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The results showed that technique conditions were temperature 80 ℃ and time 2 h, the content of carboxyl group increased with the increase of amount of the carboxylation agent and the conversion was more than 60%.

结果表明:在反应温度80℃、反应时间2h的工艺条件下,随着羧化剂用量的增加,HCTPB的羧基含量增加,且转化率都在60%以上。

Hrough copolymerization of styrene with few quantity of methacrylic acid, maleic anhydrate or 4-vinyl pyridine respectively and of butyl methacrylate with maleic anhydrate, the functional groups carboxyl, simple anhydride and pyridyl have been introduced respectively to the chain of PS or PBma.

通过苯乙烯与少量的甲基丙烯酸、马来酸酐或4—乙烯基吡啶的共聚及甲基丙烯酸正丁酯与马来酸酐的共聚,可在聚苯乙烯及聚甲基丙烯酸丁酯链上分别引入功能基因羧基、酸酐基和吡啶基对共聚物进行了红外光谱、酸碱滴定、元素分析、玻璃化转变温度、粘度及紫外光谱的测定。

The paper carries on qualitative analysis to the acetone extractives before and after discoloring, shows the main components of the extractives and then takes comparison. The results shows :①The hydroxyl is oxidized and then shifted to the carbonyl,carboxyl, ester and ketone groups during inducing discoloration under the pretreatment conditions,which makes the wood color deep;② There are plenty of auxochromic groups in the acetone extractives of silver chain, the interaction between the auxochromic groups and the chromophoric groups makes the wood color deep.

摘 要:本文通过对刺槐变色前后丙酮抽出物的定性分析,得出变色前后丙酮抽出物的主要成分,进行对比分析,初步得出抽出物对诱发变色的作用为:①变色前后羟基在预处理条件下氧化成羰基,羧基,酯基和酮基等官能团,使木材颜色加深;②刺槐丙酮抽出物的主要成分中含有大量助色基,这些基团会与木素中的发色基团相互作用,使木材颜色加深。

One class is CAAX-mimetic compounds with an imidazolyl residue on one end and a carboxylic group on the other connected by benzodiazepine scaffold at different positions.

连有咪唑基的苯并二氮杂草化合物,以苯并二氮杂草-2-酮为分子骨架,7位连接含有咪唑基的侧链,1位或3位连接含羧基或酯基的侧链。此类化合物模拟了CAAX配体。

Property : This product is a polymer composed of carboxyl, sulphonic, phosphonic . There is organophosphate in the chain and side chain, so it is of superior effect of scale-preventative and be of certain corrosion-proof effect.

5.1性能:本品是含有羧基、磺酸基、膦酸基羟基等基团的共聚物,由于它的直链上和部分支链端含有膦基酸,因此本共聚物具有优异的防垢性能,并具有一定的防腐蚀性能。

Cooking at the course functional groups of residual lignin changes, methoxyl content decreased, from 15.42% dropped to 12.35%, the phenolic hydroxyl group content and carboxyl content has increased, from 2.08% rosed to 3.17%, carboxyl content from 5.36% rosed to 5.99%.

木质素研究指出:甜竹原料木质素中C9单元式甲氧基含量与青皮竹比较相近、分子量主要集中在小于4000组分(占50.5%)而大于16000只占少量、甲氧基含量为15.42%、酚羟基含量2.08%、羧基含量5.36%、硝基苯氧化结果摩尔比为

The latter is chlorinated in the side chains under free-radical conditions to give 2,4-dichloro-5-fluoro-3-dichloromethyl-1-trichloromethylbenzene. The latter is hydrolysed via 2,4-dichloro-5-fluoro-3-dichloromethylbenzoic acid, which can be isolated if necessary, to give 2,4-dichloro-5-fluoro-3-formyl-benzoic acid, the aldehyde group of which is reacted to give 2,4-dichloro-5-fluoro-3-N-hydroxyiminomethyl-benzoic acid, from which, with simultaneous conversion of the carboxyl group into the chlorocarbonyl group, water is eliminated using an acid chloride to give the nitrile 2,4-dichloro-3-cyano-5-fluoro-benzoyl chloride.

随后,在游离基条件下进行侧链的氯化,得到2,4-二氯-5-氟-3-二氯甲基-1-三氯甲基苯、后者被水解,经过2,4-二氯-5-氟-3-二氯甲基苯甲酸(如果需要此化合物可以分离),得到2,4-二氯-5-氟-3-甲酰苯甲酸,将其醛基反应,得到2,4-二氯-5-氟-3-N-羟基亚氨基甲基苯甲酸,用酰氯从其中除去水,同时将羧基转化为碳酰氯,得到一种腈,即2,4-二氯-3-氰基-5-氯-苯甲酰氯。

We have synthesized 4,4'-dinitro-3 4''-dimethyl triphenylamine,(1), in 84% yield in an one-step condensation process between 3,4-dimethyl aniline and 4-fluoro-nitrobenzene. After the auto-oxidation of (1) and the subsequent hydrogenation of the nitro-groups, an AB2 type triphenylamine polyimide intermediate bearing two amine groups and one acid-anhydride group each on individual phenyl ring,{AB2 PI Intermediate}, was prepared successfully. The yields of the autoxidation and the hydrogenation steps are 81% and 90% respectively.

中文摘要本研究以3,4-二甲苯胺及4-氟硝基苯为原料,经一步骤缩合反应得到产率为84 %之4,4'-二硝基-3&,4&-二甲基三苯胺(1),由(1)经自氧化法后再以氢化法还原硝基,成功地制备出带有二胺基与一羧基的三官能基之AB2型三苯胺中间体(AB2型PI中间体),自氧化反应与氢化法的产率各为81%及90%。

Among it wrap up surface auxiliary that cover,-COOH,-OH, sulphur base S032~ sour hydroxyl carboxyl , etc. group last the not facilitating last aluminium the buoyancy of floatings of the powders, and C-C chain , alkyl phenyl R-C6HU fatty alcohol base fatty acid base R-COO, R-0- long in structure, etc. base group kiss not oily, base these group add , facilitate aluminium powder water build rise of area.

表面包覆的助剂中,羧基-COOH、羟基-OH、磺酸基SO_3~(2-)等集团是亲水性的有助于提高铝粉的漂浮力,而C-C结构长链、烷基苯基R-C_6H_(14)脂肪醇基R-O-、脂肪酸基R-COO~-等基团是亲油性的,这些基团的加入有助于铝粉水盖面积的提高。

Preferably, at least one member selected from among heterocyclic compounds having any of hydroxyl, carbonyl, carboxyl, amino, amido and sulfinyl and containing at least either a nitrogen or a sulfur atom is contained in the polishing solution.

优选其中包含杂环化合物,所述杂环化合物含有羟基、羰基、羧基、氨基、酰胺基和亚磺酰基中的任1种,且含有氮和硫原子中的至少1种。

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