聚酰亚胺

The preparation process of self-holing polyimide with organosilicon block includes the following steps: 1 the first reaction of polyacid anhydride in functionality not lower than 2, silicon oil with 2 or more amino or imino groups and polyamine with 2 or more amino groups, and the second reaction with one or several kinds of added isocyanate with 2 or more isocyanate radicals to produce sol of polyamido acid containing organosilicon block; 2 solidifying the sol to obtain solid polyamido acid containing organosilicon block; and 3 imidonating the solid to obtain self-holing polyimide with organosilicon block.

本发明公开了一种有机硅嵌段自发孔聚酰亚胺的制备方法，该方法包括以下步骤：(1)有机溶剂中具有大于或者等于2的酸酐官能团度的多酸酐与具有大于或者等于2的胺基或亚胺基的硅油以及具有大于或者等于2的胺基的多胺反应，随后添加一种或多种具有含有等于或者大于2个异氰酸酯基的异氰酸酯反应，生成含有机硅嵌段聚酰胺酸的溶胶。(2)溶胶固化制成有机硅嵌段聚酰胺酸固体。(3)固体亚胺化，即得有机硅嵌段自发孔聚酰亚胺。

As the widely used resin matrix and composites, two kinds of epoxy matrix and its CF/epoxy composite and GF/composite have different mechanics property under different temperature. The result shows that the thermal property of the composite mainly depends on the matrix. If the matrix can resist high temperature, its composite can also have high strength under high temperature. resin matrix composite, thermal resistance, thermal deformation coefficient, severity retentivity ratio

多年来 ，人们一直致力于耐高温复合材料的研究工作，在耐高温树脂中能经受长期高温氧化的热固性树脂只有聚酰亚胺，本文主要研究三种树脂基复合材料在不同温度下的性能，即以聚酰亚胺为基体的复合材料以及两种环氧基复合材料在不同温度的性能。2 实验2 。1 材料选择研究中所用的增强材料选用英国考陶尔兹公司T30 0型碳纤维和进口UM - 40碳纤维以及南玻院S2高强玻璃纤维

The company has LED Packaging Tape Products Tape, PCB using high temperature Polyimide Labels, AB tape, printed circuit board-specific red tape, PET spray protection shelter Guarding security tape, polyimide tape, high temperature Masking Tape , Nomex tape, hot melt adhesive tapes, tear tapes, Cold tape, paper tape Tape, PET fixed tape, glass fiber tape, PTFE tape, etc., and another coated silicon, fluoride, etc. from the products, and a variety of fitting , die-cutting process.

公司主要胶带产品有LED封装胶带、PCB用聚酰亚胺高温标签、AB胶带、印刷线路板专用红胶带、PET喷涂遮蔽保保护护胶带、聚酰亚胺胶带、高温美纹胶带、Nomex胶带、热熔胶带、撕带、冷压胶带、编带纸带、PET固定胶带、玻纤维胶带、PTFE胶带等，另有涂硅、涂氟等离型产品，并进行各种贴合、模切加工。

Polyimide films were thermally treated at different temperatures ranging from 100℃ to 270℃.

薄膜的后热处理温度对聚酰亚胺的性能有重要影响，从而影响到聚酰亚胺表面LIPSS的制备。

In this article,recent advances in thermosetting polyimide resin are presented.

在聚酰亚胺材料家族中，热固性聚酰亚胺是重要的一类。

The aerocraft materials are required to have high resistance to elevated temperatures by the development of spaceflight techniques.

在耐高温聚酰亚胺的研究中，耐热性的提高主要是从设计聚酰亚胺的分子结构上入手的。

The copolycondensation type polyamic acid was synthesized by using 3,3', 4,4'-Benzophenonetetracarboxylic dianhydride as the dianhydride monomer, 4,4'-Diamino diphenylmethane and 4,4'-Oxydianiline as the diamine monomer under microwave irradiation in Dimethylformamide.

在微波辐射条件下，采用3，3'，4，4'-二苯酮四羧酸二酐、4，4'-二氨基二苯甲烷和4，4'-二氨基二苯醚为单体，N，N'-二甲基甲酰胺为溶剂，低温合成一种共缩聚聚酰亚胺的前驱体聚酰胺酸，化学亚胺化脱水环化生成BTDA型共缩聚聚酰亚胺。

The results showed that new type structure of organic phase containing inorganic phase between polyimide and titania particle by bond conjunct was formed.The discomposing temperature was decreased with the increasing of TiO2 contents,and the thermal stability was better than polyimide materials under the temperature of 450℃.The pore size increased with the increasing of TiO2 contents,and pore size distribution tended to disperse.The permeability of N2,H2 and CO2 across the membrane were controlled by Knudsen diffusion,and the memebrane exhibited outstanding hydrophilicity since their permeation coefficients of H2O／N,are higher than the Knudsen diffusion values.

结果表明，杂化膜材料形成了有机相包裹无机相的交联结构；聚酰亚胺与二氧化钛粒子形成了新型键联结构；其热分解温度随二氧化钛含量的增加而降低，在 450℃以下热稳定性优于聚酰亚胺膜材料；平均孔径随二氧化钛含量增大而增大，孔径分布趋于弥散；N2、H2和CO2在膜内渗透由Knudsen扩散控制，H2ON2分离因子均大于Knudsen扩散值，表现出良好的亲水性。

Polyimide films capped with nonreactive phthalimide end groups were synthesized with theoretical number average molecular mass of 10000 and 30000 calculated using the Carothers equation. The effect of end-capper on the thermal properties was studied by investigating the change of the glass transition temperature T(subscript g of films after cured at high temperature.

制备了经邻苯二甲酸酐封端的理论数均分子量为10000和30000的聚酰亚胺薄膜，通过差示扫描热分析测定薄膜高温热处理前后玻璃化温度的变化，研究了PA封端对ODPA/ODA聚酰亚胺薄膜热稳定性能的影响。

With the in-situ single-stage self-metallization protocol,surface-silvered polyimide film has been prepared using pyromellitic dianhydride/ 4,4\'-oxydianiline-based polyimide as the matrix and (1,1,1-trifluoro-2,4-pentadionato)silveras the silver precursor.

在原位一步自金属化法中，以均苯四甲酸酐/4，4\'-二胺基二苯醚基聚酰亚胺为基体，以三氟乙酰丙酮银作为银的母体制备出了表面金属化的聚酰亚胺银复合薄膜。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。