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A new method to separate the anodic peaks of asorbic acid and dopmine was reported in this paper.

推导了电化学聚合苯胺的聚合速率方程,重点讨论了聚合电位对聚合速率的影响。

At present, the application in the packaging business card printing and membership card making the UV light oil formation, in addition polymerization, the film uses initiator aggregation and energy initiating two forms (both called conglutinate, that is, light oil system of conglutinate in the ultraviolet radiation occurs under resin polymorization formation of varnish film, known as UV-curing on).

目前,应用在包装制卡和会员卡制作制品上的UV光油,除氧化聚合形成外,薄膜采用引发剂引发聚合和能量引发聚合两种形式(均称为光敏树脂,即光油体系的光敏树脂在紫外线照射下树脂发生聚合反应形成的光油薄膜,称为紫外线固化上光油)。

The influences of polymerization conditions such as the dosage of cyanobenzene, catalyst, co-catalyst and polymerization temperature on the polymerization (gelation time and monomer conversion) and the swelling value of PDCPD were investigated.

考察了主要反应条件如苯甲腈的用量、聚合反应温度、主催化剂的用量和助催化剂的用量等对聚合反应速率、聚合反应转化率和PDCPD膨胀值的影响,并得到了最优的聚合反应条件:苯甲腈与WCl_6的摩尔比为3,聚合反应温度为70℃,DCPD与WCl_6的摩尔比为1500,Et_2AlCl与WCl_6的摩尔比为11。

Specifically, itcontains 8 chapters.In chapter 1, the formation, structures, properties and the futureprospect of liposome were thoroughly reviewed;In chapter 2, the stibility and permeability of phopholipid -eleostericacid liposome were studied together with the effect of polymerizationof eleostearic acid. This membrane system was very sensitive to 〓,the effect of 〓 was clarified to increase the aggregation/fusion ofliposomes and made the permeability of mixed liposomes much higher;In chapter 3, two polymerizable conjugated diyne bolaamphiphiles were synthesized. They could form very stable mixed liposome, andthe diyne could be polymerized by UV light in bilayer liposomes, as aresult, the stability of mixed liposome against solvent or surfactantafter polymerization were enhanced. In chapter 4, two kinds of amphiphilic amino acids were synthesized andstable liposomes were formed therefrom After the condensationpolymerization of amino acid in bilayer liposomes, stable polypeptide liposomes were obtained, which had lower phase transition temperatureand higher permeability.In chapter 5, four kinds of glycolipids were synthesized and theiraggregation behavior in water was comparied. When incorporated intophospholipid bilayer membranes, they could increase the phase transitiontemperatures and inhibit the aggregation and fusion of mixedliposomesat lower temperature.In chapter 6 and 7, three kinds of steroidal bolaamphiphiles withdifferent chain lengths were synthesized. Incorporation of steroidalmoiety to the center of lipid bilayer membrane obviously increased themobility of lipid membrane and shifted Tc to lower temperature side incomparasion with cholesterol. The bolaamphiphile which was shorter thanthe hosted lipid bilayer membrane thickness influenced the lipid packingmore obviously.

全文共分8章:第一章对脂质体的形成、结构、性质及展望进行了较为详细的文献综述;第二章研究了磷脂-桐酸脂质体的稳定性,通透能力及桐酸的聚合对这些性质的影响;磷脂-桐酸混合脂质体为一类对〓灵敏的脂质体,〓的作用首先是使脂质体集聚然后使脂质体融合,并加速内包荧光物的释放;第三章通过合成两种可聚合共轭双炔双极性双亲分子DDCA,DDOL,研究了共双炔分子在双分子层脂质体膜上的聚合及对脂质体性质的影响,聚合可以提高脂质体相对于溶剂及表面活性剂的稳定性;第四章合成了两类氨基酸为极性基团的双亲分子,它们均可以在超声下形成稳定的脂质体结构;氨基酸基团可以在脂质体上进行缩聚反应,若聚合后脂质体表面仍有足够的亲水能力,则可得到稳定的多肽型脂质体;聚合后脂质体的相变温度降低,通透能力增加;第五章合成了四种亲水基团为单糖基的双亲分子GL-l,GL-2,GL-3, GL-4,研究了它们在水中的分散情况、集合体形态与分子结构的关系;在DMPC双分子层膜中加入糖脂分子可以使脂质体的相变温度提高,阻止脂质体在低温放置时的集聚与融合;第六章-第七章合成了三种不同碳链长度的双极性含胆甾环双亲分子 CL-1,CL-2,CL-3;它们可以象胆固醇一样与磷脂混合形成稳定脂质体,胆甾环基团位于脂质体双分子层膜的中间;与胆固醇的作用相反,它们可以增加磷脂双分子层膜的流动性,降低混合脂质体的相变温度;三种分子的作用与其碳链长度和磷脂双分子层膜的厚度有关,比膜厚度短的分子影响最大。

Through changing various conditions, the conversion of polymerization was determined gravimetrically by sampling with an injector at different time in the course of polymerization system and it was found that conversion was increased linearly firstly and non-linearly finally along with reaction time.

通过改变单一聚合条件,在不同反应时间,利用注射器进行取样,称重法测定聚合物转化率,考察聚合条件的影响,说明此合成体系受单体/引发剂、催化体系、聚合温度、反应时间等因素的影响(如聚合温度90℃,反应时间12h时,产率可达90%以上)。

Due to great amount of double bond on rubber chain,a lot of intramolecular reaction occurred in the system,which made the uncontrolled cross-linked system into a controlled cross-linked copolymerization,resulting in chain growth can't go illimitably in cross-linking process.

苯乙烯和二乙烯苯共聚体系是典型的不可控制的交联聚合体系,加入天然橡胶后,通过阳离子聚合方法,生成三元共聚物线团,由于橡胶分子链上含有大量的双键,聚合体系中能进行分子内反应,使不可控的交联聚合体系成为可控的交联聚合体系,其链增长不能无限制进行,从而可以合成可溶解的交联的聚苯乙烯-二乙烯苯-天然橡胶聚合物。

A series of polymers containing 1,8-naphthalimide moieties in the side chains have been prepared via RAFT technique. Firstly, five styrene and two methyl acrylate based 1,8-naphthalimide monomers were synthesized and characterized. Then, carbazyl group terminated polystyrene was used as macromolecular RAFT agent.

我们合成了5种苯乙烯类和2种甲基丙烯酸酯类萘酰亚胺单体,以一种含末端带咔唑结构的聚苯乙烯为大分子RAFT试剂,考察了所得单体的RAFT聚合,发现苯乙烯类1,8-萘酰亚胺单体可以聚合,但是聚合度不高,甲基丙烯酸酯类1,8-萘酰亚胺单体RAFT聚合不可控。

The influence of reaction temperature, emulsifier and initiator on the preparation of micro - latexes was discussed with emphasis.

在概述乳液聚合及微乳液聚合特点的基础上,介绍了胶乳剪切分散法和微乳液聚合法制备超微胶乳,重点讨论了反应温度、乳化剂和引发剂对微乳液聚合法制备超微胶乳的影响。

The nuclei of eukaryotic cells contain three types of RNA polymerases: polymerase Ⅰ,Ⅱ and Ⅲ. They perform different functions in the cells.

真核生物的细胞核中具有三种不同的RNA聚合酶,分别是RNA聚合酶Ⅰ、RNA聚合酶Ⅱ和RNA聚合酶Ⅲ。

The copolymers were systematically characterized by elementary analysis, FT-IR, UV-visible spectroscopy, solution high-resolution 〓H-NMR and solid-state high-resolution 〓C-NMR spectroscopes, solubility examination; circular dichroism technique was firstly used to characterize chain structure of the copolymers.

本文通过在刚性的PD聚合物分子链中引入邻乙氧基苯胺链节,使用化学氧化聚合和电化学氧化聚合两类新型聚合方法,合成了三种PD异构体与PHT的共聚物,并进行了聚合反应、结构和性能表征的系统研究,并且比较了氨基的相对取代位置对聚合活性的影响。

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With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐,因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。

Closes the eye, the deep breathing, all no longer are the dreams as if......

关闭眼睛,深呼吸,一切不再是梦想,犹如。。。。。。