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When the powder loading was fixed as 58%,the molded compact of a gearwheel whose addendum circle diameter is 700 μm was obtained with well shape retention.

3μm的羰基铁粉和石蜡基热塑性粘结剂体系,当粉末的装载量为58%时,获得了形状良好的齿顶圆直径为700μm的微型齿轮注射生坯。

The thermolysis of the isomerized products derived from norbornadiene-coordinated carbonyl iron complexes gave two sorts of the thermolytic products based on different substituents on the olefin ligands. One is the corresponding diiron dimer complex, and the other is the complex in which the C-C bond of the cycloolefin ligand is broken.

以降冰片二烯三羰基铁络合物衍生出来铁卡宾络合物的异构化产物的热解,随着烯烃配体上取代基的不同,而分别得到了络合物发生二聚和烯烃配体发生碳碳键断裂的两类热解产物。

At lower temperature, the interaction between the Ir particles and the adsorbed ethoxyl species is not strong enough to abstract H atom from the nearby CH3 group, and thus acetaldehyde acts as the key intermediate. Acetaldehyde can decompose to methane and CO and/or convert to acetone through decarbonylation.

低温时Ir粒子与吸附的乙氧基的相互作用的强度不足以从-CH3基团中提取H原子,此时乙醛是关键的反应中间物,乙醛可以裂解生成甲烷和一氧化碳或脱羰基生成丙酮。

In the fourth chapter, four new complexes of hydrazide of podophyllic acid with transition metals have been prepared. Elemental analysis, molar conductivity, IR,〓 NMR and TG-DTA were used to characterize them. The results show that general formula of the complexes is M〓(n=0 or 2). The ligand is linked through the carbonyl oxygen and the terminal nitrogen of the hydrazide base to the transition metal ions in bidentate mode.

第四章 合成了四种鬼臼酰肼的过渡金属配合物,通过元素分析、摩尔电导、红外光谱、核磁共振氢谱和热重-差热对配合物进行了表征,研究结果表明,配合物的组成为M〓(n=0或2),配体是通过羰基氧和肼基上的端氮以双齿形式与金属离子配位的。

The FTIR spectrum showed that the ketone carbonyl groups of DAAM reacted with hydrazide groups of ADH to form hydrazone during film formation.TEM picture showed that the structures of particles were core and shell, and TGA curves indicated that the thermal stability of cured film decreased, which was attributed to the presence of C=N groups.

傅里叶红外光谱表明在涂膜形成过程中DAAM的酮羰基与ADH的酰肼基反应生成腙,TEM分析显示乳液的乳胶粒子呈核壳结构,TGA分析发现DAAM改性的PAE降低了涂膜的热稳定性。

Constituting dicycle; 2. region selectively reducing six-membered ring ketocarbonyl radical; 3. introducing 7alpha-hydroxy group; 4. Aldol reaction to introduce side chain and obtain 8alpha-hydroxy group; 5. oxidizing the position 7 hydroxy group into ketone; 6. turning the configuration of the position 7 hydroxy group; 7. glycosidating the position 7 hydroxy group; and 8. eliminating protecting group to obtain the target compound.

该方法包括如下步骤:(1)双环的构建;(2)区域选择性还原六元环酮羰基;(3)7α-羟基的引入;(4)Aldol反应引入侧链,同时得到8α-羟基;(5)7位羟基氧化为酮;(6)7位羟基构型的翻转;(7)7位羟基的糖苷化;(8)脱除保护基得到目标化合物。

Thus if we control the reaction temperature at somesolvent we can obtain the products either by the reaction of phosphoryl-stabilizedcarbonanion with N-tosyl imines or by the reaction of methoxycarbonyl-stabilizedcarbanion with N-tosyl imines.

在一定溶剂中,如果控制反应的温度可以控制得到由膦酰基稳定的碳负离子和亚胺反应或由甲氧羰基稳定的碳负离子和亚胺反应。

Acetic acid equipments using material in PTA, PVA, aldehyde oxidation and methyl alcohol carbonyl synthetic four plants in chemical industry and chemical fibre production are analyzed.

对化工化纤生产中的精对笨二甲酸、聚乙烯醇、乙醛氧化生产醋酸与甲醇羰基合成醋酸4个装置醋酸设备用材进行分析,并对含Cl-、含Br-、含I-的醋酸及含Cl-的甲乙混酸对不锈钢、铜、钛与镍基合金等金属材料腐蚀原因作了讨论。

The reaction is most likely initiated by electrophilic addition of NO to the C-C double bond specifically at the a-position.

反应可能是由少量NO_2对C=C的加成引发的,推测反应过程中在羰基β位形成了以碳为中心的自由基中间体。

Copper iodide CuI has a apparent inhibition effect on addition rearrange of the Grignard reagent with carbonyl compounds.

为抑制烯丙基格氏试剂与羰基化合物加成反应中的重排反应,进行了碘化亚铜CuI对此类格氏试剂及加成产物组分比例关系的研究,CuI对这类化合物加成反应重排有明显的抑制作用。

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