellitic dianhydride, biphenylyl tetracarboxylic dianhydride, thiodiphthalic dianhydride bis benzene dianhydride and oxydiphthalic dianhydride were prepared in different solvents.

以所合成的AB_2单体为原料,合成了一系粘度较低、溶解性良好,带端酚羟基、苯甲酰基、乙酰基、氰代苯基和苯酰苯亚胺基的芳香族超支化聚酰亚胺,通过核磁波谱、红外光谱分析和元素分析对其结构进行确证。

It is prepared through preparing the materials including alpha-silicon nitride crystal whisker, deionized water as solvent, polyethylene imine as dispersant, PVA as adhesive, propylene glycol as plasticizer and ammonium tetramethyl chloride to regulate pH value; mixing; twice ball milling and post-treatment.

所述浆料的制备方法是:加入α-氮化硅晶须,以去离子水为溶剂,以聚乙烯亚胺为分散剂,聚乙烯醇作为粘结剂,丙二醇作为增塑剂;加入四甲基氯化铵来调节料浆的pH值;制备步骤包括配料、混合、两次球磨及后处理工序。

Mercaptopropyl methyldimethoxysilane was synthesized by thiourea in the presence of tetramethylammonium iodine as a catalyst and mixed liquid containing ethylenediamine and trichloroethylene as a neutralizer, without solvent, in which the reaction temperature, catalysts ,neutralizer and their amounts were optimized.

以四甲基碘化铵为催化剂,乙二胺和三氯乙烯的复合液为中和剂,在无溶剂体系中,用硫脲法合成了甲基巯丙基二甲氧基硅烷。

With the increase of content of triamine monomer, the mechanical property of polyimide foams is improved, and the glass transition temperature of polyimide foams increases.

随着三胺单体含量的增加,聚酰亚胺泡沫材料的力学性能和玻璃化转变温度得到提高。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

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