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The neighbor-ing two Gd3+ ions are connected by two simple bridged carboxyl groups and a μ2-bridging carboxylgroup. Each G-d3+ ion is simuetaneosly coordinated by two water molecules. So the coordination num-ber of Gd3+ is nine, forming a coordination polyhedron of distorted mono capped square antiprism.

相邻Gd3+离子通过2个简单羧基桥和1个μ2羧基桥联结起来,还有2个水分子配位于每个Gd3+离子,所以Gd3+的配位数为9,形成变形的单帽四方反棱柱体。

Structural analyses reveal that all species consist of a pair of hetetrometallic atoms triplybridged by bidentate pivalate ligands.

它们共同的结构特征是异金属离子间均由三个双齿的羧基桥连,在四核的化合物20和21中两个稀土离子通过两个双齿羧基相连。

Ferrocenecarboxylic-ssdeoxyribonucleic acid probe was made by chemically bounding FCA to terminal 5'-amino of oligonucleotide in the presence of a water-soluble carbodiimide. The hybridization reaction was conducted by immersing the immobilized-ssDNA electrode in FCA-ssDNA probe solution.

在偶联活化剂碳二亚胺的存在下,通过羧基二茂铁上的羧基与DNA分子上的氨基共价键合,将FCA标记在氨基修饰的寡聚核苷酸片段上,制备成FCA-ssDNA探针。

Crystal by DTT into the protoxin with an end amino group; activation and derivation of abamectin to form abamectin-COONa with a carboxylic group; final bioconjugation by using amino-carboxylic conjugator EDC to achieve the substance combination of two biotoxins.

晶体进行酶解改造,形成带末端氨基的原毒素;将阿维菌素的羟基进行激活、衍生化,形成带羧基的阿维菌素衍生物(Abamectin-COONa);再利用氨基-羧基偶联剂进行两种生物毒素的生物耦合。

Effects of different anti-ions on dispersivity indicated that the best dispersivity was gained when diethanolamine was used.

使用氢氧化钠对聚丙烯酸不同程度的中和,通过红外光谱分析了羧基的中和程度,考察了羧基中和程度对分散剂性能的影响。

In this article, high-pure lactic acid and ethanol acid were used to synthesized PLGA by direct condensation polymerization, and zinc octanoate of low nocuity was used as katalyst, instead of stannous octanoate to synthesize PLGA by the way of opening ring.

本文首次采用高纯度乳酸、乙醇酸直接缩聚合成无催化剂的端羧基PLGA,并分别采用了低毒性辛酸锌代替辛酸亚锡为催化剂通过开环聚合法合成端羧基/酯封端PLGA。

In - situ photoelectrochemical microscopic method has been used to characterize the spatial variation of the film formed on the copper surface in buffer - borax solutions (pH 9.2) with different concentration of benzotriazole and combined benzotriazole methanoic acid ester .

采用激光扫描微区光电化学显微技术对不同浓度下的苯并三氮唑及其衍生物4-羧基苯并三唑甲酯与5-羧基苯并三唑甲酯的混合物在硼砂缓冲溶液(pH9.2)中对铜电极的缓蚀作用作了比较研究。

The influence of the use level of base and monochloroacetic acid on the degree of substitution in CMS,the influence of DS and H/Na(ratio of free and salified carboxylic acid in CMS)on swelling and disintegrating of CMS have been discussed.

考察了碱和一氯乙酸用量对CMS取代度的影响及DS和CMS中游离羧基和成盐羧基比对崩解剂吸水溶胀性能的影响。

ATA was found to exhibit more distinctive cytotoxicity toward human cervical squamous carcinoma HeLa cells than oleanolic acid, which suggested that the position of the carboxyl group significantly affects the cytotoxicity of oleanane-type pentacyclic triterpenes with a carboxyl group.

周晓华被发现展品更为鲜明的细胞毒性,对人体颈部鳞癌Hela细胞比齐墩果酸,这表明的立场与羧基显着影响细胞毒性的齐墩果烷型pentacyclic三萜类化合物与羧基

Several types of ligand reactions observed under hydrothermal condition were summed up:(1) hydrolysis of pyridine nitrile, aldehyde and ester in mixed water and alcohol into pyridine-carboxylate;(2) replacement of carboxylate group with sulfonic group;(3) coupling of phenanthroline by dehydrogen;(4) oxidative coupling of methanol into oxalic acid;(5) hydroxylation of isophthalate.

总结了以往在水热条件下观察到的几类配体反应:(1)吡啶腈、醛和酯在醇和水混合溶液中水解成吡啶羧酸;(2)磺基取代羧基反应;(3)邻菲啰啉的脱氢的聚合:(4)甲醇被氧化偶合生成草酸:(5)间苯二甲酸的羟基化反应。

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