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When the sodium lauryl sulfate and p-octyl polyethylene glycol phenyl ether is used and its level in 3% and 6: 4 ratio, the polymerization process has the lowest coagulum and the highest monomer conversion. Higher reaction temperature and more level hydroxyl value lead to more coagulum, the latter also lead to larger particle size. The acid value has larger influence on viscosity and coagulum, there exist a best range. The emulsion particle size is larger for its hydrophilicity, most of its particles are connected together.

在含较高亲水单体的乳液聚合体系中,难以制得稳定的预乳化液,不能采用工业生产中常用的预乳化工艺,而只能采用混合单体直接滴加的方法;由于单体混合物的亲水亲油值较高,用阴离子型乳化剂十二烷基硫酸钠和非离子型乳化剂聚乙二醇辛基苯基醚混合,用量为单体总量的3%,且比例在6:4时,乳液聚合时具有最低的凝聚物含量和最高的单体转化率;乳液聚合反应温度升高,可以提高单体转化率,增加反应速度,但凝聚率相应提高;随着羟基单体含量的增加,聚合过程中凝聚率增加,聚合物乳胶粒平均直径增加;羧基单体有一个最佳的用量(2.6%),过高或过低凝聚率均提高;羧基含量对乳液的粘度有较大的影响,当羧基含量较低时,羧基含量增加,乳液粘度增加明显;含羟基乳液粒子由于含亲水基团较多,使得乳胶粒径增大,乳胶粒子大多数互相凝聚在一起,处于凝聚态。

The biological activity tests show that some target compounds have a good activity as plant growth regulator, and N-5-(3-carboxy-1H-1,2,4-triazolyl)-N'-o- chlorophenylfonnyl urea, N-5-(3-carboxy-1H-1,2,4-triazolyl)-N'-o- bromophenylformyl urea, N-5-(3-carboxy-1H-1,2,4-triazolyl)-N'-p- methyl-phenyl formyl urea have excellent activity of auxin.

生测试验证明部分酰基脲类化合物具有良好的植物生长调节活性,其中N-5(3-羧基-1,2,4-三唑基)-N'-o-氯苯甲酰基脲、N-5-(3-羧基-1,2,4-三唑基)-N'-o-溴苯甲酰基脲和N-5-3-羧基-1, 2,4-三唑基)-N'-p(或m-甲基苯甲酰基脲具有优良的生长素活性。

The study suggests that the carboxyl of the template is the function group responsible for the formation of complementary interacting site in the polymer P1, and the double hydrogen bonds formed between the carboxyl groups of ferrocenecarboxylic acid and methacrylic acid are the main interactions in the recognition process.

研究还表明,FCA的羧基是在聚合物的孔穴中产生识别位点的功能基,模板分子上的羧基与MAA的羧基形成双重氢键作用是分子识别的主要作用力。

WithinPMAO LB films,because the distance between the metal ions is no morethan 0.3nm,the carboxylate groups of a molecule form a nanoparticle(the size is less than 0.2nm)by the hydrogen bond or metal ion asthe bridges.

实验表明,在这种高羧基密度的聚合物中,由于羧基距离较近(<0.3nm),羧基通过氢键或金属离了为桥在分子内聚集成纳米团簇(<2nm)。

Zeta potential,density of surface carboxyl groups,the interaction between carboxyl groups and component in copolymerization emulsion,mechanical properties of films,state of water,particle diameter and distribution of particle diameter and theological behavior of emulsion were investigated by Zeta meter,the conductometric titration, particle size apparatus,dynamic mechanics analysis,differential scanning calorimmetry,scanning electron microscope,rheological apparatus,respectively, to study the mechanism on the water resistance of modified PVAc emulsion.

利用Zeta电位仪、电导滴定法、激光粒度仪、DMA、DSC、SEM、流变仪等手段从Zeta电位、表面羧基密度、羧基和乳液组分中的相互作用、羧酸改性后胶膜的力学性能、水的存在状态、粒径分布、流变性能和微观形貌方面探索了羧基提高乳液耐水性的机理。

In the structures of these complexes, zinc can act as the vertex of the networks in various styles: single atom; dicarboxylate, tricarboxylate or tetracarboxylate bridged binuclear SBU ; and octacarboxylate bridged trinuclear SBU.

在这些配合物的结构中,锌离子可以按多种形式作为网络结构的顶点:单原子,双羧基、三羧基或四羧基桥连的双核锌次级结构单元,八羧基桥连的三核锌次级结构单元,再与配体组装成不同的配位聚合物网络。

The behaviors of supramolecular self-assembly of cabboxyl porphyrin-anthraquinone systems, carboxyl porphyrin zinc-copper systems, porphyrinatozinc-imidazolyl tailed porphyrinatomanganese systems, porphyrinatozinc-anthraquinone hybrids/imidazolyl tailed porphyrinatomanganese systems and porphyrinatozinc-fluorescein hybrids/imidazolyl tailed porphyrinatomanganese systems driven by hydrogen-bonding or coordination-bonding have been studied.

设计、合成了多种新型羧基卟啉、卟啉-蒽醌二元化合物和卟啉-荧光素二元化合物,研究了氢键或配位键驱动的羧基卟啉-蒽醌、羧基卟啉锌-羧基卟啉铜、锌卟啉-咪唑基尾式卟啉锰二元超分子,卟啉-蒽醌二元化合物与咪唑基尾式卟啉锰三元超分子的构建和光诱导电子转移性质。

In this paper, the orthogonal experimental analysis method is used to study on the effects of molar ratio of the unsaturated vinyl monomers, with carboxylic groups or sulphonic groups or polyoxyethylene side chain groups,etc., and the effects of the mean degree of polymerization in PEO side chains.

根据聚羧酸系高效减水剂的结构特点,采用正交试验分析法,分别研究了带羧基、磺酸基、聚氧化乙烯链酯基等活性基团的不饱和单体的物质的量之比及聚氧化乙烯链的聚合度等因素对聚羧酸系减水剂性能的影响,从而得出合成聚羧酸系高性能减水剂的一种最佳配方,并对试制产品进行了性能试验。

Results show that acid value of carboxylic wood powder from alkaline hydrolysis is higher,but its yield is lower than that from acid hydrolysis. The adsorption capacity of carboxylic wood powder for basic pink dye increased with increase of the initial concentration of the adsorbate,and could be kept over 500mg/g after repeated use and regeneration for 4 times.

实验结果表明:(1)在适量引发剂(FeSO4 * 7H2O=1g)和适当温度(60℃)作用下,可得到较高接枝增量和接枝率的PANW;(2)在PANW的水解反应中,在碱性催化剂作用下,可得到羧基含量高的产物,但收率较低;而在酸性催化剂作用下,则得到羧基含量低的产物,但收率较高;(3)羧基木粉对阳离子型染料--碱性桃红的吸附容量与起始浓度有关,本实验中,羧基木粉对碱性桃红的吸附容量最高可达500mg/g,对Cu2+的吸附容量最高可达39mg/g;(4)经0.3mol/LHCl再生4次后,羧基木粉对碱性桃红的吸附容量保持在440mg/g以上,在含有多种金属离子的溶液中,羧基木粉优先吸附Fe3+等硬酸型离子。

In this paper,the method for determining the COOH in PET has been introduced by three electrode potential titration .

采用三电极电位法,对以苯酚-四氯乙烷为溶剂测定聚酯中端羧基进行了实验和探讨,并建立了端羧基测定的新方法,此方法的相对标准偏差为 2 78%,可用于聚酯中端羧基测

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