联基

Aging mechanism of wood-plastic composite was: light and heat break down the long molecular chains of wood flour and plastic; the free radicals reacted with the oxygen, which generated carbonyl groups, hydroperoxides and so on; the free radicals also had cross linking reaction, which generated alkoxy; Water destroyed the interface of wood flour and plastic, hydrolyzed ester additives, extracted the small molecule additives and degradation products; Microorganism degraded cellulose, semicellulose, lignin and ester additives; degradation product from different component accelerated the aging, which could be exampled by the fact that HCl from degradation of PVC accelerated the hydrolyzation of cellulose and semicellulose.

木塑复合材料的老化机理为：光和热引发木塑复合材料中木质组分和塑料组分大分子链断裂，产生的自由基与氧气作用，发生链支化反应生成羰基、氢过氧化物等，发生交联反应生成烷氧基等；水分破坏木-塑界面、水解酯类添加剂、抽提小分子添加剂和降解产物；微生物分解纤维素、半纤维素、木素和酯类添加剂；木塑复合材料中各组分的降解产物相互促进老化，PVC降解产生的HCl溶于水，促进了纤维素和半纤维素的水解。

The hydrophobic core serves as a reservoir for water-insoluble drugs.Hence,these nanoparticles can be used as carriers for hydrophobic drugs.For the synthesis of cholesterol-modified glycol chitosan conjugates,a carboxyl group was initially introduced to cholesterol molecule using succinic anhydride,and then covalently coupled with the primary amino group of glycol chitosan in the presence of 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide hydrochloride and N-hydroxyl succinimide.

本文采用二步反应将胆固醇接枝到乙二醇壳聚糖，首先将胆固醇进行羧基化，将胆固醇与琥珀酸酐反应生成胆固醇半琥珀酸酯，然后用1-乙基-3-(3-二甲基氨丙基)碳二亚胺盐酸盐与N-羟基琥珀酰亚胺作为偶联剂，将胆固醇半琥珀酸酯的羧基与乙二醇壳聚糖主链的氨基进行反应，得到胆固醇疏水改性乙二醇壳聚糖共聚物。

In order to obtain versatile ulitity of host molecules, three new chiral calix [4] crown ethers containing aza, thio atoms bearing two chiral sites provided by -cysteine ester were synthesized by the condensation of calix [4] arene diacid dichloride with oligoethylene glycol bridged bis-amino acid methyl ester. All new compounds were characterized by NMR, MS and elemental analysis.

以-半胱氨酸为手性源，利用多甘醇二氯醚在碱性条件下对半胱氨酸巯基进行烷基化反应，成功地合成了多甘醇醚链桥联的半胱氨酸衍生物，醚化反应后，在高度稀释条件下与对叔丁基杯[4]芳烃二乙酰氯进行双功能基缩合反应成功地合成了新型的手性杯[4]含氮、硫杂冠醚，并利用〓H NMR、MS等谱图手段对其结构进行了表征。

In chapter 4, we have described an improved method for the preparation of ethynylferrocene. Ethynylferrocene was prepared in satisfactory yield by reaction of formylferrocene with triphenylphosphine and carbon tetrachloride followed by dehydrohalogenation in the presence of n-BuLi.

第三章中，我们研究了钯催化下碘杂环化合物的羰基化—酰胺化反应、羰基化—酯化反应和与末端炔烃的羰基化交叉偶联反应，为一步合成多官能团化合物开辟了新的途径，同时，得到的这些产物经过进一步官能团转化后，可以成为一些天然产物合成中的重要中间体化合物。

The mobility of the abutments was significantly reduced when they were splinted together. Conclusion: Mini-SGF attachments used in free-end RPDs have no evident adverse effect on periodontal health of the abutment teeth, and the way of splinting the abutments is advantageous to their long-term health and stability.

Mini-SGF附着体在游离端义齿修复中对基牙牙周健康无明显不利影响，基牙的联冠修复形式有利于基牙的健康和稳定。

When 3-benzoyl-5-formyl-indolizine or ethyl 5-benzoyl-indolizine-3-carboxylatewere used as substrates, a novel coupling reaction occurred, givinghydroxy-cycl[3,2,2]azines. A mechanism of the reaction was proposed.

其中3-苯甲酰基-5-甲酰基中氮茚和5-苯甲酰基-3-中氮茚甲酸乙酯在低价钛试剂的作用下，发生了新奇的偶联反应，得到了用其它方法难以制备的Hydroxy-cycl[3，2，2]azine，并对此现象作了解释。

This PhD thesis mainly summarizes the original results on studies of aromatic amide-derived phosphines,including the precatalyst system consisting of Aphos and Pd_2 and the applications for promoting room temperature Suzuki cross-coupling of aryl chlorides and aryl/vinyl bromides,respectively,with aryl/vinyl boronic acids,and alkyl boranes.

本博士学位论文主要总结了对芳基酰胺衍生的膦配体的研究，以及该类型配体与Pd_2组成的催化剂在室温下催化氯代芳烃、溴代芳烃、溴代烯烃分别同芳基硼酸、烯基硼酸及烷基硼试剂进行的Suzuki偶联反应中的表现。

The target molecules were synthesized through a Sonogashira coupling reaction of 1-trans-4-(trans-4-n-pentylcyclohexyl)cyclohexylacetylene and 4-iodo-2,3-difluoro- phenyl ether with total yields of 27%～28%.

目标化合物采用1-trans-4-(trans-4-正戊基环己基)环己基乙炔与4-碘-2，3-二氟苯基醚进行Sonogashira偶联反应制备，反应总产率27%～28%。

This paper is studied on a new synthesis method of epoxy-modified organic silicone micro-emulsion by one step with a silane-alkyl coupling,silicon hydride resin acceptor while opening-cyclo polymerization of the octa-methyl cyclo tetra siloxane,thus the optimal manufacturing conditions are determined by comparing test of their properties.

采用偶联剂缩水甘油醚氧丙基三甲氧基硅烷、八甲基环四硅氧烷开环聚合，探索一步合成环氧基改性有机硅微乳的新方法，通过其性能测试得出最佳工艺条件。

A new method for synthsising a heatresistant explosive HNS-Ⅰor HNS-Ⅱ in two steps by raw material TNT through intermediate HNBB is studied in this article.

研究了以六硝基联苄为中间体，用梯恩梯为起始原料，分两步合成耐热炸药六硝基Ⅰ型或六硝基Ⅱ型的新方法。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失