聚苯乙烯

In this paper octadecyl acrylate-maleic anhydride copolymer were prepared and used as compatibilizing agent of the blend system of polypropylene,starch and inorganic filler,which can be used as photo-biodegradable plastic.

采用丙烯酸十八酯-马来酸酐的共聚物作为聚丙烯(PP1330)淀粉无机填料共混体系的相容剂，制成的共混材料，代替聚苯乙烯发泡体作为可降解的一次性餐饮具。

The organic montmorillonite VC18-MMT was prepared by the exchanging inorganic cations with vinylbenzyldimethyloctadecylammionun chloride which could be co-polymerized with styrene.The predispersion of VC18-MMT was realized via sonicating the suspension of the montmorillonite particles in emulsifier solution,and then the styrene was added into the system and the in situ emulsion polymerization was carried out to prepare PS/VC18-MMT nanocomposites.

以可与苯乙烯发生共聚的阳离子表面活性剂乙烯苄基二甲基十八烷基氯化铵为插层处理剂改性蒙脱土（VC18-MMT），有机蒙脱土在超声波强剪切作用以及乳化剂作用下预分散在乳化剂溶液中，然后引入苯乙烯单体进行原位乳液聚合制备聚苯乙烯/蒙脱土纳米复合材料。

The research of polymer/layered silicate nanocomposite was introduced detailedly, including the classify, property and the latest research advance. On the basis of consulting the document and the exploratory experiment, the experimental method which first creative preparing poly (acrylonitrile-vinyl acetate)/raontmorillonite nanocomposite by emulsion intercalation copolymerization was established; the structure and property of polyacrylonitrle different molecule weight with inorganic mineral super fine nanocomposite was reseached. The reaction principle of PMMA by photo-initution was explored. The mixture principle with productor condition, property of PE/Clay nanocomposite milt insert was seal prived. By PS/Clay nanocomposite munufacture, the monomer ins-polymerization and polymerial solution was proved.

在查阅文献和探索性实验的基础上，确定采用乳液原位插层聚合方法首先创制了聚/蒙脱土纳米复合材料，利用正交实验得出了最佳实验条件，通过X射线衍射和红外光谱对纳米复合材料的结构进行表征，研究了复合材料的溶解性能，并测定了其溶液的绝对粘度；研究了不同相对分子质量的聚丙烯腈与不同的无机矿物超细粉复合材料的结构与性能；探讨了在蒙脱土中光引发聚甲基丙烯酸甲酯的反应机理；通过聚乙烯与粘土的纳米复合材料制备，探讨了热塑性树脂熔融插层复合机理与最佳工艺条件和复合材料性能关系；通过聚苯乙烯与蒙脱土纳米复合材料制备，验证了单体原位聚合插层和聚合物溶液插层机理。

Thirdly, The preparation of 3-aryl-5-substituted-ethenyl isoxazoles and l-isoxazolyl-2-isoxazolinyl substituted-ethenes was developed through 1, 3-dipolar cycloaddition of nitrile oxides,α-alkylation reaction and another 1, 3-dipolar cycloaddition of nitrile oxides based on polystyrene-supported propargyl selenide.

三、从聚苯乙烯负载的炔丙基硒醚出发，经过腈氧化物的1，3-偶极环加成反应、α-烷基化反应和腈氧化物的1，3-偶极环加成反应固相分别合成了3-芳基5-取代--乙烯基异噁唑和1—异噁唑—2—异噁唑啉取代的-乙烯。

Fourthly, The preparation of 1 -triazolyl-2-isoxazolinyl substituted-ethenes was developed through an one-pot 1, 3-dipolar cycloaddition of NaN_3 and RI,α-alkylation reaction of substituted allyl bromides and 1, 3-dipolar cycloaddition of nitrile oxidesbased on polystyrene-supported propargyl selenide.

四、从聚苯乙烯负载的炔丙基硒醚出发，通过与叠氮化钠和碘化物的一锅法1，3-偶极环加成反应、取代烯丙基溴的α-烷基化反应和腈氧化物的1，3-偶极环加成反应固相合成了1—三唑—2—异噁唑啉取代的-乙烯。

The resin is prepared by swelling chlorine balls in a solvent such as nitrobenzene; adding catalyst to obtain polystyrene-divinylbenzene adsorptive resin; removing reaction mother solution; washing to remove residual solvent and catalyst; swelling; adding pyrane reagent to further react with chloromethyl residual on inner and outer surfaces of the resin to obtain the pyranyl modified adsorptive resin with the composite function.

该树脂的制备方法：将氯球溶胀于硝基苯等溶剂中，加入催化剂，得到聚苯乙烯-二乙烯苯吸附树脂；抽尽反应母液，洗去残留的溶剂和催化剂；溶胀，加入吡喃试剂与树脂内外表面残留氯甲基进一步反应，可制得吡喃基修饰复合功能吸附树脂。

Preparation of polymeric nanocapsules by radiation induced miniemulsion polymerization (1) Polystyrene nanocapsules with liquid core were prepared by ~(60)Coγ-ray radiation induced miniemulsion polymerization, in which N-vinyl pyrrolidone was used as polar monomer.

本文首先通过辐射引发细乳液聚合制备了聚苯乙烯纳米微胶囊，并从热力学与动力学两方面研究了影响纳米微胶囊形貌的因素；之后使用反相乳液聚合制备了磁性复合微球和磁性复合空心微球，并研究了有关影响因素。

The results showed the addition of OMMT was beneficial to improve the mechanical properties, flame retardance, and thermal stability of HIPS matrix.

结果表明，OMMT的加入有助于提高高抗冲聚苯乙烯基体的力学性能、阻燃性能和热稳定性。

With the increase of Mg2, the concentration of CO2 gradually reduces, and the majority of the volatile and semivolatile organic products, especially styrene monomer and some polycyclic compounds, take on increasing tendencies.

随着氢氧化镁含量的增加，二氧化碳的浓度逐渐降低；残渣中焦碳的含量以及大多数的挥发性和半挥发性有机产物，尤其是聚苯乙烯单体和一些多环化合物明显增加。

At wall-floor connections a sheet of expanded polystyrene is inserted which acts as thermal insulation at this point and also as permanent shuttering.

在相邻面墙和地板的接缝中放进一层聚苯乙烯泡沫，使接缝处能充分的隔热防寒。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。