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The preparation of polymer/montmorillonite intercalation composite materials has been studied by applying two kinds of photo polymerization reaction (photo acid generation and photo radical generation)in this work.

用小角X光衍射技术对产物内蒙脱土的结构进行表征,结果表明,蒙脱土经改性后能很好地使聚合单体及预聚物插入黏土层内并在光照下"就地"聚合生成光聚合复合材料。

At first, the polymerization characteristic of BMA was discussed in the paper, by contrast with MMA, using the instrument dilatometer. It was confirmed that the polymerizing activity of BMA was lower than MMA, and its polymerizing condition was stricter.

本文首先对甲基丙烯酸丁酯和甲基丙烯酸甲酯的聚合特性进行了对比研究,用膨胀计法测定了两者在不同引发条件下的聚合动力学,证实了甲基丙烯酸丁酯的聚合活性比甲酯要低,聚合条件更为严格。

C Thermally controllable light valves:As described above, the clearing temperature of PDCLCs can be increased by UV-curing because of the reduction of impurity concentration. Therefore, when the texture of a CLC cell in the UV-cured region are changed to focal conic one, the scattering of light from the sample is maximum. However, the clearing temperature of PDCLCs can be increased continually with continually irradiating with UV light onto the sample, but the scattering is unchanged.

当PDCLC照射紫外光的时间超过某一特定时间,则表面配向被聚合物薄膜破坏而达成散射态之穿透度最低状态,若持续照光聚合时,因仍然处於focal conic态,故穿透度不再改变,但单体聚合造成相变温度上升,直到单体全部聚合为止。

The synthesis of flame retardant for cotton with a new catalytic system ;2. Advances in the catalytic system s for synthesis of terephthalic acid via oxidation of paraxylene

在不同二苯基二甲氧基硅烷用量、聚合温度及聚合时间等条件下,考察DDS对α-烯烃聚合载体型催化体系活性中心的影响。

After photopolymerization, the lc molecules are confined by a thin polymer layer and polymer walls which define the cell gap.

在光聚合作用后,液晶分子则受到薄聚合层和确定液晶盒间隙聚合墙的限制。

With longger perianth segment and Liriodendron tulipiferawith widder perianth segment. The length of fruit ahd number of little key fruits showed patroclinal transgressive inheritance, so Liriodendron interspecific hybrids with bigger fruit could be selected by Liriodendron tulipifera?

聚合果长度和聚合果具翅小坚果数表现为偏父超亲遗传,选用聚合果较长和聚合果具翅小坚果数目较多的的北美鹅掌楸作父本,有望选育出大果的杂交鹅掌楸个体,而且这两者呈显著正相关(r=0.888)。

Result of thermogravity analysis showed that the thermal stability of polyvinylamine chloride lowers with increasing in amination degree. Moreover, properties of dilute aqueous solutions of three types of poly chloride with different amination degree were compared by use of viscosimetric, conductometric, and potentiometric measurements. Results showed that both the electrostatic interaction of neighboring groups on the chain and the reduced viscosity of poly chloride are increased with increasing the degree of amination of poly . The equivalent conductivity is decreased with the increasing the concentration of poly chloride and increased with the increasing the amination degree of poly .

研究了聚乙烯胺盐酸盐的热稳定性和水溶液性质,发现:随着胺化度的提高,聚乙烯胺盐酸盐的对热稳定性逐步降低;聚乙烯胺盐酸盐是一种典型的聚电解质,其水溶液的pH值随平均分子量的变化并不明显,而随着聚乙烯胺胺化度的升高,pH值降低;随着聚乙烯胺盐酸盐的平均聚合度由82.3增加到201.8,它的m值(用于表征聚电解质侧链基团之间相互作用大小的常数)从5.13升高到5.58,而当聚乙烯胺盐酸盐的平均聚合度增加到311.4时,它的m值反而降低到了5.48;随着胺化度由55.65%升高到82.36%,m值由3.65提高到5.50;随着聚乙烯胺盐酸盐的平均聚合度的提高,聚乙烯胺盐酸盐的平均解离常数由7.48降低到7.26,同时随着胺化度的提高,聚乙烯胺盐酸盐的平均解离常数也由8.33降低到7.37;随着聚乙烯胺盐酸盐浓度的提高,溶液的摩尔电导率逐步降低,随着聚乙烯胺胺化度和聚合度的提高,溶液的摩尔电导率有所升高;在pH值为4左右时,聚乙烯胺盐酸盐的比浓粘度分别达到极值,而与聚合度的大小关系不大;聚乙烯胺盐酸盐的特性粘数明显高于其原料聚丙烯酰胺的特性粘数,分子量对特性粘数的影响十分明显,胺化度对特性粘数的影响并不显著。

In order to reflect the catalyst deactivation during the oxidative polymerization and difference of the reactivity between monomer,the oligomer soluble in water,and the oligomer unsoluble in water,a new heterogeneous kinetic model was proposed according to Flory statistical theory.It was found that the polymerization rate estimated by the new model was consistent with the calculated data.

根据DMP氧化聚合过程中催化剂随时间延长而逐渐失活,不同种类的苯氧阴离子活性不同以及非均相聚合特点,提出了水介质中DMP氧化聚合动力学模型,并采用多元非线形回归计算得到模型参数,采用模型计算得到的聚合速率与实验测定值一致,证明所提出模型的正确性。

The polymerization of preparing PDA could be impacted by allyl chloride, allyl alcohol and allyl aldehyde. The content of allyl chloride, allyl alcohol and allyl aldehyde in the DMDAAC monomer solution varied from 0mg/kg to 1000mg/kg, their intrinsic viscosity of PDA descended from 10.3dL/g to 8.0dL/g, 6.8dL/g and 8.8dL/g respectively. The polymerization of preparing PDA could be carried out well in the case the content of NaCl, active carbon, yellow residua and low molecular polymer of DMDAAC were less than 10000mg/kg, 1000mg/kg, 1000mg/kg and 50000mg/kg respectively.

单一杂质含量变化对聚合产物PDA特征粘度影响的研究结果表明:在DMDAAC单体溶液聚合反应过程中,当Fe~(3+)、Fe~(2+)和Cu~(2+)含量分别达到7mg/kg、9mg/kg和5mg/kg时无法得到聚合产物PDA胶体;当烯丙基氯、烯丙醇、烯丙醛含量分别从0mg/kg增加到1000mg/kg时,聚合产物PDA的特征粘度从10.3dL/g分别下降到8.0dL/g,6.8dL/g和8.8dL/g;活性炭和黄色物质含量在1000mg/kg以下,低聚物含量在50000mg/kg以下以及氯化钠含量在10000mg/kg以下时产物PDA的特征粘度降低变化量不超过0.2dL/g。

Based on the pure styrenes polymerization, the inhibited polymerization by inhibitor was studied. The effect of polymerization temperature, the addition of ethylbenzene, the content of inhibitor, and the compound of inhibitors was measured for the bulk thermal polymerization of styrene.

在纯苯乙烯聚合基础上,着重考察了阻聚剂(缓聚剂DNBP和阻聚剂M)阻聚下苯乙烯的聚合行为,并系统研究了聚合温度、乙苯含量、缓聚剂及阻聚剂含量、阻聚剂的复配对苯乙烯本体热聚合动力学的影响规律。

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With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐,因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。

Closes the eye, the deep breathing, all no longer are the dreams as if......

关闭眼睛,深呼吸,一切不再是梦想,犹如。。。。。。