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By using lead ion as the template molecule, sodium vinylbenzoic- acid as the functional monomer and divinyl benzene as the cross-linking monomer, lead molecularly imprinted polymers were synthesized by preassembling and surface-imprinting technology.

以对乙烯基苯甲酸钠为功能单体,铅离子为模板分子,对乙烯基苯为交联剂,采用预组装方法结合表面印迹技术合成得到铅的分子印迹聚合物。

Three novel rigid compounds 3, 6-bis[2-(4-pyridylethenyl]-9-ethylcarbazole (L~1), 3,6-bis[2-(2-pyridyl)ethenyl]-9-ethylcarbazole (L~2), 3,6-bis[2-(4-pyridyl)ethenyl]-9 -ethylpyridylcarbazole (L~3) were successfully synthesized by Heck reaction, which were fully characterized by elemental analyses, NMR, MS, IR spectra and single X-ray diffraction analysis.

利用Heck偶联反应,成功地合成了三种新型刚性的吡啶基咔唑类化合物:3,6-二[2-(4-吡啶基)乙烯基]-9-乙基咔唑(L~1),3,6-二[2-(2-吡啶基)乙烯基]-9-乙基咔唑(L~2)和3,6-二[2-(4-吡啶基)吡啶基]-9-乙基吡啶基咔唑(L~3),通过元素分析、核磁共振谱、质谱、红外光谱和单晶X-射线衍射等分析手段确证了它们的结构。

The invention relates to a mixed additive used in lithium secondary battery electrolyte, which is characterized in that: its components comprises that biphenyl at 0.5-95.4%, phenylcyclohexyl at 1.1-93.8%, vinylene carbonate at 0.4-93.2%, tertiary carbon alkyl benzene at 0.5-96.5%; and ethenyl sulfonyl benzene at

本发明公开了一种锂离子二次电池电解液用混合添加剂,其特征在于:组分与重量%分别是:联苯类0.5%~95.4%;环己基苯类1.1%~93.8%;碳酸亚乙烯酯0.4%~93.2%;叔碳烷基苯0.5%~96.5%;乙烯基硫酰苯0.5%~95.8%。

Furthermore,using oxaldehyde,make the emulsion crosslinked and form a kind of net structure,thus a new kind of water-resistant adhesive is created.

通过醋酸乙烯酯共聚改性的方法,用醋酸乙烯与丙烯酸系单体共聚,采用无皂乳液聚合,然后用乙二醛交联,使乳液形成网络结构,制备了一种新型耐水性胶粘剂,研究了共聚单体对乳液性能的影响,并采用DSC、透射电镜等对乳液结构及性能进行了测试。

A new kind of non-formaldehyde water-resistant emulsion is prepared by modifying polyvinyl acetate with the surfactant-free copolymerization to polymerize vinyl acetate and the acrylic acid monomers,and then by using oxaldehyde to make the emulsion crosslinked to form a kind of net structure.

通过醋酸乙烯酯共聚的改性方法,用醋酸乙烯与丙烯酸系单体共聚,采用无皂乳液聚合,后用乙二醛交联,使乳液形成网络结构,制备了一种无甲醛的新型耐水性乳液。

The first step in the degradation is most probably the classical ester scission reaction to give a carboxylic acid and olefinic end groups. Further ester scission on the adjacent ester groups of carboxylic acid and olefinic molecular chains can then lead to the formation of lower weight pyrolytic products, such as: CH〓=CHOCOPhCOOCH=CH〓、CH〓=CHOCOPhCOOH and HOOCPhCOOH, and they can pyrolyze continually to produce substrate pyrolytic compounds, such as: HOOCPhCOCH〓、PhCOOH、PhH、PhCOCH〓 and CO、CO〓. At the same time, a corsslinking cyclization reaction occurred of the formation of the gas products during the degradation of PET.

断裂大分子链端邻近羰基和乙烯基的酯键持续断裂,不断地形成小分子裂解产物,如:CH〓=CHOCOPhCOOCH=CH〓、CH〓=CHOCOPhCOOH以及HOOCPhCOOH,这些产物还会进一步裂解成分子量更低的小分子裂解产物,如:HOOCPhCOCH〓、PhCOOH、PhH、PhCOCH〓以及CO、CO〓等,与此同时,一部分乙烯基酯端基的大分子链碎片会发生支化而相互连接,再经&链脱离&和环化反应形成难燃的交联产物。

Ambient temperature self-crosslinking acrylic latexes were prepared through semicontinuous emulsion polymerization using 3 different polymerizable alkoxysilanes, i.e. vinyl tri silane (A172), Vinyl triethoxy silane and γ-methacryloxypropyl trimethoxy silane (A174). The hydrolysis of these siloxanes under different pH was characterized, and dependence of the latex and polymer properties on these siloxanes and their incorporated amounts in the polymers was studied.

使用三种含不饱和双键硅氧烷,乙烯基三硅烷(A172)、乙烯基三乙氧基硅烷和γ-甲基丙烯酰氧丙基三甲氧基硅烷(A174)为功能单体,采用半连续乳液聚合法制备了室温自交联丙烯酸酯乳液,探讨了硅氧烷功能单体在不同pH条件下水解情况以及其种类和用量对乳液及乳胶膜性能的影响。

The synthesis of the unbridged metallocene (2, 4-Me〓Ind)〓ZrCl〓, which is not found in reference. Polymerization of ethylene or propylene with the metallocene has high activity. The resulted ethylene/1-hexene copolymer characteristic of uniform comonomer distribution. The catalyst possess commercial value

合成了未见文献报道的非桥联茂金属(2,4-Me〓Ind)〓ZrCl〓,用这种茂金属催化乙烯或丙烯聚合均达到了很高的催化效率,所得的乙烯/1-己烯共聚物表现出共单体分布高度无序的特点,具有工业应用前景

EVA/LDPE/ CB conductive foam was made of EVA and LDPE as matrix,HG-1P CB and ACET CB as conductive filler,AC as foamer and DCP as crosslinker.

文章以乙烯-乙酸乙烯酯和低密度聚乙烯为主基体,特导炭黑(HG-1P)和乙炔炭黑为导电填料,偶氮二甲酰胺为发泡剂,过氧化二异丙苯为交联剂,制备了EVA/LDPE/炭黑导电泡沫复合材料。

A kind of silica loaded cerium dioxide particles was prepared by the sol-gel method and the heat-resist performance of the silica loaded cerium dioxide particle added silicon rubber materials improved evidently as compared with that of the purely silica added materials.

研究了两种硅烷偶联剂——乙烯基三乙氧基硅烷(A-151)和乙烯基三特丁基过氧硅烷对高硬度硅橡胶性能的影响,比较发现A-151不但可以显著改善高硬度硅橡胶的回弹性,而且使用方便、成本较低。

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On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面,更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值,分为几个相等的区间作为横轴,并将各区间内所测定值依所出现的次数累积而成的面积,用柱子排起来的图形,也叫做柱状图。

You rap, you know we are not so good at rapping, huh?

你唱吧,你也知道我们并不那么擅长说唱,对吧?