聚合的

This model was finely fitted by theexperimental results and was used to calculate the activation area,which was 0.127 〓/mol with little dependence of subphasetemperature. The positive activation area indicate that there is anincrease in area when the activated complex is formed, increasingthe surface pressure should decrease the rate constant and that theactivated complex is unimolecular in nature.

在一系列实验曲线的基础上，我们提出测量的面积变化应该由聚合中分子结构变化引起的急剧的瞬时面积变化与随后的与此面积变化相反的弛豫过程两部分组成，并据此提出一种反应动力学模型，此模型与实验结果相当吻合，此模型用于处理聚合速率的紫外光强依赖性，得到聚合速率常数近似与光强成二次幂指数关系；此模型也被用于计算活化面积，发现活化面积为〓，几乎与温度无关。

A series homopolyme of ethylene synthesised by metallocene catalyst was analyzed by the high temperature gelatin permeation chromatography. The results showed that the molecular weight distribution changed not too much when the ratio of Al/Ti ranging between 1000 and 4000, while the molecular weight distributed increased from 2.48 to 2.81 when the ratio ranging between 4000 and 7000; catalyst D had the lowest activity to be used as asymmetric metallocene catalyst; the curve of molecular weight moved much to the left with the increases of temperature and two active centres appeared when the temperature is 70℃.

通过高温凝胶渗透色谱对茂金属催化合成的一系列乙烯均聚物进行了分析，可以看出Al/Ti比从1000变到4000时，分子量分布曲线图变化不大，而从4000变到7000时，变化相当大，分布宽度从2.48增至2.81；催化剂D的活性最小，可作为非对称性茂系金属催化剂；该聚合体系分子量的大小受聚合温度的影响很明显，随温度的升高，分子量分布曲线图向左发生很大位移，在聚合温度为70℃时存在两个活性相当的活性中心。

Through lots of tests, the new technology of preparing the polymeric ferric aluminum silicate sulfate by using the waste-acid of Ti02-industriy and the coal fly ash has been designed. The highest Al-acid stripping rate can be achieved by the waste sulfate acid under boiling degree for 1. 5h when the mass ratio between NaCl and Coal Fly ash is 0. 05:1, as well as that between Coal Fly ash and Waste Acid ratio is 1:10. By means of the oxidation-polymerized reaction under 40-50*C and normal pressure, using NaNCkas catalyst and air as oxidation, the polymeric ferric aluminum sulfate can be obtained. The poly-silicic acid is polymerized with soluble glass in the optimum conditions of pH=5-6 and the concentration of Si02 is about 3%. The inorganic high molecule coagulant of PFASS is synthesized with the poly-silicic acid into the solution of polymeric ferric aluminum sulfate.

本论文通过大量的试验，研究开发出了用粉煤灰及钛白废酸制取聚合硫酸硅酸铁铝的新工艺，其最佳工艺条件为：于沸点温度，以NaCl为助溶剂(NaCl与粉煤灰质量比为0.05：1)，以钛白废酸浸取粉煤灰(固液比为1：10)中的铝1.5小时，最大浸取率可达40％；经过滤洗涤后，调节滤液pH至2.0左右，以NANO_2为催化剂(NaNO_2用量为滤液中FeSO_4·7H_2O量的3％)，空气为氧化剂，于40-50℃进行常压催化氧化反应，制取聚合硫酸铁铝，催化氧化时间为2小时；将工业水玻璃稀释至3％左右，调节其pH于5-6，室温下制备活性聚硅酸；将活性聚硅酸与聚合硫酸铁铝按照一定比例复合，经熟化，即制得新型无机高分子混凝剂PFASS。

The polymerization systems can be divided into four categories: styrol, acrylate, hydrophilic and non-ethylene according to the difference of the structure and characteristic of the monomer.

总结了目前各种不同组成的分散聚合体系，按单体的结构、性质的差异，分别介绍了苯乙烯类、丙烯酸酯类、亲水性单体类、非乙烯单体类的分散均聚合研究情况，列出了各种分散聚合体系中的介质、稳定剂和引发剂等组成。

Various mole ratios of acrylonitrile and methyl methacrylate were used to copolymerize in aqueous solution by Redox and the copolymers were obtained. The copolymers containing MOCT were synthesized by adding MOCT before copolymerization. The copolymer were derived from the copolymerization of AN and MMA in 30L kettle and then were mixed with various contents of MOCT, the copolymer films were cast by solution of the copolymer containing MOCT.

本课题采用不同摩尔比的丙烯腈和甲基丙烯酸甲酯进行水相沉淀聚合，制备了AN／MMA共聚物；在聚合阶段加入正十八烷微胶囊，制得了正十八烷微胶囊含量不同的共聚物；选择合适的条件进行大釜聚合，得到共聚物后与不同比例的正十八烷微胶囊混合，通过流延制得正十八烷微胶囊含量不同的共聚物膜；并尝试进行了纺丝实验。

The photopolymerization led to stable latices and they were obtained with neither coagulation during synthesis nor destabilization over time. It was found that the obtained MMA homopolymers exhibited relatively narrow molecular weight distributions(PDI=1.27—1.36), which was characterized by GPC. The plots of number-average molecular weight vs. conversion and ln([M0]/) vs. time were linear respectively, indicating that the reaction was a controlled/living free radical polymerization.

结果表明，该细乳液体系非常稳定，在整个聚合过程中即没有絮凝物产生，也没有沉淀析出，获得了良好的ln([M0]/)与时间、数均分子量与转化率之间的线性动力学关系，并且在整个聚合反应过程中MMA均聚物的分子量分布比较窄，其多分散性指数较低(PDI=1.27~1.36)，具有明显的活性聚合特征。

Secondly, according to the construction and characteristic of the N-isopropylacrylamide and the temperature-sensitivity of PNIPA hydrogel, Pdualistic hydrogel was synthesized by microwave low temperature plasma. The effects of the factors on the swelling characteristic of P dualistic hydrogel, such as treatment time and power of plasma, concentrations of crosslinking agent and total monomers, proportion of AMPS, polymerizing temperature etc, was discussed in detail. The three dimensions structure , thermostability , reversional volume , swelling/deswelling kinetics, temperature-sensitivity and pH-sensitivity of the hydrogel were also investigated. The optimal synthesizing technics of P dualistic hydrogel initiated by microwave low temperature plasma was confirmed.

在此基础上，结合NIPA的结构特征和PNIPA的温敏性，用微波低温等离子体引发聚合了P二元智能凝胶，详细探讨了微波低温等离子体处理功率、处理时间、总单体浓度、AMPS单体浓度、交联剂浓度及聚合反应溫度等因素对P二元凝胶溶胀性能的影响；并对其三维交联结构、热稳定性、失水-吸水动力学、温度敏感性、pH敏感性、体积复原性等进行了研究；确定了适合微波低温等离子体引发聚合P二元智能凝胶的最佳工艺。

Factors exerting influence are discussed, such as amounts of initiator and crosslinker, pH value of water phase, polymerizing temperature, as well as inductive time.

研究引发剂用量、交联剂用量、水相pH值、聚合温度和诱导时间等因素的影响，得出的最佳聚合条件为：引发剂用量为共聚单体质量的0.18%，交联剂用量为共聚单体质量的0.27%，pH值6.5，聚合温度65~75℃，诱导期40~60min。

As far as the Fe catalytic system, the higher the Al/Fe molar ratios, the stronger Lewis acidities and the higher reactivates of carbon-aluminum bond in the cocatalysts resulted in the higher polymerization activities.

以铁配合物为主催化剂时，各种助催化剂催化乙烯聚合活性随Al／Fe比的增加而升高；助催化剂的Lewis酸性越强，其分子内碳—铝键的反应活性越高，聚合体系的聚合活性则越高。

Effects of the mol ratio of acrylic acid/vinyl acetate and the churn-dasher on conversion, molecular weight and molecular weight distribution of the obtained polymers were investigated by gravity method and gel permeation chromatography.

通过聚合转化率和凝胶渗透色谱的测定，研究了聚合过程和所制备聚合物的分子量及其分布，以及丙烯酸对聚合物分子量分布的影响；进一步探讨了反应装置的安装及结构对聚合反应的影响。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。