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胺化

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The results indicate that polyborazine precursor prepared at 150℃ for 10 h and propylamine/isopropylamine molar ratio 2:1, could possess nearly linear molecule skeleton and he prone to melt spinnability. When melt at 90℃, the precursor fibers are prepared with average diameter 10-20μm and BC1.27 N1.52 H structure. After curing process and sintered in NH3 at 1200℃, the near-stoichiometric BN fibers was obtained, which proved this precursor is apt for preparation of BN fibers.

结果表明,当正丙胺/异丙胺摩尔比为2:1,聚合温度为150℃,反应时间为10h时,合成产物具有近似线性分子结构,熔点为90℃,具有良好的成丝性,可获得平均直径10~20μm,组成为BC1.27N1.52H的先驱体纤维,先驱体纤维再经不熔化处理及1200℃氨气高温锻烧等工艺可获得近化学计量比的氮化硼纤维。

In the synthesis process, aluminum isopropoxide or pseudo-boehmite is used as aluminum resources, and hexacosanoic propylamine and isopropylamine or the mixture of both are used as templates, thereby realizing the purposes of single feeding adoption, relatively mild crystallization condition, suitable water-solid ratio and great template dosage reduction.

一种用杂原子取代AEL骨架结构磷铝酸盐分子筛的合成方法,该方法是以氯、钛、钴、钙、钯、锌、铈和锆等杂原子为杂原子物料来取代磷铝酸盐分子筛的AEL骨架结构,并在合成过程中以异丙醇铝或拟薄水铝石为铝源,正二丙胺、异二丙胺或两者的混合物为模板剂,从而实现采用一次投料,晶化条件相对温和,水固比适宜,模板剂用量大大下降的目的。

American Dupont NOMEX fragrant gathers the amide paper, it is (chromatographic analysis textile fiber and short fiber) is composed of two kind of shape aromatic polyamide polymer, uses the special papermaking or the system board method, agglutinates Cheng Jibo the fibrous reticulum, undergoes high temperature high pressure processing, carries on the densification and the calendering causes them reliable to fix lowly in the same place, becomes not penetrable, electrical and mechanicalness energy level high whole.

美国杜邦NOMEX芳香聚酰胺纸,它是是由两种形态的芳香族聚酰胺的聚合物组成,使用特殊的造纸或制板方法,粘合成极薄的纤维网,经过高温高压处理,进行密化和轧光使它们牢固低固定在一起,成为不可渗透的,电气和机械性能极高的整体。

Rat ventral mesencephalic precursors can be induced to differentiate into plenty of tyrosine hydroxylase-positive DNs, mainly originating in A10 regions.

大鼠腹侧中脑多巴胺能前体细胞可在体外大量诱导分化成酪氨酸羟化酶阳性的主要源自中脑腹侧被盖区(A10)的多巴胺能神经元。

Myristic monoethanolamide ammonium sulfatewas synthesized from myristic acid and monoethanolamide with sulfamic acid as sulfating agent .

在芳烃类溶剂与羰基化合物催化剂存在下,以肉豆蔻酸和乙醇胺为原料,氨基磺酸作硫酸化剂,制备了肉豆蔻酸单乙醇酰胺硫酸酯铵盐。

In the same time, the intra-molecular photoinduced electron transfer process between naphthyl group and nitrogen atom of tertiary amine group at the tip of molecule was found and this process strongly depends on the acidity of solution.

通过对该类化合物在溶液中的光物理行为以及酸度影响的比较研究,观察到以叔胺为骨架的三足化合物存在分子内光诱导电子转移,且这一过程强烈地依赖于介质的pH值;叔胺基的氮原子质子化将会减弱这一PET过程。

In a DMF solution of CuCl〓-ethanolamine-acetic acid (1: 2: 2), 27 formed a highly oxidized heterocyclic compound 2-hydroxymethyl-naphtho [1, 2-a] oxazole (30) by the carbon-nitrogen coupling and carbon-oxygen coupling with the ligand of ethanolamine, which brings a chance to develop a novel approach to this heterocyclic compound via one-pot reaction of phenols under mild condition.

在氯化铜—乙醇胺—乙酸(1:2:2)的DMF溶液中,27与配体乙醇胺发生碳氮偶合与碳氧偶合,生成深度氧化的杂环化合物:2-羟甲基-萘并[1,2-a]〓唑(30)。这可望为酚类一锅化直接转化为30及其类似物提供一种简便的新合成路线。

The intermediate which obtained from oximation of 7a-e reacted withmethyl N-(2-bromomethylphenyl)-N-methoxycarbamate to synthesize oxime ether methyl carbamate 3a-e.

以邻位卤代苯甲醛和3-丁烯-2-醇为原料通过钯催化&一锅法&反应合成了2-乙酰基茚7a-e,7a-e 肟化之后和N-(2-溴甲基苯基)-N-甲氧基氨基甲酸甲酯反应合成了肟醚类氨基甲酸甲酯3a-e,进一步胺解之后得到了肟醚类氨基甲酰甲胺3f-j。

Pyridoxine, pyridoxal , pyridoxamine as well as their phosphated forms are structural analogues in which pyridoxal-5"-phosphate and pyridoxamine-5"- phosphate are the biological active forms in vivo which act as the cofactors of aminotransferases, amino acid decarboxylases, cysteine desufbrase and cystathionine , etc by constant transconversions. Recently, it was discovered that B6 played a novel role in tumor growth suppression.

它包括三种结构十分近似的化合物:吡哆醇(Pyidoxine,PN)、吡哆醛(Pyridoxal,PL)和吡哆胺(Pyridoxamine,PM),分别以磷酸化的形式发挥作用,其中吡哆醛-5'-磷酸(Pyridoxal-5'-phosphate,PLP)为B_6在体内的活性形式,通过与磷酸吡哆胺(Pyidoxamine-5-phosphate,PMP)的互变,作为多种酶(氨基转移酶、氨基酸脱羧酶、半胱氨酸脱硫酶、胱硫醚酶等)的辅酶而发挥传递基团的作用。

The copolymer of N isopropylacrylamide and acrylamido azobenzene was synthesized for the study of the effect of the photoisomerization of a water soluble copolymer containing azobenzene groups on the photocontrolled release behavior of liposomes.

为了研究侧链含有偶氮苯基的水溶性共聚物的光异构化对脂质体内包容物的光控释放的影响,设计合成了N-异丙基丙烯酰胺和丙烯酰胺基偶氮苯的共聚物。

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