羧基化

The invention aims at improving the quality of flour to researche a method for preparing new flour modifying agent, namely, the microencapsulation glucose oxidase, chitose-calcium alginate-glucose oxidase microcapsule which is obtained through the method is copolymer hydrogel which is obtained through double cross-linking, both amidogen and carboxyl group are fixed, and the whole system is a reticular formation.

本发明以改善面粉品质为目的，研究一种新型面粉改良剂――微胶囊化葡萄糖氧化酶的制备方法，采用上述方法制得的壳聚糖-海藻酸钙-葡萄糖氧化酶微胶囊，是经双重交联得到的共聚凝胶，氨基和羧基均被固定，整个体系为网状结构。

The surface morphology visualized by AFM as well as the regularity of the films studied by XRD was also reported.We found that the diazonium group can form H-bond with phenolic hydroxy and the multilayered film from DR and phenol-formaldehyde resin was first fabricated.

并且利用重氮树脂的光反应这一独特性质，发展了组装纳米粒子及羧基功能化纳米管的方法，这将会在制备胶体晶体(胶体粒子规整排列，具有似晶体的结构)和固定纳米管上有所应用。

After investigation of a series of synthetic routes of Cefepime, we determined the best route and researched each step of the synthetic process for the goal of cost-cut, simplifying operation procedure and improving yield.

以7-ACA为起始原料，经硅烷化保护氨基和羧基、碘代、置换、脱保护、成盐、缩合、成盐等六步反应，合成了目标化合物，总收率为21％（以7-ACA计）。产品结构经1H-NMR、MS确证。

Various chrome complex dyes(1:1 ratio) of mordant black 1,mordant black 7,mordant black 9 and mordant black 11 have been synthesized and sodium dichromate is been used as mordant agents instead of Cr3+ to oxidate dyes sufficiently.

还设计合成了媒介黑1、媒介黑7、媒介黑9和媒介黑11的高水溶性1∶1络合染料，重铬酸钠作为铬化试剂，染料得到了充分的氧化，无色配体多羟基羧基酸的引入使染料有很好的水溶性，该实验路线未见报道。

The catalytic system composed of NHPI and transition metal ion can catalyze effectively ethane into acetic acid,cyclane into dicarboxylic acid,toluene into benzoic acid,alkene into epoxide,alkyne into acetylenic ketone,and amide into imide;NHPI used alone can catalyze adamantane to be carbonylated,hydrogen peroxide prepared by oxidization alcohol;NHPI combined with as...

NHPI与过渡金属离子组成的催化体系能高效地催化乙烷氧化为乙酸、环烷烃氧化为二元羧酸、甲苯氧化为苯甲酸、烯烃氧化为环氧化物、炔烃氧化为炔酮、酰胺氧化为酰亚胺；NHPI单独使用能催化金刚烷发生氧化羰基化反应、催化氧化醇制取过氧化氢；NHPI与有机助催化剂如偶氮二异丁腈、溴化季铵盐、蒽醌和醇等也能催化分子氧氧化反应。

A series of novel bile acid derivatives as potential hepato-biliary and intestinal scintigraphy imaging SPECT (single photon emission computed tomography) tracers were prepared from bile acids by es-terification, aminolysis of esters and alkylation of amino groups.

以胆酸、鹅去氧胆酸为起始原料，经羧基的酯化、酯的胺解以及氨基的烷基化，合成了一系列潜在的针对肝胆显像和肠显像的SPECT (Single photon emission computed tomography)分子探针前体。

Based on the problem of various types of catalyst and according to the features of carbonylation catalysts reactions, our team has been designed a series of new metal complexes of benimidazoles, which can be used for carbonylation catalyst of industry. Seven new benzimidazole derivatives were prepared by the o-phenylenediamine、oxalic acid、glycolic acid、monomethyl monopotassium malonate、ethyl cyanoacetate、succinic anhydride. The structures of them were confirmed by IR、Elemental analsis. The crystal structures of d and e were determined by X-ray single crystal diffraction of Germanic Bruker Smart APEX II CCD. The catalysis of them was tested by carbonylation reactions.

本文设计以邻苯二胺和草酸、羟基乙酸、丙二酸单甲酯、氰基乙酸乙酯、丁二酸单甲酯为原料采用PPA催化和无机酸催化法，合成了4种苯并咪唑-2-羧酸衍生物并进行了表征；培养了2个化合物d、e的晶体并测定和讨论了晶体结构；制备了3种未见报道的苯并咪唑金属配合物，对配合物在羰基化法制醋酐-醋酸反应的催化作用进行了初步试验。

A series of ABEPS were synthesized from long chain fatty acids, benzene, polyglycol and 1, 3-propane sultone by the procedure of Friedel-Crafts acylation, Huang-Minlon reduction, Williamson and sulfonation reaction, and these compounds had never been reported in the past time.

以长链羧酸、苯、多缩乙二醇和丙烷磺内酯为初始原料，依次经Friedel-Crafts酰基化反应、Huang-Minlon还原、Blank反应、Williamson成醚以及磺化反应等过程，合成了系列未见报道的ABEPS。

Influence of the chemicals on the composition of pyrolysis products of Tilia amurensis lignin was discussed. During the pyrolysis process, a great deal of CO2, CO and H2O was produced, which was mainly attributed to the elimination of carbonyl, carboxyl, hydroxyl, methyl and the further reaction to form polycyclic aromatic hydrocarbons.

结果表明：木质素在裂解过程中，产生大量的CO2、CO、H2O，其主要原因是高温时羰基、羧基、羟基、甲基等脱除反应以及环芳香族化反应深入进行，而所选用的阻燃剂大多数促进了CO2、CO、H2O的产生。

Meldrum is a carboxyl-phthalocyanine weak resistance agent, with the activity of this enzyme metal ion (Mg2 + Mg2 +) formed fairly stable chelate, and its derivatives benzene methyl malonic acid is a strong resistance agent.

丙二酸是一个羧基酞酶的弱阻化剂，它与这种酶的活性金属离子(镁离子Mg2+)形成相当稳定的螯合物，而它的衍生物苯甲基丙二酸则是一个强阻化剂。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。