联乙炔

The platinum terpyridyl acetylide complex containing a simple amine group in the acetylide ligand could be utilized as a chemo-sensor for detection of micromolar concentration of protons by monitoring the changes both in luminescence and color.

实验发现： 1.4-N，N-二甲基苯乙炔为辅助配体的三联吡啶Pt络合物TA在质子存在下吸收和发光变化明显，因此可以通过颜色或发光的变化检测微量质子的存在。

The first ethynyl group is reacted with the first reactive group in a first carbon-carbon bond formation reaction and the second ethynyl group is reacted with the second reactive group in a second carbon-carbon bond formation reaction to crosslink the first backbone with the second backbone, thereby forming the packaging substrate.

在第一个碳－碳键生成反应中，使第一个乙炔基与第一个反应性基反应，在第二个碳－碳键生成反应中，使第二个乙炔基与第二个反应性基反应，将第一种主链与第二种主链交联，从而制成组装基片。

Six lateral difluorine substituted tolan -type liquid crystals were synthesized via Sonogashira cross-coupling of 4-alkylphenylacetylene and 4-iodo-2,3-difluoro-1-alkoxybenzene under the protection of argon.

用邻二氟苯为起始原料，在-78℃经过两次选择性"邻位金属化"反应、醚化反应、氧化反应制得2，3-二氟-4-碘-1-烷氧基苯，再与4-烷基苯乙炔在氩气保护下进行Sonogash ira偶联反应，制备出6种侧向二氟取代二苯乙炔类液晶。

Bathochromic shifts of the emission maxima also occurred and increased with the enhancement of the substituents electron-donating ability.

在把催化下通过4-甲基一7一碘香豆素和苯乙炔的偶联反应制备了7一位苯乙炔基取代香豆素化合物。。

Bathochromic shifts of the emission maxima also occurred and increased with the enhancement of the substituent's electron-donating ability.

在钯催化下通过4-甲基-7-碘香豆素和苯乙炔的偶联反应制备了7-位苯乙炔基取代香豆素化合物。

In this paper,- and (5)-2,2'-diethynyl-1,1'-binaphthyl with highly stable chiral configurations were employed as structural templates, and a new type of helical cyclophane compounds-3 and-3 were synthesized in enantiopure form by the introduction of benzyl sulfone through Sonogashira coupling reaction, followed by the treatment of disulfone with lithium diisopropylamide.

基於2，2'-二取代的联萘衍生物在手性构型上高度稳定的特点，分别从光学活性的-和-2，2'-二乙炔基-1，1'-联萘结构模板出发，通过Sonogashira偶连反应导入苄基碸，然后用二异丙基氨基锂处理制得的联萘二碸成功地合成了一种新的螺旋环芳分子－对映异构体-3和-3。

From the optically active 2, 2'-dihydroxy-1,1 '-binaphthyl, through esterification, Kumada coupling, bromization, hydrolization and Wittig elimination reaction, 2,2'-diethynyl-1,1'-binaphthyl was obtained.

从光学活性的2，2'-二羟基-1，1'-联萘出发，经过酯化，Kumada偶联，溴化，水解和Wittig消除反应五个步骤，成功地获得了具有单一手性的的2，2'-二乙炔基-1，1'-联萘。

Under UV irradiation, ordered diacetylene molecules can be polymerized and form polydiacetylene vesicle.

有序排列的联乙炔分子，在紫外光照射下发生聚合。

Using 1,4-dibromobenzene,1,3,5-tribromobenzene and 2-methyl-3-butyn-2-ol as starting materials and PdCl2,triphenylphosphine,CuI and KOH as catalysts,1-bromo-4-ethynylbenzene,1,4-diethynylbenzene and 1,3,5-triethynylbenzene were synthesized by Sonogashina coupling reaction and elimination reaction.

以对二溴苯、1，3，5-三溴苯和2-甲基-3-丁炔-2-醇为原料，在PdC l2、PPh3和CuI的催化作用下进行Sonogash ina偶联反应，偶联产物在KOH作用下发生消去反应，分别得到对溴苯乙炔、对二乙炔基苯、1，3，5-三乙炔基苯。

Recently, ''click'' reaction has been regarded as a simple and versatile coupling strategy for the functionalization of nanoparticles.12 It is a green and ecient coupling approach, utilizing the copper-catalyzed 1,2,3-triazole formation between azides and terminal acetylenes.

近来，&点击&反应已经被看作一种用于纳米粒子功能化的简单而万能的偶联策略。[12] 它是一种绿色而有效的偶联方法，利用叠氮化物和端乙炔之间的铜催化1，2，3三氮唑的形成。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。