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联二萘

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A novel binaphthalene -based copolymer which containing alternating ionic conductive and light-emitting blocks on the main chain was designed and synthesized in order to overcome phase separation problem between the polar ionic conductive and the apolar conjugated polymers in the traditional light-emitting electrochemical cells.

为克服聚合物电化学发光池中极性离子传导性聚合物与非极性发光聚合物两相分离的矛盾,设计合成了一种聚合物分子主链上同时含有发光链段与离子传导性链段的联二萘功能性发光共聚物 EO- PN。

It is found that the dihedral angle in the two kinds of molecules were affected by the formation of the nanotubes, as a result, the CD spectra are different.

制备了手性分子二—2—萘基吡咯醇及--2,2'-甲氧基-1,1'-联二萘的纳米管,发现纳米管结构的形成对手性分子的二面角产生一定影响,进而影响其圆二色谱。

Bi-2; 2′-naphthol ; enantiomer resolution ; asymmetric synthesis ; asymmetric oxidation reaction ; asymmetric reduction reaction

1; 1′-联二萘酚;对映体拆分;不对称合成;不对称氧化反应;不对称还原反应

GC/MS analysis showed that the poly (1,1'-bisnaphthol carbonate), 2-ethylhexyl acetate, heptanone,octene and acetic acid were formed during the ester interchange.

本文用金属化合物作催化剂进行1,1′-联二萘酚-4,4′-二乙酸酯和二(2-乙基己醇)碳酸酯的酯交换反应,评价了不同金

From optical BINOL, the chiral phosphoryl azide compound was prepared. Its application as chiral auxiliaries in the stereoselective ring-opening of meso-epoxides was examined. No obvious asymmetric induction, however, was observed.

从光学活性的联二萘酚出发合成得到了手性磷叠氮化合物,并将其应用于环氧化合物的不对称开环反应中,考察了它作为手性辅助剂在该反应中的不对称诱导效果。

In this paper research progress of synthesis of 1,1'- binaphthol and its derivatives by raceme resolution and asymmetry oxidative coupling reaction, related to 63 binaphthol compounds is detailed.

联二萘酚作为配体在催化不对称反应方面取得了极大的成功,是有机化学家研究的热点。

The separation of optical isomers of 2, 2'-dihydroxy-1, 1'-binaphthyl and 2, 2'-diamino-1, 1'-binaphthyl was studied by reversed-phase high performance liquid chromatography on a chiral stationary phase consisting of-hydroxypropyl-β-cyclodextrin (Cyclobond Ⅰ 2000 SP)using methanol/water as the mobile phase. The effects of mobile phase ratio, flow rate and column temperature on separation of optical isomers of DHBN and DABN were investigated.

在S-羟丙基-β-环糊精手性柱(CyclobondⅠ2000 SP)上用反相高效液相色谱法研究了2,2'-二氨基-1,1'-联萘和2,2'-二羟基-1,1'-联萘光学异构体的分离,考察了流动相组成、流速以及柱温等对联二萘胺和联二萘酚光学异构体分离的影响。

An inclusion complex -BINOL--Omeprazole or -BINOL--Omeprazole was first obtained from racemic omeprazole with chiral host --or --2, 2'- dihydroxy-1, 1'-binaphthyl in high selectivities, and thus both optically pure enantiomers of omeprazole were prepared as syrup with more than 99% enantiomeric excess, the overall yields of both two enantiomers are more than 60%.

首次发现光学纯R--或s--联二萘酚高效识别并包结R--或S--奥美拉唑,形成包结络合物的现象,并首次将包结拆分法应用于手性苯并咪唑类抗溃疡药物的制备,用一种构型的光学纯联二萘酚直接拆分奥美拉唑,可同时得到油状或糖浆状e.e。

By experiment we found that the reaction of aldehydes and nitromethane can proceed smoothly in the presence of a catalytic amount of Disodium Binaphtholate (3 mol %),and obtain a corresponding rate of product up to 100%.

通过筛选,我们发现在催化剂量的联二萘酚双钠盐(3 mol%)存在下,henry反应能够快速的进行,产率高达100%。

Synthesis of racemic 1,1′-bi-2,2′-naphtholby catalytic oxidative coupling of 2-naphthol was reviewed.

综述了催化氧化偶联2-萘酚合成外消旋体1,1′-联二萘酚的方法。

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Finally, according to market conditions and market products this article paper analyzes the trends in the development of camera technology, and designs a color night vision camera.

最后根据市场情况和市面上产品的情况分析了摄像机技术的发展趋势,并设计了一款彩色夜视摄像机。

Only person height weeds and the fierce looks stone idles were there.

只有半人深的荒草和龇牙咧嘴的神像。

This dramatic range, steeper than the Himalayas, is the upturned rim of the eastern edge of Tibet, a plateau that has risen to 5 km in response to the slow but un stoppable collision of India with Asia that began about 55 million years ago and which continues unabated today.

这一引人注目的地域范围,比喜马拉雅山更加陡峭,是处于西藏东部边缘的朝上翻的边框地带。响应启始于约5500万年前的、缓慢的但却不可阻挡的印度与亚洲地壳板块碰撞,高原已上升至五千米,这种碰撞持续至今,毫无衰退。