胺化

The optimum reaction conditions are as follows: diphenylmethanethiol : methyl chloroacetate is 1:1.5, and the reaction carried out at 100℃ for 4 h, 2- acetamide can be carried out in the room temperature for 20 h, the yield of 2- acetamide was 76%, hydrogen dioxide: 2- acetamide is 1:1, and the reaction carried out at 60℃ for 3 h, the yield of modafinil was 79%, the total yield of reaction can be reached 48%.

研究表明，采用氯乙酸甲酯作为醚化试剂，反应时间4h，反应温度100℃，二苯甲硫醇：氯乙酸甲酯=1：1.5，室温下氨解反应20h，二苯甲硫乙酰胺收率76%；采用过氧化氢作为氧化试剂，反应时间3h，反应温度60℃，过氧化氢：二苯甲硫乙酰胺=1：l，莫达非尼收率79%，反应总收率可达48%。

On the basis of these studies, sensitive and rapid determination methods of AM and MA in urine by gas chromatography with electron-capture detection combined with various acyl derivatization were developed.

在此基础上，建立了人尿中苯丙胺和甲基苯丙胺的酰基衍生化的气相色谱－电子捕获检测分析方法。

The charge-remote fragmentation of protonated alkylamines and the fragmentation of alkylamine ions can be explaned by using the radical mechanism and hydrogen abstraction of intramolecule, respectively.

自由基机理可以解释质子化脂肪胺分子的远电荷反应。分子内氢抽取可以解释脂肪胺分子离子的碎裂反应。

The fragmentations of alkylamine ions C~nH~2~n~+~1NH~2^+ produced from 18 kinds of alkylamine salts by the electron impact ionization and protonated alkylamine C~nH~2~n~+~1NH~3^+ produced from them by the chemical ionization were examined using collision- induced dissociation.

应用碰撞诱导解离技术研究了电子轰击方法产生的脂肪胺分子离子和化学电离方法产生的质子化脂肪胺分子的碎裂反应。

After hydrogenation of the double bond and the addition of alkyne to a carbonyl we introduced the N-hydroxy group by SN2 reaction.

不对称氢化和炔负离子对羰基的立体选择性加成构建了两个新的手性中心，之后用羟胺衍生物对羟基的SN2取代反应引入了羟胺片断。

Over the AlPO〓, the deamination and dealkylation of diethylmine and triethylmine produced ethylene selectivily. Over AlPONs of acid-base bifunctional catalysts the ethylnitrol formed selectivily.

二乙胺、三乙胺在酸性的磷酸铝上选择性的脱烷基/脱氨生成乙烯，在酸碱两性的氮化磷酸铝上选择性脱烷基/脱氢生成乙腈。

In the orthogonal designable experiment ,the analysis results of zirconium source, precipitation , the sulfating agent is 1.54%, 2.27%, 5.11%,respectively. This result show that the influence of sulfating agent to the catalytic activity is the biggest. Under the same density of the sulfuric acid soaks, the effect of sulfuric acid is well compared to ammonium sulfate .The second is the precipitation, but the influence of the zirconia source is the smallest.

正交设计实验中锆源、沉淀剂、硫酸化试剂的极差分析结果分别为1.54%，2.27%，5.11%，此结果说明硫酸化试剂对催化剂的影响最大，其次是沉淀剂，锆源的影响最小，同时表明以Zr(NO3)4·5H2O为锆源、乙胺为沉淀剂、硫酸为硫酸化试剂是催化剂的最佳制备方案。

acetyl chloride, a novel fluorescence derivatization reagent, has been developed for the determination of sterols and stanol .

采用荧光衍生化试剂2-(9-咔唑)乙酰氯，对天然产物谷甾醇、豆甾醇、菜油甾醇及谷甾烷醇的柱前衍生化条件，包括催化剂的种类、反应温度、衍生化时间等进行了考察，结果表明：催化剂选用三乙胺，反应温度80℃，时间20min，衍生产物具有恒定的最大检测响应值。

Little literature on the aspect of surfactants containing boron with long-carbon chain alkyls had been found.Using diethanolamine, boric acid, hexadecanol as starting materials, after a series of reaction such as vapour phase process bromizating, esterifying, alkylating, a new type of surfactants with boron RNB had been obtained. The structures of the compounds had been identified by elemental analysis, IR and HNMR.

本论文采用二乙醇胺、硼酸、十六醇等为主要原料，经气相法溴化、酯化、烷基化等一系列反应合成了一种新型含硼表面活性剂RNB，并通过元素分析、红外、核磁对其结构进行了确认。

Uniform, highly stable and well-dispersed hydrophilic CdSe-AET (2-aminoethanethiol hydrochloride) quantum dots are synthesized by changing hydrophobic TOPO to hydrophilic AET.

本实验使用高温裂解法合成出疏水相硒化镉量子点后经过官能基转换方式，将疏水性的硒化镉在安全且简单的反应条件下得到大小均匀、稳定性高、分散性佳的水相硒化镉-半胱胺盐酸盐量子点。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。