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In this paper, the thermally reversible crosslinking reaction and the properties of synthesized TPE based on the reactions of chlorine containing polymers such as PVC , chlorined polyethylene , epichlorohydrin rubber and acrylic rubber with salts of dicyclopenladienyl dicarboxylate crosslinking agents were studied.

本研究以环戊二烯二酸盐衍生物作热可逆共价交联剂,通过与聚氯乙烯、氯化聚乙烯、氯醚橡胶和丙烯酸酯橡胶等含氯聚合物的脱MX酯化反应来实现共价关联,并制取相应的新型TPE。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作:1合成了三种可进行光二聚反应的光敏小分子单体,LPUV 辐照制作了光控取向膜;用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应,发现小分子的光反应程度可达到50%以上,至少比光敏高分子高出5倍;薄膜的偏振红外光谱证实,经过LPUV 辐照后薄膜出现了明显的各向异性;将小分子光控取向膜制成液晶器件,在偏光显微镜下观察看到均匀一致的液晶取向;并且热稳定性达到100℃左右,接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜;采用接触角的方法监测自组装反应的动力学过程;紫外-可见光谱证实了自组装单层膜在石英基板表面形成;自组装单层膜经LPUV 辐照后能诱导液晶均匀取向,而且热稳定性可达130℃,热稳定性进一步提高。3合成了含有光敏双键的双季铵盐,在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜,紫外-可见光谱证实这是一个逐层均匀的沉积;在LPUV 照射下,自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应,形成取向膜,用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平;实验证明用自组装多层膜制成的液晶器件亮暗态均匀,静态对比度约为100,达到实用化器件的水平。

An integral core rod, a round-hole diffluent bracket and an extrusion head with double tubes to the extrusion head were applied in extrusion head designing,and the designing process of the ex-trusion head was introduced in detail.

针对一种材料为低密度聚乙烯、外径1.0 mm、内径0.4 mm、壁厚0.3 mm的医用微细介入导管,设计了一种专用微管挤出机头,其特点是采用了整体芯棒、圆孔分流支架和双管机头结构,详细介绍了该挤出机头的设计过程。

Two kinds of hybrid composite resins and two kinds of polyacid-modified composite resins (Dyract AP and F2000)were made into discal restorations, which were divided into 4 groups and each group were then divided into 5 subgroups.

分别以卡波姆和聚乙烯吡咯烷酮作为漂白剂的增稠载体,以11%和15%的CP作为漂白活性成分,配制漂白剂。

However, this technique is associated with complications, as reported by Barrack et al,17 including detachment of the femoral head, dislodgement of the polyethylene liner from the acetabular shell and asymmetrical rotation of the liner.

然而,Barrack等报道这项技术也伴随有相关的并发症,包括股骨头分离,聚乙烯跑出髋臼之外及衬垫位置偏移。

It is obvious that the rheological property and dispersity of color masterbatch are improved with the addition of polyethylene wax.

影响色母粒黑点含量的主要因素不在于聚乙烯蜡的灰分含量,而取决于它的制备工艺。

M. Particles in sub-micron can be found dispersively. The main constituents of those tissue-detached particles are composed of polyethylene segments, metallic elements and their mixtures.

临床磨耗残屑的主要物种为聚乙烯片断、金属元素或两者聚集的混合物,且其元素的组成与人工膝关节组件所使用的材质有关。

The thesis chose 4, 4\'-diazostilbene-2, 2\'-disulfonic acid disodium saltas cross-linking agent to crosslink poly in commercialNafion117 membranes under the irradiation of ultraviolet.

本论文选择4,4'-双叠氮菧-2,2'二磺酸钠为交联试剂,以紫外光引发,使聚乙烯吡咯烷酮在Nafion膜中发生交联,从而制备了semi-IPN型Nafion/PVP复合膜。

Our current major products are: polyethylene agricultural plastic film, PE, PP, polypropylene plastic film, stiletto plastic film, pinhole terra plastic film, HDPE stiletto film, flower plastic film, terra plastic film, dividable plastic film, black and white plastic film, canopy film, water un-drop film, long life film, vest bag, square mouth bag, rolling bag, trash bag, hand bag, 8-folded bag, tiny hole spray belt, with all kinds of specifications.

目前主要产品有聚乙烯农用薄膜、PE、PP、聚丙烯薄膜、打孔薄膜、针孔地膜、HDPE打孔膜、花卉薄膜、地膜、降解地膜、黑白膜、大棚膜、无滴膜、长寿膜、背心袋子、平口袋子、连卷袋子、垃圾袋子、拎攀袋、八折连卷袋、微孔喷水带,规格齐全(如客户提供样品各种规格也可以,本厂以厂价直销,服务周到),年生产能力已达2000吨以上。

In this paper, based on the propagation characteristic of sound wave in pulsed electroacoustic method and temperature dependence of polyethylene properties, the effect of temperature gradient on space charge measurement is analyzed and the space charge waveform is recovered.

本文基于电声脉冲测量方法中声波的传播特性和温度对聚乙烯材料特性的影响,分析了温度梯度场对空间电荷测量结果的影响并进行了波形恢复。

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