聚合的

Effect of polymerization by MTGase on the functionalities of sodium caseinate were studied, it showed that the viscosity, thermal stability and hydration property, emulsifying properties of sodium caseinate were improved remarkably, And the emulsifying activity index increased with the time of polymerization, and the emulsifying stability increased with the polymerization time at low degree of polymerization while declined at high degree of polymerization.

研究了MTGase聚合酪蛋白酸钠对其功能特性的影响，结果表明：MTGase聚合酪蛋白酸钠显著地提高或改善了粘度、水化性质、乳化性能，其中乳化指数随聚合时间的增加而增加，而乳化稳定性在相对较低聚合度时随聚合时间的增加而增加，然而在高聚合度时反而会有所下降。

The advantage of supercritical carbon dioxide used as an environmental medium in polymerization and reactions in supercritical carbon dioxide are described. It includes homogeneous free radical polymerizations, precipitation free radical polymerizations, dispersion free radical polymerizations, emulsion and inverse emulsion free radical polymerizations, cationic polymerizations, ring-opening polymerization, melt-phase condensation polymerizations, sol-gel polymerizations, polymer blend synthesis, catalytic chain transfer polymerizations, oxidative coupling polymerization, nitroxide-mediated radical dispersion, atom-transfer radical polymerization, reversible addition-fragmentation chain transfer polymerization, electrochemical polymerization, simultaneous one-pot combination of enzymatic and chemical polymerization, copolymerization of carbon dioxide used as monomer.

评述了ScCO2作为聚合反应介质的优点，以及在ScCO2中可进行的聚合反应类型，包括均相聚合、沉淀聚合、分散聚合、乳液及反相乳液聚合、阳离子聚合、开环聚合、熔融态缩聚、溶液-凝胶聚合、聚合物混合合成、链催化转移聚合、氧化-偶合反应聚合、氮氧自由基可控活性聚合、原子转移自由基聚合、可逆加成-断裂链转移、电化学聚合、原子转移聚合与酶催化开环聚合两种活性聚合在ScCO2中同时聚合、二氧化碳作为原料共聚合等。

This project studies the scale-dependent deformation behavior of the metal matrix composite, the void nucleation and void growth mechanisms at the micron/submicron scale. The main results are:(1) In prophase, growth and coalescence of the void embedded in the graded matrix are analyzed in detailed;(2) Based on the infinite solid model containing a micro-void, coupling effects of the void shape and the void size on the void growth are studied carefully, the results show that it seems to exist a critical equivalent void radius, which is associated with the material length. When radius of a microvoid is close to or smaller than the critical void radius, the micro-void growth rate is essentially eliminated;(3) The coupling effects of the particle shape and size on the mesoscopic stress fields within the particle and matrix are also investigated by introducing the conception of inclusion/matrix interfacial energy. The results show that the stress concentration factors within the particle and on the matrix/particle interface are also strongly size-dependent,so the void nucleation mechanism is size-dependent.(4) By employing a specific orthogonal curve coordinate frame and a 'kernel function' conception, a 'unified method'solving the spheriodal and spherical void problems is suggested; by this unified method, size-dependent plastic potentials of the porous materials containing the spheriodal or spherical voids are obtained, which extend the traditional Gurson model for the spherical void and GLD model for the spheriodal voids to the micron scale.(5) Based on the RVE model containing the spheriodal or spherical particles, the influences of the particle shape and size on the size-dependent mechanical behavior of metal matrix composite are studied.

中文摘要：本项目对金属基复合材料在微细观尺度下的尺度相关变形行为、孔洞形核及长大的机理和模型进行了研究，取得了如下主要结果：1）在前期研究中，探讨了基体的梯度分布对孔洞长大和聚合的影响；2）基于含孔洞的无限大体模型，探讨了孔洞形状和孔洞尺寸对其长大的耦合作用，结果表明：可能存在一个与材料特征长度相关的临界孔洞尺寸，当椭球孔洞的等效半径小于临界孔洞半径时，孔洞的长大受到明显抑制；3）通过引入基体/夹杂界面能的概念，分析了夹杂尺寸、夹杂形状对材料细观应力场的耦合影响，结果表明：颗粒内部和界面上的应力集中因子强烈地依赖于夹杂的尺寸和形状，因此，孔洞的形核机理是尺寸相关的；4）采用一种特殊的正交曲线坐标系和引入"核函数"的概念，"统一"地得到了含椭球和球形孔洞的材料的尺寸相关塑性势，它将传统的Gurson球形孔洞模型和GLD椭球孔洞模型推广到微尺度范围；5）基于含椭球和球形夹杂的体胞模型，初步研究了夹杂形状、夹杂尺寸对金属基复合材料尺寸相关力学行为的影响。

In this study, Chitosan-Poly complex nanoparticles were prepared by template polymerization of acrylic acid in the chitosan solution. The preparation and characterization of CS-PAA nanoparticles including the yields of the nanoparticles, FT-IR spectrum analysis, dynamic light scattering, zeta potential, and morphology of nanoparticles were concentrated in this study. The effects of temperature, weight ratio of CS and PAA, and pH value on the physicochemical properties of nanoparticles were studied.

本研究中，我们以模板聚合法在几丁聚醣（Chitosan， CS）溶液中聚合丙烯酸（Acrylicacid， AA）以制备几丁聚醣－聚丙烯酸复合奈米颗粒并计算其产率，再以傅利叶红外线光谱仪、动态光散射粒径分析仪（Dynamic light scattering， DLS）、表面电位测定仪及穿透式电子显微镜等仪器分析CS－PAA 复合奈米颗粒之性质，以探讨聚合时温度、聚合反应时间、CS 与AA 之重量比，以及介质pH 值对CS－PAA 复合奈米颗粒结构的影响。

From the influnce of pH change in water on the copolymerization, the copolymerization mechanism was provided. The copolymerization mechanism is that there is hydrogen bond, which can enhance the copolymerization, between acrylic acid and crotonaldehyde at low pH and there is"Charge Transfer Complex", which gives the more crotonaldehyde in P (acrylic acid-crotonaldehyde), between acrylic acid and crotonaldehyde at high pH.

根据共聚合反应介质pH值变化对丙烯酸-丁烯醛共聚合反应的影响，提出了丙烯酸-丁烯醛共聚合反应机理，即在低pH值时，丙烯酸、丁烯醛之间可形成氢键，从而使共聚合体系具有较高的聚合反应速率和转化率；在较高pH值时，丙烯酸、丁烯醛之间则有电荷转移络合物形成，从而使共聚物中含有更多的丁烯醛链段。

After the oxidative polymerization of DMP,styrene was in-situ polymerized under the initiation of dibenzoyl peroxide and dicumyl peroxide,finally thermodynamically compatible PPO/PS alloy was prepared.When styrene content was 50 wt%,for the synthesized PPO/PS alloy the yield and the weight-average molecular weight were determined to be 95%and 1.7×10~5 for PPO,93%and 2.0×10~5 for PS,respectively.The influence of the concentration of DMP and catalyst,molar ratio of N/Cu, oxygen partial pressure,NaOH concentration and temperature on the initial polymerization rate(R_0) of DMP was studied.It was found that the initial polymerization rate of DMP increased with the concentration of DMP and catalyst. The initial polymerization rate increased with the molar ratio of N/Cu at first and then decreased.

通过测定DMP氧化聚合过程中氧气吸收量随时间的变化，研究了DMP和催化剂浓度、N/Cu摩尔比、氧气分压、氢氧化钠浓度及温度对水介质中DMP氧化聚合初始速率的影响，发现DMP氧化聚合初始速率与氧气分压的0.1次方成正比；DMP氧化聚合初始速率随DMP和催化剂浓度及温度的增加而增加；随氢氧化钠浓度和N/Cu摩尔比的增加DMP氧化聚合初始速率先增加后降低。

At the isoelectric point, pH=3.07, the flocculation effectsFentonof iron polysulfate , aluminium polychloride and chitosan chloride are compared . It is illustrated that the optical flocculation reagent is aluminium polychloride and its optical dosage is 0.30g per 50mL effluent.

在等电点pH=3.07处，对聚合硫酸铁、聚合氯化铝、壳聚糖盐酸盐的絮凝效果进行比较，确定了最佳絮凝剂为聚合氯化铝，最佳用量为每50mL处理液加入0.30g聚合氯化铝。

In this article, the factors that affect molecular weight and solubility of polyacrylamide are studied and suitable initiator system is selected. The optimum parameters of copolymerizing process are obtained as follows: the molar proportion of acrylamide and sodium acrylate is 7:3, the monomer concentration is 30%, pH value of solution is 12, the oxidizer (K2S2O8) concentration is 0.1%, the reducing agent (NH2CONH2) concentration is 1%, the chain-transfer agent concentration is 0.4%. The initial reaction temperature is 35℃.

讨论了影响聚丙烯酰胺分子量和溶解性能的因素，选取了合适的氧化-还原引发体系，确定了制备超高分子量速溶型部分水解聚丙烯酰胺的优化聚合工艺参数：起始共聚合反应温度为35℃，保持在密闭条件下的共聚合反应2.5h后，再将聚合反应温度升高到55℃，继续反应2h，反应结束；反应溶液单体总浓度：30％，共聚合反应溶液pH值：12，氧化剂K_2S_2O_8：0.1％，还原剂NH_2CONH_2：1％，共聚合反应中两种单体的投料比：丙烯酰胺：丙烯酸钠=7：3，异丙醇链转移剂：0.4％。

There are three types of RNA polymerases in eukaryote: polymerase I, II and Ⅲ.

真核生物细胞核中具有三种不同的RNA聚合酶，分别是RNA聚合酶Ⅰ、RNA聚合酶Ⅱ和RNA聚合酶Ⅲ。

They are affected by total aluminiumconcentration and preparing methods as well as basicity mainly in differentcomponents of Ala, Alb and Alc. In addition, the aluminium species component isalso affected by some environmental conditions, such as diluting in water,different pH value, aging time and so on.

此外，一些环境因素也会影响其聚合形态组成的变化，如聚合氯化铝在水中稀释时，不同的稀释阶段和稀释倍数对其各聚合形态组成之间的转化作用不同；随着pH 值的逐渐升高或熟化时间的延长，聚合氯化铝中各种聚合形态均向着聚合度较高的形态转化。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。