羰基的

The variables considered in this study were the metallic substrate (cold rolled steel and phosphatized cold rolled steel), the thickness (20 and 25 mm), and finally the deposition potential in the cataphoretic cell...

红外光谱显示，作为材料老化的标志，羰基浓度随照射时间的增加而增加，但是紫外线结果显示羰基峰值随照射的增加而降低。光程长度、羰基浓度的变化以及C–H。。。

In ionic liquid, the carbonyl peak of AA is 1739 cm^(-1), and DHAA is 1785 cm^(-1), in comparison with the dissociative carbonyl peak, both of which show Einstein shift.

在EMIMBF4中，AA的羰基峰出现在1739cm^(-1)处，DHAA的羰基峰出现在1785cm^(-1)处，它们相比于游离态的羰基发生了红移。

Formyl-3-acetyl-4-methyl-5-carbobenzoxypyrrole (6) was synthesized via the selective oxidation of 2,4-dimethyl-3-acetyl-5-carbobenzoxypyrrole (5), which was produced from acetylacetic benzylester (1) via nitrosation, reduction and addition-cyclization with acetylacetone. The total yield of the product was about 34%.

以乙酰乙酸苄酯(1)为原料，经过亚硝化、还原、与乙酰丙酮加成环化生成2， 4-二甲基－3-乙酰基－5-苄氧羰基吡咯(5)，通过选择性氧化反应制得目标化合物2-甲酰基－3-乙酰基－4-甲基－5-苄氧羰基吡咯(6)，反应的总收率约为34%。

A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3－甲氧基丁烯－1及其混合物)或者丁二烯与醇的混合物羰基化的方法，以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进，用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β－γ不饱和羧酸酯(如甲基－3－戊烯酸酯)的方法。

The 6- cyano-1, 1 (1, 3- dioxypropylidene)-7-(carbomethoxyl group- methyl - 5- oxo-Delt6 (8)- tetrahydrochysene indolizine and haloethane reacts with each other for ethylization with existence of alkali and organic solution with or without phase transversion catalyst, and produces mentioned product.

本发明在相转移催化剂或无相转移催化剂存在下，6-氰基-1，1-(1，3-亚丙二氧基)-7-(甲氧羰基-甲基-5-氧代-Δ6(8)-四氢中氮茚类化合物与卤代乙烷在碱和有机溶剂的存在下进行乙基化反应即得6-氰基-1，1-(1，3-亚丙二氧基)-7-1′-(烷氧羰基-丙基-5-氧代-Δ6(8)-四氢中氮茚类化合物。

The aim of this study was to develop a novel amphiphilic functional block poly(ε-caprolactone) bearing ketone groups MPEG-b-P(OPD-co-CL. 2-oxepane-1, 5-dione was copolymerized with ε-caprolatone in which methoxy poly (MPEG, Mn=5 000) and stannous octoate were used as initiator and catalyst, respectively. The syntheses were conducted by bulk and solution polymerization. 1H NMR results showed that peak position and splitting of the polymers synthesized through solution polymerization were consistent with theoretical data, demonstrating the products were designed block copolymers. While in the bulk polymerization, polymer peak position was changed due to their high reaction temperature, suggesting their structural variation.

将带有羰基官能团的4-羰基己内酯和ε-己内酯分别在甲氧基聚乙二醇(MPEG，Mn=5 000)为引发剂，异辛酸亚锡为催化剂溶液和本体体系中开环聚合，合成了两亲性侧基带有羰基官能团的聚己内酯嵌段共聚物MPEG-b-P(OPD-co-CL.1H NMR结果表明采用溶液聚合法合成的聚合物各峰的峰位置和分裂情况与理论一致，证明了产物是实验所设计的嵌段共聚物，而采用本体聚合法合成的聚合物由于温度的影响，聚合物各峰的峰位置发生了变化，说明其结构发生了变化；差示扫描量热法分析结果表明随着OPD单体含量的增加，聚合物的熔点，玻璃化转变温度和熔融焓增加；热失重测试结果表明OPD单体的引入增加了聚合物的热敏感性。

Alkyl manganese pentacarbonyl compounds5MnR (R = CH3, p-CH2C6H4CH3, p-CH2C6H4OCH3) were synthesized by metalation of manganese pentacarbony potassium salt with corresponding alkyl halides in ether. Photolysis of these with 1-2 equivalent of (CH3)2(C6H5)SiH or (CH3)(C6H5)2SiH in C6D6 solution at 5℃ produces silyl manganese pentacarbonyl compounds5MnSi(C6H5)(CH3)2 and5MnSi(C6H5)2(CH3) respectively (yield 70-88%).

用五羰基锰钾盐和相应的卤代物在乙醚中的金属化反应合成了五羰基锰烷基合物5MnR（R = CH3，p-CH2C6H4CH3， p-CH2C6H4OCH3 ），产率达到72-93％，将这些化合物与1-2当量(CH3)2(C6H5)SiH和(CH3)(C6H5)2SiH的C6D6溶液在5℃光解，分别得到五羰基锰硅烷基化合物5MnSi(C6H5)(CH3)2和5MnSi(C6H5)2(CH3)（产率达到70-88％）。

In chapter 4, we have described an improved method for the preparation of ethynylferrocene. Ethynylferrocene was prepared in satisfactory yield by reaction of formylferrocene with triphenylphosphine and carbon tetrachloride followed by dehydrohalogenation in the presence of n-BuLi.

第三章中，我们研究了钯催化下碘杂环化合物的羰基化—酰胺化反应、羰基化—酯化反应和与末端炔烃的羰基化交叉偶联反应，为一步合成多官能团化合物开辟了新的途径，同时，得到的这些产物经过进一步官能团转化后，可以成为一些天然产物合成中的重要中间体化合物。

The complexing properties of compounds 10a, 10b, 11a and 11b toward alkali metal ions were studied by 〓H NMR titration, ESI-MS, UV-Vis spectra, Fluoresence spectra and liquid-liquid extraction. The results show:(1) the 1:1 complexes were formed.(2) The calix-crown 10a, 11a have a higher selectivity for Na〓 ions, whereas 10b, 11b for K〓 ions.(3) The complexing ability toward alkali metal ions was enhanced when the calix-crown have side arm carbonyl.(3) The coordination of alkali metal ions toward phenoxy, carbonyl and crown ethereal oxygens take place by rotation around the carbon-carbon bond of carbonyl and methylene.

六，用〓H NMR滴定，ESI-MS，UV-Vis，Fluorescence，液-液萃取实验研究了10a，10b，11a和11b对金属离子的配位性质，研究结果表明：1）杯芳烃冠醚衍生物同碱金属离子形成了1：1配合物，化合物10a、11a对Na〓具有较高的配位能力，化合物10b、11b对K〓具有较高的配位能力；2）在杯冠醚环的旁边引入带有羰基氧原子的基团作为侧臂参与配位可以加强对碱金属离子的配位能力；3）金属离子分别同苯酚氧，羰基氧，聚氧醚链氧发生了配位，配位过程中侧链基团涉及到了羰基碳与亚甲基碳的碳碳键的旋转过程。

In order to obtain the processing parameters of high speed depositing nickel film, experiment was undergone by metallic organic chemical vapor deposition with nickel carbonyl as precursor.

为了获得高速沉积镍膜的工艺参数，以羰基镍 [Ni 4 ]为前驱体，用金属有机物化学气相沉积法进行试验，以SEM ，DSC ，XRD测试分析技术探讨了载气、温度和羰基镍的摩尔分数对沉积速率的影响；也探讨了温度及羰基镍的摩尔分数对镍膜微观形貌的影响。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。