胺化

After acidify with hydrochloric acid, the plasma was extracted with ethyl ether and then analyzed by Hypersil ODS2 (250×4.6 mm,5 μm) column with the mobile phase of methanol-water-triethylamine-acetic acid(2500∶1500∶15∶7), and at the detection wavelength of 355 nm.

血样经盐酸酸化后以乙醚提取，进行 HPL C分析，色谱柱为 Hypersil ODS2 (2 5 0× 4.6 m m，5 μm)，流动相为甲醇-水-三乙胺-冰醋酸(2 5 0 0∶15 0 0∶ 15∶ 7)检测波长为 35 5 nm，尼美舒利为内标。

We have synthesized 4,4'-dinitro-3 4''-dimethyl triphenylamine,(1), in 84% yield in an one-step condensation process between 3,4-dimethyl aniline and 4-fluoro-nitrobenzene. After the auto-oxidation of (1) and the subsequent hydrogenation of the nitro-groups, an AB2 type triphenylamine polyimide intermediate bearing two amine groups and one acid-anhydride group each on individual phenyl ring,{AB2 PI Intermediate}, was prepared successfully. The yields of the autoxidation and the hydrogenation steps are 81% and 90% respectively.

中文摘要本研究以3，4-二甲苯胺及4-氟硝基苯为原料，经一步骤缩合反应得到产率为84 %之4，4'-二硝基-3&，4&-二甲基三苯胺(1)，由(1)经自氧化法后再以氢化法还原硝基，成功地制备出带有二胺基与一羧基的三官能基之AB2型三苯胺中间体(AB2型PI中间体)，自氧化反应与氢化法的产率各为81%及90%。

However, no examples of a copper-catalyzed combination of N-alkenylation and N-alkylation of amides had been reported.

然而，组合铜催化的酰胺N—烯基化和N—烷基化偶联生成二氢吡咯衍生物的反应未见文献报道。

It was shown that the absorption peaks of amine and amide groups of gelatin were shifted in HDPE/PE-g-MAH/Gelatin blends because of the reaction of PE-g-MAH with gelatin. The addition of PE-g-MAH made the increase of HDPE glass transition temperature. The compatibilizing effect of PE-g-MAH was due to the crystal compatibility produced by forming the co-crystals of HDPE, PE-g-MAH and PE-g-MAH-g-gelatin. The blends of EAA and gelatin were prepared by melting process and the compatibility of the blends was also studied.

红外光谱分析结果表明：体系中明胶的氨基吸收峰、酰胺Ⅱ带吸收峰峰位发生了明显的变化；二甲苯和水抽提实验表明，在熔融共混过程中EAA与明胶发生了反应；DMA测试共混物的玻璃化转变温度发现：两组分的玻璃化转变温度差值减小；SEM的实验结果表明，共混物中明胶的表面有接枝物形成。

The blends of PE-g-MAH and gelatin were prepared by melting process and the compatibility of PE-g-MAH and gelatin in blends were characterized. The results of FTIR showed that the characteristic absorption band peaks of amine and amide groups of gelatin were shifted in PE-g-MAH/Gelatin blends, the equilibrium values of torque were higher with the increase of blending temperature, which proved that graft copolymer PE-g-MAH-g-gelatin was formed during the preparation process, and the amount of PE-g-MAH-g-gelatin was increased with increasing the amount of PE-g-MAH. SEM micrographs exhibited that there was PE-g-MAH-g-gelatin formed in surface of gelatin phase.

通过红外光谱分析、HAAKE流变分析、抽提等实验证明：共混物中明胶的氨基、酰胺基团吸收峰峰位发生了明显的变化；在熔融共混过程中，随着温度的提高，平衡扭矩增大；明胶与PE-g-MAH发生了反应形成PE-g-MAH-g-明胶接枝共聚物，而且随着PE-g-MAH用量的增加，形成接枝共聚物的量也提高；SEM的实验结果表明，在明胶的表面确有接枝物形成；通过DMA测试共混物的玻璃化转变温度，发现两组分的玻璃化转变温度差值减小，二者的相容性提高，实现了共混体系的自增容。

It was shown that the absorption peaks of amine and amide groups of gelatin were shifted in HDPE/PE-g-MAH/Gelatin blends because of the reaction of PE-g-MAH with gelatin. The addition of PE-g-MAH made the increase of HDPE glass transition temperature. The compatibilizing effect of PE-g-MAH was due to the crystal compatibility produced by forming the co-crystals of HDPE, PE-g-MAH and PE-g-MAH-g-gelatin. The blends of EAA and gelatin were prepared by melting process and the compatibility of the blends was also studied. The FTIR results showed that absorption peaks of amine and amide groups of gelatin were shifted in EAA/Gelatin blends.

通过红外光谱分析、HAAKE流变分析、抽提等实验证明：共混物中明胶的氨基、酰胺基团吸收峰峰位发生了明显的变化；在熔融共混过程中，随着温度的提高，平衡扭矩增大；明胶与PE-g-MAH发生了反应形成PE-g-MAH-g-明胶接枝共聚物，而且随着PE-g-MAH用量的增加，形成接枝共聚物的量也提高；SEM的实验结果表明，在明胶的表面确有接枝物形成；通过DMA测试共混物的玻璃化转变温度，发现两组分的玻璃化转变温度差值减小，二者的相容性提高，实现了共混体系的自增容。

Because a part of hydroxyl group in methyl cellulose were substituted by trimethylsilyl group , the product could be dissolved in amounts of common organic solvents, such as chloroform, xylene and so on.

通过甲基纤维素与六甲基二硅亚胺的反应，成功地实现了对水溶性物质甲基纤维素醚三甲基硅化的改性；红外光谱验证了反应的发生，核磁共振氢谱确定了三甲基硅甲基纤维素的取代度；纤维素醚上的部分羟基被三甲基硅化后取得了在普通溶剂中的良好的溶解性，且随着取代度的增加，在非极性溶剂中的溶解性逐渐变好；通过热失重实验，对其热稳定性进行了测试。

In our studies, the behavioral sensitization animal models, including rats and mice, induced by morphine, methamphetamine or cocaine were established to investigate the effects of L-type calcium channel antagonists, mood stablers (lithium salts, valproate, and carbamazepine), and a novel mu-receptor partial agonist the morphine on development, transfer, and expression of behavioral sensitization.

本课题建立吗啡，甲基苯丙胺以及可卡因诱导的大、小鼠行为敏化模型。探讨了L-型钙通道阻滞剂，情绪稳定剂（锂盐，丙戊酸钠和卡马西平），以及新型μ受体部分激动剂噻吩诺啡对行为敏化形成，转化以及表达的影响。

The pure cotton fabrics finished by perfume compound microencapsulation with melamine resin as shell material were described.

论述了用部分醚化的蜜胺树脂作为壁材，对香精进行胶囊化制成香精微胶囊，再对纯棉织物进行香味整理的过程。

On the basis of the above N-vinylaiton of amides,the Cu-catalyzed intramolecular C-S coupling of thiols was implemented for the first time with CuI (10 mol%) as the catalyst and K_3PO_4·3H_2O2 equiv.

在酰胺氮烯基化研究的基础上，我们进而开展了烷基硫醇分子内烯基化反应研究。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新