联羧基

The influences of different organic bridging ligands pyrazine,2-pyrazinecarboxylate,4,4′-bipyridine and 1,2-bis(4-pyridyl)ethane on the cobalt vanadate system were explored.

同时还研究了不同的有机桥式配体吡嗪、2-吡嗪羧酸、4，4′-联吡啶和1，2-联(4-吡啶基)乙烷在钴钒体系中的作用。

The specific properties of materials, such as the palate adhesion, dynamic cruor, anti-bacterial and the degradability of lysozyme, were studied, which provide valuable data for further application. The main creative ideas are listed as follows:(1) The water-retention chitosan/poly vinyl alcohol blend fiber was obtained by coagulating in 10％ NaOH/ethanol solution, and the blend and crosslink due to GA can enhance the mechanical properties of fiber;(2) The controlled degradable chitosan/gelatin blend fiber was obtained by solution filature, and the mechanical properties were improved;(3) The N-acylchitosan with the different degree of substitution were successfully prepared, and the relationship between structure and properties was estabilished;(4) By a new solvent system of 6％ NaOH/4％ urea for cellulose, the blood anti-coagulant function films were prepared by blending cellulose with chitin;(5) In the same solvent system above mentioned, the anti-bacterial blend films based on cellulose and carboxymethyl-chitosan were prepared, and the relationship of DS and the anti-bacterial property was concluded;(6) The controlled degradable chitosan films was obtained by the chemical crosslink.

本论文的主要创新点：（1）以NaOH水溶液／无水乙醇为凝固液，采用溶液纺丝法制备出保水性壳聚糖／聚乙烯醇纤维，共混和戊二醛交联极大提高了壳聚糖纤维力学性能；（2）用壳聚糖和明胶共混，以溶液纺丝法制备出可控降解的壳聚糖／明胶纤维，并大幅度提高了壳聚糖共混纤维的干、湿态抗张强度；（3）确立了不同取代度N-酰基壳聚糖的合成方法及其膜的结构与性能的关系；（4）利用纤维素新溶剂6％NaOH／4％尿素制备出抗凝血性纤维素／甲壳素共混膜；（5）利用上述纤维素新溶剂制备出抗菌性纤维素／羧甲基壳聚糖共混膜，揭示了羧甲基壳聚糖取代度与抗菌性能的关系；（6）制备出可控降解壳聚糖交联膜。

The result is that both tin atoms are five-coordination, have a distorted trigonal bipyramidal geometry with an additional week interaction between another oxygen atom and tin atom.

分子中四个羧酸酯基有桥联双齿和单齿两种不同的配位模式；在内环锡和外环锡的配位单元中，锡均形成具有五配位的畸变三角双锥配位构型，同时另有一氧原子与中心锡原子之间有弱相互作用。

In this paper, according to principles of molecular design, Cu,Ag, Cu,Fe, Ni, Mn, and Co were selected as templates, 8,8'-Dithiodiquinoline,4-cyanopyridine,2,2'-Bipyridyl-3,3'-dicarboxylic acid, 4,4'-bipyridine as building blocks.

本课题通过分子设计，以Cu，Cu，Mn，Co，Ni，Fe，Ag为模板，以8，8'-二硫联喹啉，4-氰基吡啶，4，4'-联吡啶和2，2'-联吡啶-3，3'-二羧酸为构件，用溶剂热法合成新的配位聚合物，测定其晶体结构，并研究其导电性和热行为。

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能，共由以下六部分组成：1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应；2、亚甲基环丙烷类化合物开环产物的偶联反应；3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应；4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应；5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应；6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1，3-偶极环加成反应。

Acrylic-oil, acrylic cool are commonly used such as acrylic paint, clear acrylic via ethhyl and butylacralate, in the resin introduction of hydroxyl and carboxylated to aminosulfonic cross-linkers gubernacular as a tree.

丙烯酸型平油，凡是拔取羟基丙烯酸酷如丙烯酸不纬乙酯和丙烯酸共聚，在树脂洋引进羟基和羧基，以氨基树胎作为接联剂。

In this paper,pyromellitic dianhydride,1,2,3,4-cyclobutanetetracarboxylic dianhydride,4[(4-aminophenyl)-bis(4-methoxyphenyl)methyl]benzeneamine,4-hexyloxy-biphenyl-3′,5′-diaminobenzoate,and additive ADD-34 were used to synthesize four PIs.

文章用均苯四甲酸二酐，4[(4-氨基苯基)-二(4-甲氧基苯基)甲基]苯胺，1，2，3，4-环丁烷四羧酸二酐，4-己烷氧基联苯酚-3′，5′-二胺基苯甲酸酯和不同含量的添加剂制备了聚酰亚胺液晶取向剂。

Ridging Hedta(superscript 3-) anions between Bi atoms and Pr atoms result into a novel infinite 3D network structure.

i-Pr间通过配阴离子Hedta(上标 3-)中4个羧基的桥联作用构建配合物的3D结构。

It is considered that the carboxylic groups coordinate to the metal ions in four modes: monodentate, the chelating bidentate, the bridging bidentate, and thebridging-chelating tridentate.

一般认为羧酸基有四种配位方式：单齿、螯合双齿、桥联双齿和螯合桥联三齿。

The complexes were characterized by elemental analysis,UV,IR,TG,NMR and molar conductance measurements.Their formulas were in accordance with C34H32O8N2LnCl·nH2O or 〔(L4)2LnCl·nH2O,Ln=Nd,n=4;Ln=Pr,Yb,n=2;Ln=Sm,Eu,Dy,n=1〕.All the water molecules were uncoordinated.Dinuclear complexes were observed in the coordination environment.The coordination number of central ions was nine.

经元素分析、红外光谱、紫外光谱、核磁共振谱、质谱、摩尔电导、差热热重分析确证结构，其化学式为C34H32O8N2LnCl·nH2O，简写为：(L42LnCl·nH2O，Ln=Nd，n=4；Ln=Pr，Yb，n=2；Ln=Sm，Eu，Dy，n=1；该类配体是以酚氧原子、亚氨基的氮原子、桥联的羧基氧原子以及氯原子同稀土离子配位，形成了九配位的双核配合物。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失