胡椒醛

Keywords piperonal;acetone;synthesis;claisen-schmidt reaction;4-（1;3-benzedioxole）-3-buten-2-one

洋茉莉醛；丙酮；胡椒烯丙酮；合成；克莱森-施密特反应

Main production and management projects: piperonyl butoxide, Piperonal aldehyde, C Piperonyl aldehyde, PMK, eucalyptus oil, according to pituitrin, citral, ionone, cubeba oil, Geranium oil, 99 % natural a bit terpineol, pine oil acetate, sassafras oil, natural spices; run: Fragrance, tobacco flavor, food flavor, natural flavor essence seasoning products.

胡椒基丁醚、洋茉莉醛、胡椒基丙醛、胡椒基甲基酮、桉叶油、按叶素、柠檬醛、紫罗兰酮、山苍子油、香叶油、99%天然甲位松油醇、乙酸松油脂、黄樟油等天然香料；兼营：日化香精、烟用香精、食用香精、调味品香精等天然香精产品等。

4Production of chemical products from which narcotics are easily made ephedrine, 3, 4-idene dihydro phenyl-2-acctonc, phenylacetic acid, 1-phenyl-2-acetone, heliotropin, safrole, isosafrole, acetic oxide

易制毒化学品生产（麻黄素、3，4-亚基二氧苯基-2-丙酮、苯乙酸、1-苯基-2-丙酮、胡椒醛、黄樟脑、异黄樟脑、醋酸酐

RESULTS: 12 compounds were isolated and identified as aurantiamide acetate (1), aurantiamide benzoate (2), physcion (3), scopoletin (4), vanillin (5), coniferyl aldehyde (6), syringaldehyde (7), syringic acid (8), luteolin (9), apigenin (10), azelaic acid (11), dotriacontanic acid (12), respectively.

结果：从羊耳菊全草的氯仿和乙酸乙酯部分共分离得到12个化合物，分别鉴定为橙黄胡椒酰胺乙酸酯(1)，橙黄胡椒酰胺苯甲酸酯(2)，大黄素甲醚(3)，东莨菪亭(4)，香草醛(5)，松柏醛(6)，丁香醛(7)，丁香酸(8)，木犀草素(9)，芹菜素(10)，壬二酸(11)，三十二烷酸(12)。

Papers in the experimental part of our literature considered on the basis of the experimental exploration, and podophyllotoxin intermediates with the structural characteristics of a simple pepper aldehyde as the starting material,α,β-unsaturated carbonyl compounds are selective reduction lithium aluminum hydrogen reduction reaction as the key steps to have the Knoevenagel condensation, peracetic acid epoxy between chlorine and alkaline hydrogen peroxide epoxy, DCC condensation esterification reaction of the three podophyllotoxin intermediates.

论文实验部分我们在综合考虑文献的基础上，经过实验摸索，并结合鬼臼毒素中间体的结构特点以简单的胡椒醛为起始原料，对α，β-不饱和羰基化合物具有选择性还原的锂铝氢还原反应为关键步骤，先后经过Knoevenagel缩合，间氯过氧苯甲酸环氧化，碱性过氧化氢环氧化，DCC缩合酯化等反应合成了3个鬼臼毒素中间体。

4Production of chemical products from which narcotics are easily made ephedrine, 3, 4-idene dihydro phenyl -2-acctonc, phenyl acetic acid, 1- phenyl -2-acetone, heliotropin, safrole, isosafrole, acetic oxide

易制毒化学品生产（麻黄素、 3 ， 4-亚基二氧苯基-2-丙酮、苯乙酸、 1-苯基-2-丙酮、胡椒醛、黄樟脑、异黄樟脑、醋酸酐

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。