羰基的

A novel carbonyl transposition led by anilines'nucleophilic addition to methyl 2-keto α-D-glucopyranoside was discovered. And the mechanism of the reaction concerned to an enol rearrangment was provided through tracing the change of 〓H-NMR and 〓C-NMR of a hemiacetal intermediate which was obtained in the reaction of o-phenylene diamine with 2-keto glycoside. Both the intermediate and the converting product were identified by 〓H-NMR,〓C-NMR,〓H-〓H COSY and HMQC.

一、发现了2-位氧化α-甲基D-葡萄糖苷的芳胺亲核加成引起羰基转位的新方法，利用核磁共振氢谱及碳谱对邻苯二胺与2-位氧化α-甲基D-葡萄糖苷加成生成的稳定中间体半缩酮化合物在氘代丙酮中的变化进行跟踪，结合对转化产物的氢氢相关谱和HMQC结构确证，提出了该反应中2-位羰基通过烯醇化互变而转至3-位的机理并得到了验证。

In this paper, with 2-oxo-propionic acid salicyloyl hydrazone as a ligand, one calcium complex, three copper complexes and thirteen rare earth(RE=La, Ce, Pr, Nd, Sm, Eu. Gd, Tb, Dy, Er, Tin, Yb and Lu) complexes have been synthesized. The crystals of four complexes were obtained, and the crystal structures were determined by single crystal X ray diffraction. One of the crystals is calcium complex, the other are binary and trinary complexes of copper.

本文选用2-羰基丙酸水杨酰腙作为配体，在水中分别与钙、铜、稀土(RE=La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Er、Tm、Yb和Lu)的盐反应，共制得了17种未见文献报道的配合物，另外还培养了2-羰基丙酸水杨酰腙、咪唑与铜、钙的二元及三元配合物的四种单晶，对La-Gd的稀土的配合物进行了溶解热的测定，并用Gauss-98软件包对铜的配合物进行了有关量化计算。

The studies are significant to propose the synthetic methodology of benzothiazole derivatives,broaden the application of the metal complexes of benzothiazoles.It is practical value of the research in preparation of phenylacetic acid from metal-catalyized carbonylation.The thesis consists of four chapters.

本论文研究了苯并噻唑衍生物及其钴、铑金属配合物的合成，并研究了两类金属配合物的羰基化催化性能，提供了合成苯并噻唑衍生物的可行路线，拓宽了苯并噻唑金属配合物的应用范围，催化羰基化合成苯乙酸的研究具有重要的实用价值。

Calculated results show that S〓, T〓, and T〓 electronic states are very close in energy for simple thiocarbonyl compounds such as CH〓CHS and 〓CS, and the excitation energies are relatively lower.

计算表明，对于简单的硫代羰基化合物CH〓CHS和〓CS，其S〓、T〓和T〓电子态的能量非常接近，并且激发能比较低，我们推测硫代羰基化合物的光化学反应很有可能是从能量较高的S〓态开始的。

Since the element sulfur has lower electro-negativity than oxygen and the C=S double bond is easier to be polarized than C=O double bond, thiocarbonyl compounds and carbonyl compounds have different reaction properties, and their photochemical reaction mechanisms often possess dramatic difference.

但是，由于硫元素较低的电负性和C=S双键较高的可极化性，硫代羰基化合物和羰基化合物有着本质不同的反应特性，光化学反应机理常常存在着戏剧性的差别。

Ferric chloride catalyzed direct conversion of carbonyl compounds to the corresponding chloride with silicon hydride ( dichloromethylsilane , chlorodiphenylsilane or trichlorosilane) was realized.

在甲基二氯硅烷作用下，FeCl3能催化羰基化合物的还原氯代反应，得到相应的氯代产物；在甲基二氯硅烷、PBr3或NaI作用下，FeCl3可以催化羰基化合物的还原溴代或碘代反应，分别以良好的收率得到相应的溴代烷或碘代烷

After 10h ball milling, the alloy of carbonyl iron and carbonyl nickel began to form, and the sample kept its original bcc and fcc structure; after 100h ball milling, the sample became a solid solution with bcc structure; after 200h ball milling, the diffraction peak of Ni almost disappeared and the isotropic grains with D achieved, which was mainly attributed to the dislocations and disclinations of the nanocrystalline bcc FeNi suffering from severe plastic deformation by ball milling.

球磨10h时，羰基铁和羰基镍开始形成合金，但大部分Fe、Ni原子仍分别以bcc结构和fcc结构存在。球磨100h时，样品以bcc结构的FeNi合金为主，球磨200h后，样品中fcc结构Ni特征峰几乎消失，FeNi纳米晶达到最小粒径的平衡值，~8nm。高能球磨过程中，晶界区域的层错缺陷是合金化和纳米晶形成的重要因素。

Once the prodrug is in the blood supply, esterases hydrolyse the ester to unmask the carboxylate group and the drug can interact with its target.

药物的醚作为前体药物，口服作用时，由于醚把羰基官能团的极性遮掩了，前体药可以穿越肠内壁的细胞膜，一旦前体物进入血液循环，就会发生水解暴露出羰基使药物与目标相互作用。

Having consulted all the available literature on the subject, according the basic principal and method of design of radar absorbing materials, composites of epoxy resin-coated ultramicro iron, ultramicro iron-coated hollow glass bead, and hollow glass bead /ultramicro iron/ EP with three-layer structure were prepared.

本文是在查阅了大量国内外文献的基础上，依据雷达波吸收材料研究的基本理论和设计方法，以羰基铁为重点研究对象，采用原位复合的方法制备环氧树脂包裹羰基铁、超微铁包裹中空玻珠以及中空玻珠／超微铁／EP三层结构复合粒子。

The principle and technology of production of refined nickel from carbonyl nickel and the application of nickel products are introduced with on analysis of technical progress and market prospect of carbonyl nickel in China and abroad.

本文简述了羰基法精炼镍的技术原理、工艺技术及其产品的主要应用，同时对国内外羰基镍技术的进展及市场展望进行了探讨和分析。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。