羰基的

Through the use of high-level quantum-chemical calculations, two experimentally observed isoenergetic isomers are assigned to complexes in which a water dimer is hydrogen-bonded either to the carbonyl oxygen of the ester function or to the amino nitrogen.

通过高层次的量子化学计算上的应用，两个实验观察isoenergetic异构体被分配到复合物，其中一个水二聚体的氢键要么酯的羰基氧的功能或对氨基氮。

Olefine, electrophilic or nucleophilic substitution of arenes, nucleophilic addition of carbonyl compounds stereochemistry in elimination reaction of double bond forming and the choosing of oxidants and reducing agents in redox system.

在化学反应方面重点是烯烃的亲电加成，芳香烃的亲电，亲核取代，羰基化合物的亲核加成，消除反应的双键定位和立体化学，氧化，还原反应中氧化还原剂的选择。

Through this research,we extended the appliacation of organozinc reagents in organic synthesis.

通过这些研究，我们扩展了有机锌试剂的应用范围，提供了高产率的合成γ-羰基酯化合物的有效方法在第三章中，我们研究了有机锌试剂在Baylis-Hillman类型反应中的应用。

A pentacarbonyl complex (3) isolatedfrom the same reaction from which the complex (1) is obtained, whose accuratestructure is yet known, is preliminarily studied.

对从含吡啶基团的二硫醇三齿配体与Fe_3_(12)的反应中得到的另一个准确结构有待确定的五羰基化合物(3)进行了初步的性质研究及表征。

Nevertheless, the yield of pinacol was also strongly affected by the steric environment surrounding the carbonyl group. The pinacol coupling of aromatic aldehydes has been achieved with high yields under such a condition. However, the diastereose-lectivities of pinacols were not satisfying. Unfortunately, the ketones and most aliphatic aldehydes appeared inert under the same reaction conditions.

然而， 呐偶合反应的产率受到羰基周围环境的立体位阻影响较大，在此条件下，锌粉能有效地促进芳香族醛类化合物进行水相呐偶合反应，得到的呐醇产率高，但非对映异构体选择性差，而脂肪族醛类化合物得到的呐醇产率较低，在同样的条件下，酮类化合物不能顺利进行呐偶合反应。

The FTIR of lignin-based polyhydric alcohol shows new characteristic peak of carbonyl is formed and the characteristic peak of aromatic ring and polyether at 1600cm-1 and 1110cm-1 respectively, which induce there is linkage of chemical bond.

所得木质素多元醇通过红外光谱图表明在1750cm-1附近有新的酯羰基生成，并且在1600cm-1含有木质素的芳香环和1110cm-1的聚醚链，表明木质素磺酸钙与聚醚多元醇在互溶过程中有化学键的接合。

Addition of metallated terminal alkynes to carbonyls is considered as an effective route for the synthesis of chiral propargyl alcohols and has gained considerable significance in recent years.

末端炔对羰基化合物的不对称加成反应是构建手性炔丙醇的重要方法之一，其产生的光学活性炔丙醇是很多天然产物，精细化学品及药物分子的重要合成砌块。

The asymmetric alkynylation of carbonyls is proved to be one of the most powerful procedures for organic synthetic chemistry,where the formation of one carbon-carbon bond and one chiral center of propargylic alcohol can be achieved in one step,and has attracted organic chemists\' most attentions.Plenty of works have been reported in recent years.

由于催化末端炔对羰基化合物的不对称加成在制备手性炔丙醇的同时，能够构建一个碳碳键和一个手性中心，因而该领域的研究受到了研究者的广泛关注，有大量的研究工作见报道。

The magnetic properties of carbonyl iron particle s were characterized by VSM;the apparent viscosities and the magnetic field-induced shear stresses of the magnetorheological fluids above were investigated by an advanced rheometric expansion system;the properties of MR damper were tested by an electro-hydralic servocontrol testing system.

研究了一种新型MR液和MR阻尼器；用振动样品磁强计测试了MPS-MRF-25羰基铁粉的磁性能；用磁流变仪测试了MR液的表观粘度和磁致剪切应力；用静置沉降法分析了MR液的抗沉降稳定性；用电液伺服材料性能试验机测试了MR阻尼器的性能。

The energy gaps among the S1, T1 and T2 states are very small, but the S2 state is much higher than the T2 state in energy. Similar results were found for other thiocarbonyl compounds.

计算结果表明： S1， T1和T2态的能量非常接近，而S2的能量远远高于T2态，这与之前对几种小的硫代羰基化合物的研究结论一致。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。