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The macro conjugated molecule fluorene derivative has 2, 3, 6, 7-tetraamino-9, 9'-dialkyl fluorene as a raw material which is added to an organic solvent respectively together with phenanthrenequinone, acenaphthene quinone or bis-carbonyl pyrene derivatives and strong base; under the protection of inert gas, reflux reaction is carried out to the materials, so as to prepare a series of trapezoidal conjugated molecules containing fluorine structures.

本发明涉及一类含大共轭分子的芴衍生物及其制备方法,大共轭分子芴衍生物是将原料2,3,6,7-四氨基-9,9'-二烷基芴,分别与菲醌、苊醌或二羰基芘的衍生物以及强碱加入到有机溶剂中,在惰性气体的保护下,回流反应制得一系列含有芴结构的梯形共轭分子。

In the paper, the research evolvement of electrocarboxylation from carbon dioxide with olefin, alkyne, and ketones in near decades was summarized, these reactions were convenient ways to synthesize some valuable pharmaceutical precursor and intermediates in organic synthesis.

文章综述了近几十年来二氧化碳与烯烃化合物、炔烃化合物以及酮类化合物的电羰基化反应的研究进展,这些反应是合成一些有价值的药物前驱体或是有机合成中间体的简便方法。

The effect of the frying time on peroxide value, acid value and carbonyl value was also analyzed.

主要探讨了真空低温煎炸胡萝卜片后3种煎炸油的稳定性,研究了3种煎炸油的酸值、过氧化值、羰基值随煎炸时间的变化规律,并分析了它们之间的相关性。

Other than conventional concept, the N→Rh bond, formed by rhodium in the complex and nitrogen at pyridine ring in the ligand, did not break in the course of the carbonylation reaction, but formed into new active species instead, i.e., the ligand and rhodium as a whole participated in the oxidative addition of CH3I and the formation of CH3COI.

配合物中铑与吡啶环上共轭N形成的N→Rh配键,在羰基化反应过程中并非通常认为的断裂而是形成新的活性物种,即配体与铑作为整体参与了CH3I的氧化加成及CH3COI的生成过程。

In the titration experiment of NMR and IR spectroscopy, we can understand how sensors binding with metal ions: the two carbonyl group and crown ether group cooperated in binding with metal ions. Furthermore, by altering the "oxygen" atoms of crown ether to "sulfur", we can change the binding affinity to the soft metal: cupper. It shows 60-fold enhancement of fluorescence.

在化合物2中,我们引进了硫原子在冠状醚中,则应对电子密度较低之金属有较好的结合能力,实验结果显示了此分子对铜离子有相当好的选择性和结合能力,萤光增加可达60倍;同时由红外光吸收光谱和核磁共振光谱滴定实验可确知,香豆素衍生物上的两个羰基对金属离子的选择性及结合上扮演相当重要的角色。

The molar ratio of different metal ions within support, the preparation methods of supports and catalysts, and other factors had been studied. The activity of catalyst was evaluated by the synthesis experiments of diphenyl carbonate.

实验考察了载体金属离子的组成和配比、载体和催化剂的制备方法等因素对催化活性的影响,以苯酚氧化羰基化反应合成DPC的实验结果对催化活性进行了评价。

By this reaction, an aldose is converted into another aldose and the corresponding ketose, and a ketose is converted into the corresponding two aldoses.

单糖的异构化涉及羰基和相邻近的羟基,通过这个反应,一种醛糖转化为另一种醛糖,和相对应的酮糖,一种酮糖转化为相对应的两种醛糖。

Therefore, studies and applications of the ring-opening reaction of 1, 3-dithiolancycolpentyl moiety should be a valuable research project.

因此,α-羰基环二硫缩烯酮的1, 3-二硫戊环的开环反应及其在合成中的应用研究是一重要的研究课题。

The Mn is coordinated by four carbonyl O atoms from the DMF molecules and two phenolate O atoms of the picrate anions, forming a distorted octahedral structure.

在不对称单胞中存在着两种配位环境相同的Mn离子,四个DMF中的羰基氧原子和两个苦味酸根离子中的酚氧原子直接和Mn离子配位,形成了一个扭曲的八面体几何构型。

The results indicated, catalytic activity was very high, the average rate of O 2 uptake was 4.25×10 -2 mmol/min after 10 min, the yield of cyclopentanone was up to 83%.

实验结果表明,该催化体系对环戊烯的羰基化显示出较高的催化活性,反应 1 0 min,反应的平均吸氧速率为 4.2 5× 1 0 -2 mmol/min,环戊酮的收率可达 83%。

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