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The results showed that the thermo-sensitivity of hairy PNIPA changed obviously in the presence of hairy PAA as polyelectrolyte.4-cyanopentanoic acid dithiobenzoate as soluble reversible addition-fragmentation chain transfer agent was directly added into the above PS particles with photo-initiator on the surface and NVP or NIPA as monomer.

其次,将水溶性RAFT试剂直接引入上述光引发聚合体系,探讨连续相中RAFT试剂的存在对微球表面N-乙烯基吡咯烷酮或N-异丙基丙烯酰胺聚合的影响,考察了RAFT试剂对聚合过程中微球壳层高分子毛发厚度和单体转化率变化趋势。

Finally, the grafting polymerization of textile materials initiated by microwave low temperature plasma was conducted. Knitted cotton fabric was grafted by AMPS first, then knitted cotton and terylene/cotton fabrics were grafted with AMPS/NIPA dualistic monomers respectively. By means of grafting polymerization, the P dualisticintelligent hydrogel was added to textile.The influences of the factors on add-on, such as treatment time and power of plasma, concentrations of crosslinking agent and total monomers, proportion of AMPS, polymerizing temperature and time etc, was studied fully. The optimal conditions of grafting polymerization initiated by microwave low temperature plasma were determined by orthogonal design, variance analysis and mathematical statistics method so as to analyze the main influencing factors. Then swelling/deswelling kinetics, temperature-sensitivity and pH-sensitivity of grafted textile were studied. The performance indexes of hydrostatic pressure, moisture permeability and bursting strength of the knitted cotton and terylene/cotton fabrics before and after grafting were compared and evaluated synthetically.

此后用微波低温等离子体引发纺织材料的接枝聚合反应,分别研究了棉针织物接枝AMPS和棉、涤棉混纺针织物接枝AMPS/NIPA二元单体,使智能凝胶以接枝的方式添加到纺织材料上;详细探讨了微波低温等离子体处理功率和时间、总单体浓度、AMPS单体浓度、交联剂浓度及聚合反应温度和时间等因素对增重率的影响,通过正交设计、方差分析及数理统计对各影响因子进行分析,确定了微波低温等离子体引发接枝聚合的最佳工艺条件;对接枝纺织材料的失水-吸水动力学、温度敏感性、pH敏感性等进行了研究;对接枝前后棉、涤棉混纺针织物的静水压、透湿性和顶破强力等服用性能指标进行了对比和综合评价。

In spite of this, the preparation of thiol-end functionalized PMMA was achieved by introducing a short block of polystyrene after the RAFT polymerization of MMA.Third, RAFT technique was applied to design and synthesize some well-defined poymers. Five monomers, lauryl methacrylate,(N,N-dimethylamino)ethyl methacrylate, poly methyl ether methacrylate, 4-(4\'-cyanobiphenyl-4-yloxy) butyl methacrylate and 2-ethyl methacrylate were chosen to RAFT homopolymerization or copolymerizations mediated by cumyl dithiobenzoate.

RAFT方法在具有特定结构聚合物的设计与合成上的应用,在机理研究的基础上,本论文选择五种不同结构的甲基丙烯酸酯类单体:lauryl methacrylate,(N,N-dimethylamino)ethyl methacrylate,polymethyl ether methacrylate,4-(4'-cyanobiphenyl-4-yloxy)butyl methacrylate和2-ethyl methacrylate,用CDB调控RAFT聚合的方法设计合成了一些特定结构的聚合物,详细而深入地研究了它们的均聚、共聚动力学,发现了双硫酯并非在聚合反应初期就全部转化,而是随着反应进行逐步消耗,这与理想的活性聚合体系有很大差别。

The stability of isophorone disocyanate and the affecting factors of in-situ miniemulsion polymerization have been studied to carry out the simutaneous or two-step procesure of polyaddition and radical polymerization.

本文主要研究了水敏性单体IPDI的稳定性和原位细乳液聚合规律,探索在细乳液中分步或同步实现缩聚反应与自由基聚合的新方法,提出了水敏性单体的细乳液聚合实施方法。

The result indicate that P has much greater initiation ability in comparison with monomeric MABP, but P does not.

聚合的引发体系的优点在于它不仅能够引发聚合而且能够参与聚合,进人聚合物链中。

The recombinant MA can undergo trimerization and the NC contains an I domain that can promoter Gag-Gag interaction. Previous studies have shown that the assembly function of NC in Gag can be replaced by sequences that dimerize or multimerize.

MA有聚合的能力,而NC上的I domain也能促进Gag-Gag之间的聚合作用,研究证实,以一种能促使蛋白间产生聚合作用的序列可取代NC 在Gag组装过程中的角色。

1MM GTP was mixed with tubulin (2mg/ml) and varying concentrations of sodium selenite. The mixture was incubated at 37℃ for 1hr. MTs were separated from unassembled tubulin by centrifugation. Both supernatants and pellets were subjected to SDS-PAGE.

其中一组实验是在相同的微管蛋白体系中加入不同浓度的亚硒酸钠,然后加入GTP,37℃聚合,离心,沉淀为聚合的微管,而上清液为未聚合的微管蛋白。

Concentrated emulsion polymerization of styrene in the presence of two polymerizable surfactants, sodium undecylenic acid and newly synthesized CS-1 was carried out.

在苯乙烯的浓乳液聚合体系中,考察了两种可聚合的表面活性剂十一烯酸钠和新近合成的阴离子型羧酸盐类的表面活性剂CS-1的聚合行为。

Herein the latest developments of olefin aqueous polymerization which are mainly promoted by late- transition metal catalysts are reviewed including ethylene,α-olefins, cyclo-olefins and dienes polymerization, along with ROMP of cyclo-olefins and CO/olefins copolymerization.

本文综述了后过渡金属催化剂水相催化烯烃配位聚合的一些新进展,内容包括烯、α-烯烃、环烯烃、二烯烃的聚合反应和环烯烃的开环聚合反应以及CO/烯烃的共聚反应等方面。

The humidity resistance and the sensitivity to chemical warfare agents simulants of the tuned films were also investigated.Self-assembled LBL polyaniline films were prepared from aniline monomers by in situ polymerization and the mechanism of film formation was discussed. It was proposed that the self-assembly of polyaniline occurred through the quick absorption of aniline monomer cations or aniline monomer cation radicals on the glass surfaces by electrostatic attractions to form homogeneous polymerization centers, then increased gradually by the way of upright to the glass supports for extensity, leading to the polyaniline chain growth. The polyaniline was doped under acidic condition to absorb anionic polyelectrolyte, such as sodium polystyrene sulfonate based on the electrostatic force, or to adsorb polymer based on hydrogen-bonding interactions, for example Polyvinyl Alcohol, and then recycled to fabricate_n or_n self-assembled multilayer films.

跟踪了原位聚合的具有纳米结构的聚苯胺多层自组装膜的成膜过程,提出了该自组装膜的成膜机理:聚合反应初始阶段的苯胺阳离子或苯胺阳离子自由基通过静电作用快速吸附到带负电荷的基片表面,形成均匀的聚合中心,然后以垂直于基片的方式进行链增长生成PANI;PANI在酸性条件下经现场掺杂后带正电荷,再通过静电作用吸附带负电荷的聚电解质如聚苯乙烯磺酸钠,或通过氢键作用吸附聚合物如聚乙烯醇,这样循环LBL-SA即得到_n或_n等原位聚合聚苯胺自组装膜。

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