羰基的

The blend has following properties with 10 parts compatibilizer. The tensile intensity and elongation at break reach 35.66MPa and 23.58%, respectively, improving by 26.6% and 65.7% respectively compared with 0 part compatibilizer; The characteristic absorption peak of carbonyl at 1725～1800cm-1 disappear and the characteristic absorption peak of hydroxide at 3438～3440cm-1 increase induce the formation of hydrogen bond; The decalescence peak of blend increase by 2℃compared with the blend containing 0 part compatibilizer near 100℃; Lignin can be dispersed homogeneously to avoid reuniting of lignin particle.

2当共混材料中增容剂含量为10份时，共混材料表现出如下特性：拉伸强度和断裂伸长率分别达到35.66MPa及23.58%，较未加增容剂分别提高了26.6%和65.7%；从1725～1800cm-1范围内羰基特征吸收峰接近消失以及3438～3440cm-1范围内的羟基波数的增加暗示了共混材料中氢键缔合的发生；共混物在100℃附近的吸热峰较未加增容剂时降低了近2℃，相容性得到了提高；木质素在基体中进一步分散，结晶度增加，从而阻止木质素的团聚，增加了两相的相容性。

A preparation method of nickel oxide-base cathode of fused carbonate fuel cell is to select alkali earth metal oxide, transition metal oxide and rare-earth metal oxide, mix with carbonyl nickel powder in the proportion of 0.01-15.00 mol%, add assistant and mix even into a slurry; after the slurry is formed into a biscuit by doctor-blade casting, sinter it into a multi-porous nickel plate; dissolve lithium nitrate and cobaltous nitrate with mole ratio of Li:Co-1:1 and citric acid or PVA in the distilled water to make a solution with Li of 0.00-0.5 mol/L; immerse the multi-porous nickel plate or nickel oxide plate in the solution, keep for 10-60 minutes under vacuum below 200 millibar, then dry in an oven at 75 degrees centigrade further transfer to a crucible electric furnace preheated 650 degrees centigrade for keeping the temp.

要約 熔融碳酸盐燃料电池氧化镍基阴极的制备方法属于燃料电池领域。选取碱土金属氧化物、过渡金属氧化物和稀土金属氧化物，按0.01－15.00mol％的比例与羰基镍粉混合，加入助剂，混合均匀成浆料；混合浆料流延成型为素坯后烧结为多孔金属镍板；将摩尔比为Li∶Co＝1∶1的硝酸锂和硝酸钴以及柠檬酸或聚乙烯醇溶于蒸馏水中，制成为0.005－0.5mol/L的溶液；将多孔金属镍板或氧化镍板浸入溶液中，在真空度低于200毫巴下保持10－60分钟；置于75℃的烘箱中烘干，转移至预热到650℃坩埚电炉中保温1－10小时；将此过程重复一次或多次即可。

Synthesis of pyruvic acid from lactic acid by catalytic oxidation with oxygen was studied. The effect of catalyst composition, amount of catalyst and oxygen, reaction temperature and time on product yield was investigated and the optimum conditions were found.

由于丙酮酸的分子中同时具有羰基和羧基两个官能团，因而反应中心多而显出比一般化合物更为重要和特殊的化学性质，已引起越来越多的化学工作者的重视。

The synthesis of the pentacyclic skeleton of Et-743 and the construction of the five chiral centers thereof.1. The core pentacyclic skeleton of phthalascidin was constructed with L-dopa as the starting material via thirteen steps. First, two basic synthons, the C-1 functionalized tetrahydroisoquinoline compounds 8 and N-protected Z-dopa derivative 9, were prepared from L-dopa. They were coupled via amide bond to form the dipeptide compounds 10, which were the first key intermediates. Then the primary hydroxyl groups were transformed into the corresponding amino aldehydes 11 via Swern oxidation. Followed by the intramolecular Pictet-Spengler cyclization, the pentacyclic compounds 12 were synthesized.

五环骨架的构建及五个正确手性中心的确立：1.1我们以L-多巴为起始原料，经过多步官能团保护和转化合成了基本结构单元8然后和苯丙氨酸衍生物9，通过缩合反应生成酰胺中间体10，经Swern氧化得到醛化合物11，然后再次利用分子内改良的Pictet-Spengler反应一步构建c，d两环，得到五环骨架化合物12，最后，实现了21-位羰基向氰基的转化，得到了C-1位官能化的化合物14，化合物14不但具有和Et-743一致的五环骨架，而且分子中五个手性中心立体构型也与其完全相同：其中，3，位和13，位的手性中心由原料L-多巴带入，而1，位，11，位和21，位手性中心则通过不对称诱导而确立。

The major causes of off-flavour of the cooked rice was due the intractions among rice proteins, lipids and carbohydrates, which result in the production of carbonyl compounds,the increase of caproaldehyde,and the decrease of acetaldehyde and mercapto group as well as the changes in the cell wall structures.

本文结合近几年研究工作及国内外对大米陈化研究的新进展，综合阐述了随大米存放时间的延长，其化学组织特别是大米蛋白质、类脂与淀粉的共同作用，促使羰基化合物的生成、乙醛减少、己醛增加、SH基减少，以及胞壁改变，是造成大米陈化、米饭&陈米臭&的主因。

Goodcatalytic activities of the phosphine palladium complexes were observed incarbonylation of benzyl chloride with atmospheric CO. In some reactions the yieldof phenylacetic acid was 91% and the catalyst could be reused repeatedly in severaltimes.

这些钯配合物催化苄基氯的常压羰基化反应有较好的催化活性，有些反应中苯乙酸的产率可达91％，可重复使用，是一类环境友好的新型绿色催化剂。

We screened a set of Lewis base organocatalysts derived from chiral pipecolinic acid and tert-butanesulfinamide for the reduction of-N-Cbz-1- phenylpropenamine, including newly designed ones and some of those previously developed in our lab. However, only moderate stereoselectivities, albeit high yields were obtained.

在本课题组前期研究的基础上，我们筛选并设计了一系列以手性哌啶酸和叔丁基亚磺酰胺为母体的有机小分子路易斯碱催化剂，它们能催化三氯氢硅对-N-苄氧羰基-1-苯基丙烯胺的不对称还原，获得很高的收率和中等的对映选择性，并且具有很好的底物普适性。

We have presented a practical method for the preparation of propargylic alcohols from terminal alkynes and carbonyl compounds promoted by KOH in the presence of 18-crown-6,and subsequent efficient cyclizations of propargylic alcohols with 2-naphthol catalyzed by InCl_3·4H_2O under the solvent-free ball-milling conditions.Ball milling exhibits its superiority over the reported methods in the preparation of propargylic alcohols and naphthopyran derivatives.

采用机械研磨方法进行了连续的两步固相化学反应的研究：首先，在氢氧化钾和18-冠-6的作用下，端基炔和羰基化合物在机械研磨条件下反应可以高效地生成相应的炔醇化合物；其次，在四水合三氯化铟的催化作用下，生成的炔醇化合物和2-萘酚在机械研磨条件下环加成生成相应的萘并吡喃产物。

The results indicated that Eu3+ mainly interacts with the carbonyl oxygen in the amino acid residues of the peptide chain of CAT because rare earth ions are easy to coordinate with O, causing the change in the peptide conformation and in turn the change in the structure of the heme group of CAT.

结果表明，由于稀土离子易与O键合，因此，Eu3+主要与CAT肽链上的氨基酸残基中的羰基氧配位，引起肽链构象的变化，而构象的变化又会诱导CAT中的血红素结构的变化。

The principal component of water-soluble acids is the saturated aliphatic diacids of C〓 to C〓 and the saturated aliphatic monoacids of C〓 to C〓; and the water-insoluble acids are organic macromolecular compounds containing a large amount of carbonyl, carboxyl structures and aromatic group.

水溶酸的成分以C〓~C〓的饱和二元脂肪酸和C〓~C〓的饱和一元脂肪酸为主；水不溶酸是含有大量羰基、羧基结构和芳环的有机大分子化合物，其结构非常接近腐植酸。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。