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The Carbonyl Compound Mode Evaluation Device is a research chemical production line newly built by Lanzhou Institute of Chemistry Physics Chinese Academy of Sciences, whose main intention is to make qualitative and quantitative evaluation of the properties of cobalt salt catalyst through the process of producing high-carbon alcohol with carbonyl compound .

"羰基合成模试评价装置"是中科院兰州化学物理研究所新建的研究性化工生产线,主要是通过羰基合成制高碳醇的过程,对钴盐催化剂性能做出定性定量的评价。

Carbonyl iron fibre with different Fe content (90%~98wt%) and diameter (200nm~l0μm) had been fabricated by adjusting fibre growth factors, such as velocity of Fe5 vapor and protective gas, temperature of chemical decomposition and magnetic field strength. So the diameter of carbonyl iron fibre could be controlled from micron to sub-micron.

对羰基化合物气化速率、保护气氛流量、分解温度和外加磁场强度等因素的调控,制备出铁含量在90%~98%可调、直径在亚微米到微米(200nm~10μm)及长径比可控的羰基铁纤维。

Diketoreductase is a new class of enzyme, and compared to other oxidoreductase, the unique property is that it can be reduced diketone substrate to corresponding dihydroxy alcohol with high stereoselectivity.

双羰基还原酶(Diketoreductase,DKR)是一类全新的酶,与其他的氧化还原酶相比,其独特之处在于它能够同时还原两个羰基还原成羟基,并有高度的立体选择性。

Diketoreductaseis a class of new enzyme, and compared with other oxidoreductase, whose uniqueness lies in its ability to restore at the same time reduced to two hydroxy carbonyl and a high degree of stereoselectivity.

双羰基还原酶(Diketoreductase,简称DKR)是一类全新的酶,与其他的氧化还原酶相比,其独特之处在于它能够同时还原两个羰基还原成羟基,并有高度的立体选择性。

Synthesis, spectral and structural studies of isomerized products of isopreneiron complexes and crystal structure of tetracarbonyl ethoxypentachloroph

异戊二烯二羰基铁配合物的异构化产物的合成,波谱和结构研究及四羰基铁的晶体结构

Thiocarbonyl compounds have similar chemical properties to those of carbonyl compounds because of their similar valence electron structures.

硫代羰基化合物与羰基化合物具有相似的价电子结构,因而具有类似的化学性质。

Fu Xiangkai Carbonylation reaction in biphase system is the important atomic economicreaction in the field of green chemistry.

含膦酸根等水溶性膦配体及其钯配合物的合成、表征和催化羰基化反应两相催化体系的羰基化反应是一类重要的绿色化学&原子经济型&反应。

The LUMO electron density geometry distribution of N-TPA1 is located on the cyanoacrylic group which favour electron injection,but for N-TPA2 it is mainly concentrated on the rhodanine framework,and resulting in the position of LUMO isolated from the -COOH anchoring group due to the presence of the -CH_2- group.

由于罗丹宁乙酸基团的羰基与五元环构架间隔一个亚甲基,使得LUMO电子分布距离吸附基团远,阻碍电子经由羰基注入TiO_2导带,这是N-TPA2的敏化电池效率比N-TPA1低的原因之一。

But very little literature concentrated on the activated methyl which closes to the carbonyl of enaminones. So the paper conducts the research to the aldol condensation of aromatic aldehydes with the activated methyl of enaminone.

但却很少有文献对烯胺酮类化合物的羰基α位活泼甲基进行研究,因此本论文对烯胺酮羰基α位活泼的甲基与芳香醛发生缩合反应进行了研究。

The polymerization mechanisms of DTC, TMC and CL initiated by Ln 〓 were fully studied for the first time, and proved to be a"coordination insertion anionic mechanism". Monomer coordinated to rare earth metal on the carbonyl group, and opened ring via acyl-oxygen bond cleavage, forming a growing chain.

本文首次研究了Ln〓引发DTC、TMC和CL聚合的机理,证实都符合&配位插入阴离子机理&:单体首先以环外羰基和引发剂中稀土原子配位,并发生羰基加成,随之通过酰氧键断裂开环而插入到Ln-O键中实现链引发,然后各单体重复上述稀土原子参与的配位、加成、开环、插入聚合步骤,活性链在Ln-O端增长。

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