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The results showed that the preoxidation of PPESK was a free radicals reaction,which was initiated by the decomposition of proton in aromatic ring and sulfone functional group and the removal of H_2O and SO_2.When the preoxidation temperature was above 460℃,the radical reaction was initiated by the decomposition of ketone functional group and the removal of CO_2.At last,the three-demensional cross-linking structure containing polyaromatic ether and biphenyl was formed.

研究表明,PPESK的预氧化过程是一个自由基反应过程,始终伴随着芳香环质子和砜基官能团的脱除引发的自由基交联反应,脱出H_2O与SO_2;当预氧化温度超过460℃后,随着反应的进行,由羰基官能团分解引发的自由基交联反应开始发生,脱出CO_2,并最终形成了含有大量聚芳醚和联苯结构的稳定的三维空间网状结构,进而完成PPESK由热塑性材料向热固性材料的转化。

This thesis reported the research of carbonyl allylation and benzylation carded out in aqueous media.

该论文主要研究了纯水作为反应介质时,羰基化合物的烯丙基化和苄基化反应。

This dissertation focused on two types of reactions, oxidative allylation of 1, 3-dicarbonyl compounds and ring-opening allylation of epoxides.

我们重点考察了两类反应:1, 3-二羰基类化合物的不对称烯丙基化反应和环氧化合物的开环烯丙基化反应。

Carbonyl arsonium ylides, which reacted with almost equimolarphenylselanyl iodide, were conversed into α-phenylseleno arsonium ylides in thepresence of triethylamine, affording a new method for the synthesis of α-phenylseleno arsonium ylides.

在弱碱三乙胺存在下半时,稳定的α-羰基胂叶立德和几乎等摩尔量的苯硒基碘作用,转化成α-苯硒基胂叶立德。提供了一个合成α-苯硒基胂叶立德的新方法。

Result Under the pretreatment conditions, the content of acetone extractives transformed. The hydroxyl and carboxyl, belonging to auxochromic groups, were oxidized into the carbonyl and ester groups. Also, there were plenty of auxochromic groups and chromophoric groups in the acetone extractives of silver chain.

结果]刺槐在预处理条件下,丙酮抽出物成分发生了变化,羟基、羧基等助色基团在预处理条件下氧化成羰基、酯基等发色基团,且丙酮抽出物的主要成分中含有大量发色基团和助色基团。

The paper carries on qualitative analysis to the acetone extractives before and after discoloring, shows the main components of the extractives and then takes comparison. The results shows :①The hydroxyl is oxidized and then shifted to the carbonyl,carboxyl, ester and ketone groups during inducing discoloration under the pretreatment conditions,which makes the wood color deep;② There are plenty of auxochromic groups in the acetone extractives of silver chain, the interaction between the auxochromic groups and the chromophoric groups makes the wood color deep.

摘 要:本文通过对刺槐变色前后丙酮抽出物的定性分析,得出变色前后丙酮抽出物的主要成分,进行对比分析,初步得出抽出物对诱发变色的作用为:①变色前后羟基在预处理条件下氧化成羰基,羧基,酯基和酮基等官能团,使木材颜色加深;②刺槐丙酮抽出物的主要成分中含有大量助色基,这些基团会与木素中的发色基团相互作用,使木材颜色加深。

Bulky and electron-rich MOP-type phosphine ligand 2-ditertbutylphosphino-2'-isopropyloxy- 1,1'-binaphthyl (L1) shows good catalytic activity in palladium-catalyzed α-arylation of 1,3-dicarbonyl compounds.

富电子、大位阻MOP型烷基膦配体2-二叔丁基膦-2'-异丙氧基-1,1'-联萘(L1)在钯催化的1,3-二羰基化合物的α-芳基化反应中显示了较好的催化活性。

Bulky and electron-rich MOP-type phosphine ligand 2-ditertbutylphosphino-2 -isopropyloxy 1,1 -binaphthyl (L1) shows good catalytic activity in palladium-catalyzed α-arylation of 1,3-dicarbony compounds.

富电子、大位阻MOP型烷基膦配体2-二叔丁基膦-2'-异丙氧基-1,1'-联萘(L1)在钯催化的1,3-二羰基化合物的α-芳基化反应中显示了较好的催化活性。

The first step in the degradation is most probably the classical ester scission reaction to give a carboxylic acid and olefinic end groups. Further ester scission on the adjacent ester groups of carboxylic acid and olefinic molecular chains can then lead to the formation of lower weight pyrolytic products, such as: CH〓=CHOCOPhCOOCH=CH〓、CH〓=CHOCOPhCOOH and HOOCPhCOOH, and they can pyrolyze continually to produce substrate pyrolytic compounds, such as: HOOCPhCOCH〓、PhCOOH、PhH、PhCOCH〓 and CO、CO〓. At the same time, a corsslinking cyclization reaction occurred of the formation of the gas products during the degradation of PET.

断裂大分子链端邻近羰基和乙烯基的酯键持续断裂,不断地形成小分子裂解产物,如:CH〓=CHOCOPhCOOCH=CH〓、CH〓=CHOCOPhCOOH以及HOOCPhCOOH,这些产物还会进一步裂解成分子量更低的小分子裂解产物,如:HOOCPhCOCH〓、PhCOOH、PhH、PhCOCH〓以及CO、CO〓等,与此同时,一部分乙烯基酯端基的大分子链碎片会发生支化而相互连接,再经&链脱离&和环化反应形成难燃的交联产物。

Preferably, at least one member selected from among heterocyclic compounds having any of hydroxyl, carbonyl, carboxyl, amino, amido and sulfinyl and containing at least either a nitrogen or a sulfur atom is contained in the polishing solution.

优选其中包含杂环化合物,所述杂环化合物含有羟基、羰基、羧基、氨基、酰胺基和亚磺酰基中的任1种,且含有氮和硫原子中的至少1种。

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