联苯酰

To improve the cyano reactivity, cyano-terminated PPENs were prepared by the end-capping reaction of PPEN-OL with CBN; benzonitrile terminated polys were also prepared by the polycondensation of excess 4,4'-oxydianiline with 1,2-dihydro-2-(4-carboxyphenyl)-4-[4-(4-carboxyphenoxyl)phenyl]-phthalazinone, followed by end-capping with CBA. The polymers synthesized exhibited good solubility in NMP, DMAc and DMF, and were crosslinked to afford phenyl-s-triazine-containing polymers under the similar conditions.

为提高氰基活性，以对氯苯腈为原料，对PPEN-OL进行封端，设计合成了含氰端基的聚芳醚腈；以含二氮杂萘酮联苯结构二酸单体与4，4'-二氨基二苯醚为原料，经Yamazaki膦酰化缩聚，并用对氰基苯甲酸进行封端，合成了含氰端基的聚芳醚酰胺。

A novel monomer the 1-methyl-4,5-bis(4-chlorobenzoy) cyclometer containing cyclohexene were prepared,so a group of novel polys containing the cyclohexene and phthalazinone moieties was prepared by the nucleophilic displacement reaction of 1-methyl-4,5-bis(4-chlorobenzoyl) cyclohexene and 4,4′-dichlorodiphenyl sulfone and 4-(3,5-dimethyl-4-hydroxyphenyl)-2,3-phthalazin-1-one.

用新型聚合单体1-甲基-4，5-二(4-氯代苯甲酰基)环己烯与4-(4-羟基苯基)-2，3-二氮杂萘-1-酮、4，4′-二氯二苯砜单体经亲核共缩聚反应，成功地合成了含环己烯结构的杂环联苯型聚醚系列聚合物。

A novel monomer the 1-methyl-4,5-bis (4-chlorobenzoy) cyclometer containing cyclohexene were prepared,so a group of novel polys containing the cyclohexene and phthalazinone moieties was prepared by the nucleophilic displacement reaction of 1-methy l-4,5-bis(4-chlorobenzoyl) cyclohexene and 4,4'-dichlorodiphenyl sulfone and 4-(3,5-dimethyl-4-hydroxyphenyl)-2,3-phthalazin-1-one.

用新型聚合单体 1-甲基-4，5-二(4-氯代苯甲酰基)环己烯与 4-(4-羟基苯基)-2 ，3-二氮杂萘-1-酮、4，4′-二氯二苯砜单体经亲核共缩聚反应，成功地合成了含环己烯结构的杂环联苯型聚醚系列聚合物。

The reductive coupling of aryl halide s to form the corresponding biaryls was effected with high selectivity in water,using formic hydrazide as a reducing agent in the presence of a catalytic amount of Pd/C.

在Pd/C催化下，以甲酰肼为还原剂，卤代芳烃通过还原偶联反应能高选择性地合成相应的联苯化合物。

In order to synthesize the functional polyquinolines (such as proton conducting polyquinolines and optically active polyquinolines) and investigate structure-property relationships, polyquinolines and polyanthrazolines containing isomeric pyrrole units or 1, 1'-binaphthyl in main chain were synthesized and their properties were studied.

建立了二乙酰吡咯的合成方法；合成并表征了四种二苯酰基-二氨基单体和五种新型的含吡咯基或联萘基的二乙酰基单体；并对部分合成方法进行了改进，简化了实验步骤，提高了产率。

In the fifth chapter, six compounds formed between nitrogen-containing ligands such as 2, 2'-bipyridyl, isonicotinamide and 1, 4, 8, 11-tetraazacyclotetradecane and the solution cadmium sulfonates such as 1, 5-naphthalenedisulfonate, 2, 6-naphthalenedisulfonate, 4, 4'-bipenyldisulfonate and 4, 4'-penyletherdisulfonate have been synthesized and structurally characterized. Besides, another compound has been synthesized with cadmium carbonate reacting with 1, 5-naphthalenedisulfonate acid.

第五章以2，2'-联吡啶、异烟酰胺和1，4，8，11-四氮杂环十四癸烷与含有Cd〓和1，5-萘二磺酸根离子、2，6-萘二磺酸根离子、4，4'-联苯二磺酸根离子和4，4'-苯醚二磺酸根离子的水溶液反应，合成了六个化合物，另外以1，5-萘二磺酸与碳酸镉反应合成出一个化合物。

This reaction was further extended to the coupling reaction of amide with diiodo biphenyl; and the carbazole derivatives were synthesized in 53%-95% yield.

另外将该反应体系的底物进行了进一步的拓展，用酰胺和二碘代联苯化合物偶联，合成了9个咔唑衍生物，收率在53％—95％之间，并运用~1H NMR、~(13)C NMR、HRMS等分析测试手段对这些化合物进行了表征。

The invention relates to a mixed additive used in lithium secondary battery electrolyte, which is characterized in that: its components comprises that biphenyl at 0.5-95.4%, phenylcyclohexyl at 1.1-93.8%, vinylene carbonate at 0.4-93.2%, tertiary carbon alkyl benzene at 0.5-96.5%; and ethenyl sulfonyl benzene at

本发明公开了一种锂离子二次电池电解液用混合添加剂，其特征在于：组分与重量％分别是：联苯类0.5％～95.4％；环己基苯类1.1％～93.8％；碳酸亚乙烯酯0.4％～93.2％；叔碳烷基苯0.5％～96.5％；乙烯基硫酰苯0.5％～95.8％。

Based on this monomer, several novel polyimides bearing side chain s composed of cyano-biphenyl mesogenic end groups and hexylene spacer were prepared.

合成了一种含氰基联苯氧基侧链的二元胺单体，然后通过两步法热酰亚胺化工艺制备了新型的含氰基联苯基团侧链的聚酰亚胺。

The compound of BNTMBP wassynthesized by the condensation reaction between 4-chloronitrobenzene (4CNB) and 4, 4'-dihydroxy-3, 3', 5, 5'-tetramethyl biphenyl in the presence of potassium carbonate in the mixture solvents of N, N-dimethylformamide and tolune.

4， 4'-二羟基－3， 3'， 5， 5'-四甲基联苯、4-氯硝基苯(4CNB)和碳酸钾在N， N-二甲基甲酰胺和甲苯的混合溶剂体系中回流反应，合成得到了4， 4'-双（4-硝基苯氧基）－3， 3'， 5， 5'-四甲基联苯；随后，在Pd/C-水合肼的还原体系中，被进一步还原，得到了4， 4'-双（4-氨基苯氧基）－3， 3'， 5， 5'-四甲基联苯。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。