羧基化

CA-CTSs including N,O-carboxymethyl chitosan,N,O-1-carboxyethyl chitosan (N,O-1-CEC),N,O-2-carboxyethyl chltosan(N,O-2-CEC),N-carboxymethyl chitosan and N-1-carboxyethyl chitosan(N-1-CEC) are quaternized using active quaternary salts prepared in laboratory.5 series including 25 kinds amphoteric chitosans characterized with polymeric ampholyte,in which 24 kinds are synthesized firstly,are obtained, 2-Hydroxypropyl dimethylbenzyl ammonium N,O-(1-carboxyethyl) chitosan chloride (GDMBA-N,O-1-CEC) is hydrolyzed into serial low molecular weight GDMBA-N, O-1-CEC with acid as catalyst and microwave as assistant instrumentality innovately.

以合成的活性季铵盐改性了N，O-羧甲基壳聚糖、N，O-1-羧乙基壳聚糖(N，O-1-CEC)、N，O-2-羧乙基壳聚糖(N，O-2-CEC)、N-羧甲基壳聚糖和N-1-羧乙基壳聚糖(N-1-CEC)等羧烷基壳聚糖，得到5个系列25种具有两性高分子电解质特征的新季铵化羧烷基壳聚糖，其中24种为首次合成；创新提出以微波辅助酸催化的方法催化2-羟丙基二甲基苄基-N，O-(1-羧乙基)壳聚糖氯化铵(GDMBA-N，O-1-CEC)水解，得到了低分子量的GDMBA-N，O-1-CEC。

It was found that there were 36 distinct differences in 184 protein spots. In-gel digestion and liquid chromatography mass spectrometry C LC-MS were made to analyze the protein SSP2801, and Mascot software was applied to identify the protein. The results showed the protein was large subunit of Rubisco, and its content in yellow mutant decreased distinctly, only about 26% of the comparison. Maybe it has relation to etiolation.

切耿其中差异最为明显的SSP2801位点蛋白进行胶内酶切、LC-MS分析，并应用Mascot软件检索鉴定，结果表明该蛋白组分为RUBP羧化酶的大亚基，其在突变体中含量明显减少，仅为对照的26％，表明突变体叶色黄化与RUBP羧化酶大亚基含量减少也有关系。

Based on our intensive studies on the lactonization of oligo/polysialic acids, we proposed for the first time that the lactone-ring formation of oligo/polysialic acids has three stages. We also provided a novel model to explain the conformational changes of oligo/polysialic acids caused by the repulsing forces among the carboxyl groups of sialic acid residues. Our results should provide novel approaches for further investigation of the structural-functional relationships of oligo/polysialic acids.

在对多/寡聚唾液酸内酯化过程进行深入研究的基础上，于国际上率先提出多/寡聚唾液酸内酯的形成具有三个阶段的观点，并首创性地提出了羧基排斥所致多/寡聚唾液酸分子空间构象改变的模型，为深入研究多/寡聚唾液酸结构与功能的关系提供了新生长点。

This paper builtup esterification model, pre-polycondensation model, polycondensationmodel, and successfully built up monitoringon-line system of some key quality tar gets as well as operation systemmodel according to the polycondensation technique of NOY company.

本文在软测量技术的基础上，建立了酯化反应控制模型、预缩聚反应控制模型、终缩聚反应控制模型，并成功开发出在线控制系统，对生产过程中的关键质量指标如粘度、二甘醇、端羧基进行在线控制，控制精度达到小于2.5％。

In this study, new benzo[l,2,3]thiadiazole derivatives were designed according to relationship of structure and efficacy. The 9 novel compounds were synsthesized with following reactions. The chlorine atom in 2-chloro-3,5-dinitro-benzoic acid as beginning raw material was substituted by 2-methylpropane-2-thiol, esterified then with bromoethane, reduced by iron powder and cyclized to obtain ethyl benzo[l,2,3]thiadiazole-7 after diazonation reation.

本论文根据苯并噻二唑诱导剂的构效关系设计了新的苯并噻二唑的结构，并合成了9个未见文献报道的化合物，合成步骤如下：采用2-氯-3，5-二硝基苯甲酸为起始原料，苯环上的氯原子被叔丁基硫醇置换，羧酸由溴乙烷酯化，硝基由铁粉还原，随后经重氮化关环生成苯并[1，2，3]噻二唑-7-羧酸乙酯。

A series of UV curable waterborne hyperbranched polyester s with different acid/amine terminal rate,which contained -OH?-COOH and methacrylic chain end groups,and were partly neutralized with thertiary amine,were synthesized from trimellitic anhydride,epichlorohydrin,glycidyl methacrylate and triethylamine.

以偏苯三酸酐、环氧氯丙烷、甲基丙烯酸缩水甘油酯、三乙胺合成了末端羧基与氨基不同比例的一系列可UV固化的高支化聚酯，研究了末端官能团对合成产物水溶性、粘度以及凝胶转化率的影响。

Citric acid anhydride was synthesized by citric acid and acetic anhydride with acetic acid as solvent.

柠檬酸酐是由柠檬酸两个羧基间脱水形成的，具有吸水性和酰化能力，是合成农药、医药、食品、饮料、清洁剂、化妆品和树脂的一种重要的中间体[1-2]。

The fast setting adhesive(HT-88)for GFRP was compounded from the prepolymer,low molecular polyamide,phenol aldehyde epoxy resin,bisphenol F type epoxy resin,liquid carboxylated butadieneacrylonitrile rubber,promotor,diluent and fillers.Its pot life,gelling time (at 60 ℃),glass transition temperature and shearing strength for bonding the unsaturated polyester GF...

该预聚物与低分子聚酰胺、酚醛环氧树脂、双酚F环氧树脂、液体羧基丁腈橡胶、促进剂、稀释剂、填料等复配的快固玻璃钢胶粘剂(HT - 88)，在室温下的适用期为 30～ 4 0min ，6 0℃的凝胶时间为 10min ，玻璃化温度 16 0℃，粘接不饱和聚酯玻璃钢的剪切强度为 5～ 7MPa。

The application of high functionalized SBR latex in the top layer of coated board was investigated.

研究了高功能化羧基丁苯胶乳在涂布白纸板面涂中的应用情况。

These two types of coupling reagents can effectively promote the condensations between N-methyl or Ca,Ca-dialkyl amino acids, and the yields are usually more than 90%. The reactions can be carried out using the so-called ￠one-pot￠ procedure without the preactivation of the carboxylic components.

这两类新型缩合剂可以高效地促进N-甲基氨基酸间或Ca，Ca-二烷基化氨基酸间的缩合，产物的收率一般在90%以上，反应可以采用&一锅法&进行，无须首先对羧基组份预活化。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。