胂基

Whenpyridine was used as reductive decomposing agent, the expecting cholest-4-en-3,6-dione-22-al was obtained. However, when Zn/HOAc was used to decomposethe ozonide, C-4,5 double bond was further reduced to give cholest-3,6-dione-22-al as main product. 2 For the side-chain construction of compound (1), the solid-liquid phase-transfer Wittig reaction was used. When (3-methyl-2-oxobutyl)-triphenylarsonium bromide was used as reagent, the reaction can be carried out inmild reaction condition and the yield is higher than that when phosphorane wasused.

但使用Zn／HOAc作为分解剂时，却得到其氢化产物胆甾-3， 6-二酮-22-醛；2在甾体支链引入过程中，采用固-液相转移Wittig反应的方法，用(3-甲基)-2-氧丁基三苯基溴化胂作为试剂，反应在非常温和的条件下便可完成，而且产率比传统采用膦烷的方法更高；3在对某些甾酮化合物的选择性还原反应研究时，发现在〓还原体系中，当加入某些金属离子后，反应有更好的区域选择性和立体选择性。

The mixed collectors studied were as following: benzyl arsonic acid-sodium butyl xanthate for walframite flotation, salicylohydroxamic acid-F〓, salicylohydroxamic acid-cupferron, salicylohydroxamic acid-TBP , F〓-TBP, cupferron-benzohydroxamic acid etc. for cassiterite flotation and mixed aliphatic acid or aliphatic amine for beryl or spodumene flotation.

研究过程中，本文选用了如下具体实例：苄基胂酸与丁基黄药浮选黑钨矿，水杨羟肟酸与F〓、水杨羟肟酸与铜铁灵、水杨羟肟酸与磷酸三丁酯、F〓与磷酸三丁酯、铜铁灵与苯异羟肟酸两两结合浮选锡石，混合脂肪胺与混合脂肪酸浮选锂辉石与绿柱石。

It is a organic hexahydric weak acid. In different acidity, the dissociation degree and the color of reagent solvent were different also. Determined and draw the absorption curve of reagent in varies acidity, and figured out the dissociation constant by Perisic-Janjic method; the complex ratio of the reagent and bismuth was determinated by mole ratio method and continuous variation method; The apparent stability constant of the complex was calculated, the mechanism of dissociation and coordination were discussed.

2，6—二溴4—硝基偶氮氟胂是本实验室合成的测定铋的一个较好的试剂，对其进行了进一步的研究，在用柱层析法对其进行了提纯后，测定了试剂在不同酸华东师范大学硕：l：学位论文摘要度下的吸光度和最大吸收波长，绘制了其吸收曲线，用Perisic一Janjic法计算了试剂的六级离解常数；用摩尔比法和连续变化法测定了试剂与秘形成的配合物的络合比：计算了配合物的表观稳定常数，研究了其离解和配合机理，为筛选高效有机显色剂提供了理论依据。

Effect of several collectors on fersmite artificially synthesized under the condition of variable pH values and dosages were studied. The collecting characteristic of several representative collectors such as benzyl arsionic acid,α-styrolphhosphonic, diphosphonic acid, cyclic alkyl hydroximic acid and C(subscript 7-9) alkyl hydroximic acid was researched.

研究了几种捕收剂在不同pH值和不同用量条件下对人工合成的铌钙矿的捕收效果，考察了苄基胂酸，苯乙烯膦酸，双膦酸，环烷基异羟肟酸，C(下标 7~9)烷基异羟肟酸等几种代表性的捕收剂的捕收性能。

Results showed that the new type rhodanine ramifications were good performance fluorescence reagents to determine the trace matter by fluorescence analysis.

同时，通过对上述试剂在测定铁、钴、铜、锡和锑时的条件的变化的研究，对这类试剂的分子结构和荧光性能的内在关系作了简要的探讨，讨论了供、吸电子基团对胂酸基偶氮若丹宁类衍生物荧光分析性能的影响。

The sixth part: The spectrophotometric performance of the new type aresenoxylphenylazo rhodanine and carboxylphenylazo rhodanine ramifications was mainly studied.

第六部分：主要研究了几种新型含胂酸基、羧基若丹宁衍生物的分光光度性能。

The fourth part: The influence of various active groups on the fluorescence performance of aresenoxylphenylazo rhodanine ramifications was studied systematically to seek the fluorescence reagents of good analysis performance.

第四部分：系统研究了各种活性基团对含胂酸基偶氮若丹宁衍生物荧光性能的影响，以寻求具有优良分析性能的荧光试剂。

The influences of groups -CH〓 and -Cl on the fluorescence analysis performance of aresenoxylphenylazo rhodanine class were mainly studied.

主要系统研究了-CH〓、-Cl基团对含胂酸基苯偶氮若丹宁衍生物荧光分析性能的影响。

The fluorescence characteristic of aresenoxylphenylazo rhodanine and the influence of-F,-Cl,-NO〓 and -OCH〓 on the fluorescence analysis performance were studied.

首次研究了胂酸基偶氮若丹宁的荧光性质，系统研究了-F、-Cl、-NO〓、-OCH〓基团对其荧光分析性能的影响。

Low valent selenium and telluronium compounds have high reducing selectivity to be used to form carbon-hydrogen bonds as special reducing reagents.

低价硒、碲化合物具有良好的还原选择性，可用于多种碳-氢键的形成，碲叶立德和α-芳硒基取代的胂叶立德均可发生Wittig型反应，是形成碳-碳双键的重要方法。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。