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On the basis of the photochemical energy state of oxygen ,the effect of oxygen on the photopolymerization , several methods and mechanism against the inhibition of oxygen were investigated .

介绍了光固化涂料在光固化过程中常见的空气中氧的阻聚作用，并从氧的光化学能量态着手，给出了氧在光聚合反应中的作用，并且探讨了几种抑制氧阻聚的方法及其机

In this study, Chitosan-Poly complex nanoparticles were prepared by template polymerization of acrylic acid in the chitosan solution. The preparation and characterization of CS-PAA nanoparticles including the yields of the nanoparticles, FT-IR spectrum analysis, dynamic light scattering, zeta potential, and morphology of nanoparticles were concentrated in this study. The effects of temperature, weight ratio of CS and PAA, and pH value on the physicochemical properties of nanoparticles were studied.

本研究中，我们以模板聚合法在几丁聚醣（Chitosan， CS）溶液中聚合丙烯酸（Acrylicacid， AA）以制备几丁聚醣－聚丙烯酸复合奈米颗粒并计算其产率，再以傅利叶红外线光谱仪、动态光散射粒径分析仪（Dynamic light scattering， DLS）、表面电位测定仪及穿透式电子显微镜等仪器分析CS－PAA 复合奈米颗粒之性质，以探讨聚合时温度、聚合反应时间、CS 与AA 之重量比，以及介质pH 值对CS－PAA 复合奈米颗粒结构的影响。

By taking the advantage of thedifferent solubility of polyelectrolyte multilayer before and after UV irradiation andpatterned mask assistanted photolithography, we can obtain patterned robustpolyelectrolyte multilayer.

并利用这一光敏性聚电解质多层膜光反应前后在特定溶剂中溶解性的差异，通过覆模光照以及超声洗脱，制备了图案化的聚电解质多层膜表面。

A novel type of amphiphilic tri-block copolymers with both pH and temperature sensitiveness: poly-poly (dimethylamino ethyl methacrylate)-poly (ε-caprolactone)(PEG-PDMAEMA-PCL) was synthesized via sequential oxyanionic polymerization of macro-molecular: PEG, with a hydroxyl at one end, and dimethylamino ethyl methacrylate andε-caprolactone, with the potassium naphthalene as the initiator.

在本文中，报道了一类新型的兼具pH和温度敏感的双亲性嵌段共聚物：聚乙二醇-聚甲基丙烯酸N，N-二甲氨基乙酯-聚己内酯(PEG-PDMAEMA-PCL)及聚甲基丙烯酸N，N-二甲氨基乙酯-聚己内酯(PDMAEMA-PCL)的制备；并利用动态光散射和氢核磁共振光谱(~1H NMR)对该嵌段共聚物的水溶液性质进行研究；在此研究结果的基础上，初步探讨了其在仿生物矿化中的应用。

Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15～4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1～2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓～IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.

以丙烯酸丁酯，甲基丙烯酸-β-羟乙酯，丙烯酸及苯乙烯合成厂丙烯酸共聚树脂，并与含-NCO端基的聚氨酯丙烯酸酯接枝反应，经水性化后，得到两个系列（Acr-g-TPU-PETA和Acr-g-PPU-PETA）各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系，粘度与水相近，为牛顿流体，固含量30％左右。光固化前干燥涂膜的玻璃化转变温度在-15℃～4℃之间，有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料，接枝样dTG峰明显宽化，表明接枝样中链段之间的相互作刚有多重性，丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50％～30％者相对较好，且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1～2级，冲击强度为50kg·cm，柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团，碳—碳双键密度太低，光固化膜交联点太少，硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中，不出现色斑，光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜，光泽度及耐丁酮溶剂性能均有所提高，不会诱导铁基生锈，钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色，对光固化涂层的颜色干扰较小，为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出，且对所附着的铁基有诱导锈蚀作用。

The effects of compositions on UV prinking ink,such as prepolymer,monomer,photoinitiator and pigment on curing rate,cohesive force,resistency and other properties were investigated. The range analysis and variance analysis method were applied to the assessment of results. The results based on orthogonal experiment design indicated that an optimum component composition of UV printing ink can be obtained from prepolymer PQ611,monomer A,photoinitiator B and active amime.

摘 要：探讨了预聚物、单体、光引发剂、颜料等组分对UV油墨固化速度、附着力、耐抗性等性能的影响，应用正交实验设计方法对UV油墨各组分种类进行选择，对正交试验结果做极差分析及方差分析，结果表明：根据预先设计的组分比例，采用预聚物PQ611，单体A，光引发剂B，活性氨为加速剂，获得性能较好的UV油墨。

Experimental results showed that aerosol created by 1,3,5-trimethylbenzene photooxidation can be classify with five distinct chemical particle classes, the predominant components of these five particles are aromatic aldehyde, phenol, nitrophenol and carboxylic acid compounds.

利用该算法对OH自由基启动1，3，5-三甲苯光氧化形成的二次有机气溶胶单粒子质谱数据进行了聚类分析，在得到的五个聚类中包含了芳香醛、酚类化合物、硝基酚和羧酸等重要的光氧化产物，为研究苯系物光氧化机理提供了新的信息。

One chamber near the epidermis was filled with OCAs, and the other one was filled with isotonic saline. The dynamic changes in transmittance and the skin thickness were monitored after the application of six saturated alcohols to in vitro skin samples. From the observed results at 60 minutes, the optical clearing effects of six OCAs, i.e., glycerol, polyethylene glycol 400 (PEG400), polyethylene glycol 200 (PEG200), 1, 3-propylene glycol, 1, 4-butanediol and 1-butanol, showed in the descending order.

针对离体皮肤，建立模拟在体环境的给药方法(皮肤表面给药、真皮面与等渗生理盐水作用)，考察6种饱和醇类试剂作用后皮肤厚度及透射光强的变化。60分钟的动态观测发现，各试剂均能产生不同程度的光透明作用，皮肤光透明效果由强到弱依次为：甘油、聚乙二醇400(PEG400)、聚乙二醇200(PEG200)、丙二醇、丁二醇、正丁醇。

G/kJ and 0.68 kJ/ respectively. Experimental results in PBR indicated that thymosin α1 could be expressed in situ in a 1. 2 L plate PBR with 3 klx incident red light intensity.

光生物反应器中转基因聚球藻7942诱导实验表明，采用1.2 L平板式光生物反应器和3 klx红光诱导可在光生物反应器中实现Tα1的表达。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。