胡椒醛

Keywords piperonal;acetone;synthesis;claisen-schmidt reaction;4-（1;3-benzedioxole）-3-buten-2-one

洋茉莉醛；丙酮；胡椒烯丙酮；合成；克莱森-施密特反应

Main production and management projects: piperonyl butoxide, Piperonal aldehyde, C Piperonyl aldehyde, PMK, eucalyptus oil, according to pituitrin, citral, ionone, cubeba oil, Geranium oil, 99 % natural a bit terpineol, pine oil acetate, sassafras oil, natural spices; run: Fragrance, tobacco flavor, food flavor, natural flavor essence seasoning products.

胡椒基丁醚、洋茉莉醛、胡椒基丙醛、胡椒基甲基酮、桉叶油、按叶素、柠檬醛、紫罗兰酮、山苍子油、香叶油、99%天然甲位松油醇、乙酸松油脂、黄樟油等天然香料；兼营：日化香精、烟用香精、食用香精、调味品香精等天然香精产品等。

4Production of chemical products from which narcotics are easily made ephedrine, 3, 4-idene dihydro phenyl-2-acctonc, phenylacetic acid, 1-phenyl-2-acetone, heliotropin, safrole, isosafrole, acetic oxide

易制毒化学品生产（麻黄素、3，4-亚基二氧苯基-2-丙酮、苯乙酸、1-苯基-2-丙酮、胡椒醛、黄樟脑、异黄樟脑、醋酸酐

RESULTS: 12 compounds were isolated and identified as aurantiamide acetate (1), aurantiamide benzoate (2), physcion (3), scopoletin (4), vanillin (5), coniferyl aldehyde (6), syringaldehyde (7), syringic acid (8), luteolin (9), apigenin (10), azelaic acid (11), dotriacontanic acid (12), respectively.

结果：从羊耳菊全草的氯仿和乙酸乙酯部分共分离得到12个化合物，分别鉴定为橙黄胡椒酰胺乙酸酯(1)，橙黄胡椒酰胺苯甲酸酯(2)，大黄素甲醚(3)，东莨菪亭(4)，香草醛(5)，松柏醛(6)，丁香醛(7)，丁香酸(8)，木犀草素(9)，芹菜素(10)，壬二酸(11)，三十二烷酸(12)。

Papers in the experimental part of our literature considered on the basis of the experimental exploration, and podophyllotoxin intermediates with the structural characteristics of a simple pepper aldehyde as the starting material,α,β-unsaturated carbonyl compounds are selective reduction lithium aluminum hydrogen reduction reaction as the key steps to have the Knoevenagel condensation, peracetic acid epoxy between chlorine and alkaline hydrogen peroxide epoxy, DCC condensation esterification reaction of the three podophyllotoxin intermediates.

论文实验部分我们在综合考虑文献的基础上，经过实验摸索，并结合鬼臼毒素中间体的结构特点以简单的胡椒醛为起始原料，对α，β-不饱和羰基化合物具有选择性还原的锂铝氢还原反应为关键步骤，先后经过Knoevenagel缩合，间氯过氧苯甲酸环氧化，碱性过氧化氢环氧化，DCC缩合酯化等反应合成了3个鬼臼毒素中间体。

4Production of chemical products from which narcotics are easily made ephedrine, 3, 4-idene dihydro phenyl -2-acctonc, phenyl acetic acid, 1- phenyl -2-acetone, heliotropin, safrole, isosafrole, acetic oxide

易制毒化学品生产（麻黄素、 3 ， 4-亚基二氧苯基-2-丙酮、苯乙酸、 1-苯基-2-丙酮、胡椒醛、黄樟脑、异黄樟脑、醋酸酐

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐